Electrochemical behavior of Li intercalation processes into a Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 cathode

Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO₂ structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂. Indeed, Li[Ni_0.50Mn_0.50]O₂ compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni_0.17Li_0.22Mn_0.61]O₂ and Li[Ni_0.25Li_0.17Mn₀.₅₈]O₂ compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni²⁺ and about Ni³⁺, while the oxidation state of Mn ion sustains Mn⁴⁺ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂, in which Ni ion changes between Ni²⁺ and NI⁴⁺. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process.     

Characteristics and structures of weak efficient surfaces of production possibility sets

This paper studies the characteristics and structure of the weak surface of the production possibility set. We apply techniques and methods of transferring a polyhedral cone from its intersection form to its sum form, identify an intersection representation of the production possibility set. We give the structure theorem of weak surface of the production possibility set, which includes three complementary slackness conditions. We define the input weak efficiency and output weak efficiency for different DEA models according to the representation of the intersection form. It investigates the characteristics of the weak surfaces, and proves the structure theorems of input weak DEA efficiency and output weak DEA efficiency. The structure theorems establish weighted combination of inputs and outputs that are weak DEA efficient. Numerical examples are provided for illustration.     

筒型基础系缆平台沉／拔过程侧摩阻力原型测试

介绍了1999年首次安装在渤海锦州9－3地区多筒基础平台安装施工过程中的侧摩阻力原型测试研究，描述了简型基础上沉和上拔过程中筒壁侧摩阻力的测试系统和测试方法，给出了主要测试结果并与现行规范进行了对比分析，这项成果对筒型基础平台的设计和施工具有直接的参考意义。     

Crystallographic report: Bis(norfloxacin)dilead(II) tetranitrate, [Pb2(H‐Norf)2(ONO2)4]

The centrosymmetric binuclear structure of [Pb₂(H‐Norf)₂(ONO₂)₄]shows the geometry around each lead(II) atom to be distorted trigonal bipyramidal with Pb–O distances ranging from 2.357(3) to 2.769(4) Å. Copyright © 2003 John Wiley & Sons, Ltd.     

PuCO气态分子的热力学稳定性

在相对论有效原子实势近似下 ,用密度泛函B3LYP方法研究得到PuCO气态分子的热力学函数 ,根据热力学原理 ,计算得到PuCO气态分子在不同温度下的标准生成自由能变 ,据此说明PuCO气态分子不具有热力学稳定性     

The Monitoring System Using FOBG Sensor for The Health of the Rocket

A novel heath monitoring system of the rocket based on fiber optic Bragg gratings is brought forward, its component units and working principle are also described.     

Geometrical study of paraxial light beam transmission in free space

By introducing an imaginary space transform curvature ρ_s, a complex space called Riemannian space is constructed, in which the light propagating in free space has the trajectory of straight line while propagating. Moreover, this curvature couples with that of the wave front of the paraxial beam ρ_w, and therefore a complex curvature ρ_c is constructed, which can be employed to investigate the behavior of the light transmission and to generalize the ABCD law. Project supported by the National Hi-Tech Inertial Confinement Fusion Committee, the Guangdong Natural Science Foundation the Postdoctoral Foundation of Guangdong and National Postdoctoral Foundation of China.     

发酵监控系统上位计算机软件编程研究

提出了利用上位机参与实时控制,综合分析在线参数、离线参数和间接参数,辅助发酵过程工艺研究和优化控制,并给出了上位机软件包的部分源程序及框图。该软件包对发酵工艺人员进一步了解菌种的遗传特性、细胞代谢调节和反应器工程特性方面有较大帮助。     

光回归反射织物的研究中粘合剂的选择

为了得到高反射率的回归反射涂层产品，本项目通过大量实验，生产出最佳的粘合剂及优选出其用量，并利用扫描电镜照片进行了分析。     

聊城地区旅游资源及其开发利用

聊城地区历史悠久，旅游资源丰富，但旅游事业起步晚，开发利用不够．为此，本文在分析聊城地区旅游资源的功能和分布的基础上，①对旅游资源的特色进行了初步评价，进而提出开发聊城地区游资源的几点设想．