不同传热规律下的热漏损失对制冷机R—ε特性的影响

本文基于存在热阻和热漏损失的定态流不可逆卡诺制冷机模型,导出了热阻损失服从牛顿定律和热漏损失服从一般传热规律时制冷系数与制冷率间的优化关系,研究了不同传热规律下的热漏损失对制冷机优化性能影响的特点。     

气相生长碳纤维的制备

以苯和氢气为原料在石墨,陶瓷等基板表面催化热解制取低成本,高性能的气相生长碳纤维（ＶＧＣＦ）,实验考察了催化剂类热解温度、热解时间,苯带入量,载气,基板材料等参数对ＶＧＣＦ生长情况及性能的影响,并提出了碳纤维的生长机理。结果表明,在合适条件下,用直接播种法制得的ＶＧＣＦ直径为０．７￣１０μｍ,长度为１￣５μｍ,采用金属原子溅射沉积的基板可得到均匀稠密的ＶＧＣＦ,直径为３￣８０μｍ,碳纤维的生长过程     

空化水射流研究现状及其应用

综述了高压水射流技术发展及应用过程,认为空化水射流是一种富有发展前途的高效新型射流．通过对空化水射流机理、空化数和冲击压力两个重要空化参数的分析,显示了空化射流的潜在优势．实验表明人工淹没空化射流具有较强的冲蚀效果,并克服了靶距范围的不足．简要介绍了该技术应用于火箭发动机内脏固体推进剂清洗工程的射流系统设计．     

构成基本串联与并联非线性系统结构模型的一种判别依据

本文基于Ｖｏｌｔｅｒｒａ理论和Ｗｉｅｎｅｒ理论,利用相关分析法,研究并给出了构成基本串联与并联非线性系统结构模型的必要条件,它们能够为辩识一大类可以表示成这些模型和＂黑箱＂非线性系统提供一种重要的判别依据。文中还给出了计算机模拟算例。     

Design and Asymmetric Synthesis of beta-Strand Peptidomimetics

We describe the asymmetric synthesis of non-peptidic compounds that feature rigid backbone conformations and present various side-chain functions. The key step in the synthesis of these compounds is the C-acylation of an appropriate ketone with a suitably protected aspartic acid derivative. The resulting dipeptide modules may be connected to form tetrapeptide mimics. Specifically is described the mimicry of a four-residue segment of CD4, the cellular receptor of HIV-1. The design was based on molecular modeling and the X-ray crystal structures of CD4 and intended to present the most important side chains and backbone elements of the Phe43-Lys46 segment.     

Photochemical Reactions of Alkyl Phenylglyoxylates(1)

Three new photoproducts, ethyl O-benzoyl mandelate (5a), ethyl O-acetylmandelate (6a), and biphenyl triketone (7a) are isolated and identified in the reactions of ethyl phenylglyoxylate (1a) in benzene. Quantum yields and initial rate constants of product formation are shown to be concentration dependent. For the formation of carbonyl product 3 at lower starting material concentrations (<0.01 M), quantum yields greater than 1 are observed. Variations in the quantum yields as a function of reaction time are due to the accumulation of alpha-hydroxyphenyl ketene (D). The relative reactivities of triplet excited states of phenylglyoxylates 1 and phenyl ketones are compared. A mechanism involving both intramolecular gamma-H abstraction and intermolecular H abstraction, which leads to radical chain reaction, is proposed. Rate constants for intramolecular gamma-H abstraction (k(N)) and intermolecular H abstraction (k(I)) of methyl phenylglyoxylate (1d) are measured.     

Surface state of molybdenum cations in MoO3/CeO2

Conclusion  

R-matrix methods for studying nuclear effects in μCF

Properties ofR-matrix theory that are useful for studying muon-catalyzed fusion reactions are reviewed, and applications to the dt system are discussed, using both improved adiabatic and non-adiabatic (variational) wave functions. We give complex eigenvalues and - sticking fractions for the (L, v)=(0,0) and (0, 1) states of dt using variational Hamiltonian matrix elements that have been properly symmetrized by means of the Block operator. Expressions for the fusion rate and - sticking fraction are developed from a time-dependent theory that uses the complex-energy states corresponding to the poles of the systemS-matrix. These are shown to reduce with the appropriate approximations to the expressions and values commonly used. Additional nuclear effects on these quantities can easily be studied within the framework developed, but they are not expected to be large.     

A five-channel grating spectrometer for millimeter-waves

A five-channel grating spectrometer for use in millimeter wave band (25100GHz) is described with its design theory of optical path, and measured results of insertion loss and resolving power.