Controlled/living polymerization of 2‐(diethylamino)ethyl methacrylate and its block copolymer with tert‐butyl methacrylate by atom transfer radical polymerization

Polymerization of 2‐(diethylamino)ethyl methacrylate (DEAEMA) via homogeneous atom transfer radical polymerization under various reaction conditions is described. The effects of the initiators and solvents were examined. With 1,1,4,7,10,10‐hexamethyl triethylenetetramine/copper(I) chloride/p‐toluenesulfonyl chloride as the ligand/catalyst/initiator system in methanol, poly(DEAEMA) with a polydispersity index as low as 1.07 was synthesized. Kinetic studies demonstrated the polymerization was very well controlled and exhibited the living characteristic of the process. Well‐defined block copolymers of DEAEMA and tert‐butyl methacrylate (tBMA) were successfully synthesized. The copolymers could be synthesized with equally good results by starting with either p(DEAEMA) or p(tBMA) as the macroinitiators. However, only the macroinitiators terminated with chlorine should be used. The corresponding macroinitiators with bromine as a transferable group did not yield well‐defined copolymers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2688–2695, 2003     

模糊集技术在网络信息过滤系统中的应用研究

本文将模糊模式识别引入到校园网信息过滤系统中，通过网页内容识别和分级技术将各种不同网站进行分类，过滤和禁止有害网络信息，从而达到校园网的信息“净化”目的。     

改善大学生耐久力的实验研究

针对大学生心肺功能弱，体力差的这一普遍问题，本文通过调查和长跑教学实验，找出问题产生的根源，提出运用点面兼顾的教学方案、灵活多变的教学方法和循循善诱的心理引导等手段，提高学生的练习兴趣，达到增强其心肺功能和耐久力的目的。     

CRP复合材料板复合型裂纹扩展方向预测理论研究

本文对碳纤维增强的复合材料板裂纹扩展方向预测理论进行了研究。介绍了最新发展起来的复合材料Z断裂理论 ,并通过试验证明了新理论的正确性     

关于足球运动员保持竞技状态的探讨

足球运动的不断发展和进步 ,赛事不断增加 ,赛季不断延长 ,比赛激烈性不断加大。如果在比赛中能够充分发挥运动员的竞技状态 ,这将对比赛起着不可估量的作用 ,而长期的保持这种状态 ,对整个赛季比赛的获胜至关重要。     

山东细犬能量需要与平衡研究

能量是营养学的重要指标,能量摄入和消耗之间的失衡对动物的健康及保持作为实验动物的重要特性都会产生影响.对于犬的能量需要研究一般是研究基础代谢率,近年来研究能量需要较多,比如热量测定法或保持体重恒定法.保持体重恒定法是指一定时间(5周以上)保持体重恒定时的能量需要为主要指标,保持体重恒定时的进食能量即为能量需要.通过选取1岁左右健康山东细犬12只,随机分为3组,每组4只,各组分别喂不同能量水平的日粮(能量水平分别为10.22MJ/kg、11.23MJ/kg、11.92MJ/kg),每天上午定时定量饲喂,自由饮水.每周空腹称重.饲养试验的第15d开始收集粪便,连续4d,将4d粪便混匀在一起,部分取样进行水分和含氮量测定,其余部分制成风干标本测定能量,用测热法测定能量.主要结果如下三组动物在不同能量水平饲喂6周体重增加不明显(P＞0.05);三组动物粪能和尿能无显著性差异,但消化能和代谢能差异显著(P＜0.05).说明对于山东细犬,维持体重的恒定不需要刻意控制饲料的能量水平,其自身可以通过不同的代谢水平调节.     

Numerical study of simultaneous natural convection heat transfer from both surfaces of a uniformly heated thin plate with arbitrary inclination

 Numerical studies were conducted to investigate the natural convection heat transfer around a uniformly heated thin plate with arbitrary inclination in an infinite space. The numerical approach was based on the finite volume technique with a nonstaggered grid arrangement. For handling the pressure–velocity coupling the SIMPLE-algorithm was used. QUICK scheme and first order upwind scheme were employed for discretization of the momentum and energy convective terms respectively. Plate width and heating rate were used to vary the modified Rayleigh number over the range of 4.8×10⁶ to 1.87×10⁸. Local and average heat transfer characteristics were compared with regarding to the inclination angle. The empirical expressions for local and average Nusselt number were correlated. It has been found that for inclination angle less than 10^∘, the flow and heat transfer characteristics are complicated and the average Nusselt number can not be correlated by one equation while for inclination angle larger than 10^∘, the average Nusselt number can be correlated into an elegant correlation. Received on 18 April 2001 / Published online: 29 November 2001     

大豆开花期缺水和遮光处理叶片解剖结构的观察

大豆珍珠塔3号具有双子叶植物叶片结构特征,但在海绵组织最上层有一层特殊细胞——平脉叶肉细胞,此层细胞具有水平运输和气体交换的特殊作用。大豆开花期光照对叶片结构发育起主导作用;水分亦是影响叶片结构发育的重要因素;光弱块水条件下,大豆表现出对光的竞争比对水的竞争更明显。     

动力减振实验装置的结构设计与研制

介绍动力减振实验装置的结构、实验的方法、步验与数据处理。实验结果表明所采用的设计方法是合理的、可行的。