基于Web of Science的河北大学科研论文统计分析

以Web of Science数据库为文献来源，利用文献计量学的方法，从文献年收录量、文献类型、语种、学科分布、作者分布、合作情况、来源期刊和引用情况等方面，对Web of Science收录河北大学2004—2013年的科研论文进行统计分析，结果表明：河北大学近10年来被Web of Science数据库收录的文献数量和被引频次呈现逐年上升的趋势，在化学、物理学、动物学和数学方面具有一定的科研能力和影响力，但同时应注重国际合作交流和文献的质量。     

3维Maxwell方程局部1维多辛格式的能量恒等式

在理想导体边界条件下,对3维Maxwell方程的局部1维多辛Preissman格式的能量守恒性质进行研究.运用能量分析法推导了2个能量恒等式,这些恒等式说明了给出的格式在所定义的离散范数下是能量守恒和无条件稳定的,数值算例验证了结论的正确性.     

一类指数Diophantine方程的解的唯一性

给出并证明了指数Diophantine方程2^x+3^x+a=5^x+b(x,a,b∈N,a>b且a,b为常数）的解的唯一性.     

抗坏血酸/谷氨酸Maillard反应体系中间产物和褐变程度的研究

用磷酸缓冲溶液配制一系列不同质量分数的抗坏血酸/谷氨酸混合溶液pH8.0并在130℃下加热发生Maillard反应,对反应后体系的中间产物(A294nm)、褐变程度(A420nm)以及反应过程中抗坏血酸和谷氨酸的含量进行检测分析.结果显示,抗坏血酸通过热解产物与氨基酸发生Maillard反应,抗坏血酸质量分数的增大能促进反应体系的褐变,谷氨酸质量分数对反应体系褐变程度的影响不大.任意增大一种反应物的质量分数均可对无色中间产物的生成起促进作用,且抗坏血酸对中间产物生成的影响大于谷氨酸.     

Chain transfer to solvent in BN 2-vinylnaphthalene radical polymerization

The synthesis of vinyl alcohol copolymers is limited due to the poor radical reactivity of vinyl acetate (VAc), the traditional precursor to polyvinyl alcohol (PVA). Main group monomers such as BN 2-vinylnaphthalene (BN2VN) have attracted attention as alternatives to VAc to form side chain hydroxyls via oxidation, but outstanding questions of molecular weight control remain. Herein we report systematic investigation of solvent, temperature, and initiator concentration as factors influencing BN2VN degree of polymerization. We find increased chain transfer to toluene, hypothesized to arise from differences in radical stabilization and reactivity by aromatic and BN aromatic rings. As a result of these combined efforts, high molecular weight (M_w ~ 10⁵ g mol⁻¹) BN2VN homopolymers and BN2VN-styrene copolymers were obtained.     

关于两个投影矩阵的相互关系

运用Moore-Penrose逆的定义及其性质和投影的定义去研究投影PR(A)和PR(AB)的相互关系,得到若干结果 .研究表明:若矩阵A,B满足如下条件:(1)BB*=I,(2)B为酉矩阵,(3)B为非奇异阵,(4)A是列满秩,B是行满秩,则两者相等;若对于任意矩阵A,B时,两者之间存在若干重要关系式,从而进一步刻画了它们的相互关系.     

自然地理野外实习研究

关于自然地理野外实习的研究,大多侧重于实习模式、实习基地建设等方面,针对具体的过程、效果评价等研究不足.本文以聊城大学自然地理野外实习为例进行探析,运用建构主义的观点提出了影响实习效果的五大因素以及相关对策,对野外实习改革具有一定的理论意义.     

用标准件对梯度磁场定标

就标准厚度卡片在霍尔传感器的定标方面的应用作了有益的探讨。在纵向测量微小长度时,霍尔片处于磁场边缘位置,其对磁场的梯度更大,即灵敏度更高,且靠中心位置的线性更好。     

Precise Synthesis and Thin Film Self-Assembly of PLLA-b-PS Bottlebrush Block Copolymers

The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time.     

pH-Sensitive Oscillatory Motion of a Urease Motor on the Urea Aqueous Phase

A self-propelled object coupled with an enzyme reaction between urease and urea was investigated at the air/aqueous interface. A plastic object that was fixed to a urease-immobilized filter paper was used as a self-propelled object, termed a urease motor, placed on an aqueous urea solution. The driving force of the urease motor is the difference in the surface tension around the object. Oscillatory motion or no motion was triggered depending on the initial pH of the urea solution. Both the frequency and maximum speed of the oscillatory motion varied depending on the initial pH of the water phase. The mechanisms underlying the oscillatory motion and no motion were discussed in relation to the bell-shaped enzyme activity of urease in the enzyme reaction and the surface tension around the urease motor.