能量色散偏振X射线荧光光谱法测定生铁中锰和钛

探讨了应用能量色散偏振X射线荧光光谱仪测定生铁中锰和钛进行炉前快速分析的方法.对测定锰及钛时仪器的工作条件,试样的制备以及工作曲线的制作等因素作了较系统的试验,该方法所得测定结果与化学法测定结果或标样标准值相吻合,相对标准偏差小于1.5%,与化学法相比,锰和钛的测定时间由50 min缩短到2 min.     

Attenuation properties of EM wave by magnetized nonuniform plasma slab coated on perfect conductor plane

The total amplitude reflection coefficient of EM wave in a nonuniform plasma slab coated on perfect conductor plane is newly derived by using the scattering matrix method (SMM), and the attenuation is calculated. Three types of plasma electron density profile, that is the hyperbolic, sinusoidal, and linear profiles, are used. The external magnetic field and plasma parameters such as the maximum electron density and collision frequencies are discussed to calculate the attenuation of EM wave. The calculation results show that the plasma electron density profile and maximum electron density exert a large effect to the attenuation of EM wave and the attenuation under the uniform external magnetic field is taken place by the electron cyclotron resonance absorption, the up hybrid resonance absorption and geometric resonances absorption.     

新型高效定量脱气器研制及试验研究

新型高效定量脱气器采用定量泵、电加热器、脱气箱、真空泵等设计,可对钻井液进行定量采集、加热、高速搅拌以及负压抽吸,且具有温度控制系统和数据采集检测系统,实现对钻井液在线油气分析;同时新型高效定量脱气器按照井场防爆要求设计,防爆等级达到Ⅰ级,满足油井使用要求。结果表明:新型高效定量脱气器采液流量为0.5L/min,能够脱出C_1~C_8、苯、甲苯等气体组分,并且其对C_1的脱气效率在50%左右,是同环境下电动脱气器的6~10倍。新型高效定量脱气器工作可靠、性能稳定,且其脱气效率远高于同环境下的电动脱气器。     

Synthesis of 4‐Vinyl‐1H‐1,2,3‐triazoles on Solid Supports via Polystyrene‐Bound But‐3‐ynyl Selenide

A facile method for solid‐phase organic synthesis of 1‐substituted‐4‐vinyl‐1,2,3‐triazoles from polystyrene‐supported but‐3‐ynyl selenide has been developed. This sequential [3+2] cycloaddition and oxidation–elimination reactions could be carried out under mild reaction conditions with straightforward operation and good yield and purity of the products, and broad scope of substrates, and could be applied in this reaction system in generation of a small library of title compounds.     

改性Y型分子筛对硫醇硫醚的吸附脱除研究

通过液相离子交换法制备了Cu(I)Y、Ni Y、Ce Y分子筛,以XRD、低温N2吸附-脱附、NH3-TPD、吡啶红外Py-FTIR等方法对其进行物性表征。利用固定床技术、WK-2D微库伦仪及硫化学发光检测GC-SCD色谱评价了改性分子筛对于硫含量300μg/g模拟油(含硫化合物二丙硫醚、环己硫醇和1-庚硫醇与壬烷配制)及HDS汽油的吸附脱硫性能。结果表明,吸附剂对模拟油和HDS燃料油品中硫醇硫醚具有吸附效果,且改性后的分子筛在吸附脱硫过程中,强的B酸对于吸附脱硫有负作用,会使油品中硫醇硫醚发生催化反应,聚合的大分子硫化物遮盖及阻塞吸附活性位点,从而使吸附剂不能够完全地吸附硫化物,造成吸附硫容较小,而弱L酸无催化活性对吸附脱硫有正面影响。     

A novel soluble polyamide containing xanthene structure and trifluoromethylphenoxy pendent

<正>A novel polyamide containing xanthene structure and trifluoromethylphenoxy pendent was prepared from 9,9-bis[4-(4- aminophenoxy)phenyl]xanthene,a novel diamine with 2-(4-trifluoromethylphenoxy)terephthaloyl chloride,by the low temperature polycondensation.This new polyamide with the inherent viscosity of 0.95 dL/g was amorphous and readily soluble in polar solvents such as DMAc,m-cresol,etc.This polyamide showed the glass transition temperature(T_g) of 236℃,decomposition temperature (Td) at 5%weight loss of 455℃and char yield of 56%at 800℃in N_2.Transparent,flexible,and tough film of the polymer cast from DMAc solution exhibited tensile strength of 93 MPa,elongation at break of 14%,initial moduli of 2.2 GPa.The electric properties such as the dielectric constant of 3.03(1 MHz) and surface resistance(2.78×10~(14)Ω),and the moisture uptake of 1.36% were also described.     

Grüss-type bounds for covariances and the notion of quadrant dependence in expectation

We show that Grüss-type probabilistic inequalities for covariances can be considerably sharpened when the underlying random variables are quadrant dependent in expectation (QDE). The herein established covariance bounds not only sharpen the classical Grüss inequality but also improve upon recently derived Grüss-type bounds under the assumption of quadrant dependency (QD), which is stronger than QDE. We illustrate our general results with examples based on specially devised bivariate distributions that are QDE but not QD. Such results play important roles in decision making under uncertainty, and particularly in areas such as economics, finance, and insurance.     

螺旋管内高压汽水两相流动沸腾干涸点的研究

在较宽的实验参数范围内(系统压力P=8～15 MPa,质量流速G=800～1800 kg·m~(-2)·s~(-1),壁面热流密度q_w=200～950 kW·m~(-2))对一立式螺旋管内(管内径为10 mm,螺旋直径为300 mm,节距为50 mm)汽水两相流动沸腾干涸特性进行了实验研究。通过研究,获得了干涸发生时螺旋管圈壁温的分布特征以及压力、质量流速和壁面热流密度这三个参数对临界干度的影响规律。同时在实验数据的基础上,提出了一个适用于计算螺旋管内高压高含汽率工况下汽水两相流临界干度的经验关系式。     

半透明介质相变中的辐射变物性问题

半透明介质相变传热在许多工程领域引起关注,其实质是变物性条件下伴随相变的辐射-导热瞬态耦合传热问题,其难点在于相变过程中的辐射变物性问题,尤其是折射率的时空演变问题.本文首次研究相变过程中的变折射率问题.假设相变介质存在固相-糊状-液相区,固/糊界面、液/糊界面假定为半透明漫反射.采用多层辐射传递模型模拟相变介质内的辐...     

(±)-二氢猕猴桃内酯的合成研究(Ⅱ)

以柠檬醛为原料，经环化、羟腈化、水解关环和脱水４步反应，以３１４％的总产率合成了（±）－二氢猕猴桃内酯