硅(100)非重构表面上乙炔吸附反应的理论研究

采用量于力学AM1半经验分子理论轨道方法计算了在Si(100)非重构光滑附氢表面上乙炔化学吸附反应过程中的体系生成热,由此得到各步骤反应的活化焓和反应热数值.结果表明,乙炔分子容易在Si(100)表面上形成稳定的双位σ键吸附.     

Fabrication and characterization of magnetic ferrofluids by the co-precipitation way using diglycolic acid

Developing of a simple method for the fabrication of superparamagnetic iron oxide nanoparticles (Nps) is still a challenge for materials scientists. This work reveals a way to fabricate especially stable ferrofluids from spherical Nps of magnetite using the co-precipitation method, for which a new (diglycolic acid) stabilizer was applied. The Nps of the average size of ~7.4–16.5 nm were characterized by means of high resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), selective area electron diffraction (SAED), Raman, FTIR and Mössbauer spectroscopy. The stabilization effect of the diglycolic acid for the growth of superparamagnetic Nps growth was discussed on the basis of experimental results.     

Study on the shock absorbing technique of high speed railway bridges

Based on the idea of "bearing function separation", a structural member called shock absorber that makes use of its plastic deformation is presented for reducing the seismic response of the bridge. The design criterion for matching material stress, strain and earthquake fortification aim, is also given. The analysis results show that the high speed railway box girder with the absorber in this paper has great reduction effect in seismic response of the bridge piers.     

Three New Apianen lactones Compounds from Dioscorea Cirrhosa Lour

Dioscorea Cirrhosa Laour. which is a species of the Dioscorea, grows abundantly in southern and eastern China. Its roots are used in Chinese medicine as a remedy for various diseases, especially use for tumours and cancers. These results have prompted a search for its chemical constituents. Continuing out previous work,further studies on the constituents of the drug yielded three new compounds along with three known compounds in the EtOAc Fr of EtOH extraction.     

项目教学法在环境影响评价中的应用探讨

本文针对环境影响评价综合性强、实践性强的特点,在对项目教学法进行研究讨论的基础上,提出了适合环境影响评价教学的具体操作方法,旨在使学生的学习由被动变为主动,从而提高学生分析问题和解决问题的能力。     

Double Modification of Electrode Surface for the Selective Detection of Epinephrine and Its Application to Flow Injection Amperometric Analysis

A glassy carbon electrode having two polymer layers has been applied to selectively detect epinephrine. The inner layer formed by electropolymerization of macrocyclic nickel complex functioned as an electrocatalyst for epinephrine oxidation and the outer layer composed of hydrolyzed polyurethane γ‐benzyl L ‐glutamate as a screening layer. Differential pulse voltammetry showed almost 100% recovery of epinephrine even in 100‐fold excess of interferents. When applied to a dual glassy carbon electrode as an amperometric detector in flow injection analysis, a linear response over 0.1 μM and 10 μM was obtained. Recovery tested for 5‐fold diluted human urine samples was 97.5%.     

柱萃取色谱法分离铽和镝的研究

本文应用CL—P507革淋树脂作为萃取色谱柱填充料,进行希土元素Tb和Dy分离的研究.研究了淋洗酸度、温度、流速、希土负载量等因素对Tb-Dy离的影响.     

Photoluminescence kinetics of wurtzite GaN quantum dots in an AlN matrix

The photoluminescence (PL) of GaN quantum dots in an AlN matrix is studied. It is found that the maximum of the PL line does not shift when the laser excitation power varies. The transient PL spectra indicate that the quenching kinetics is nonexponential and the quenching law depends on the spectral range. The experimental data are explained in the framework of a model taking into account the strong built-in electric field in wurtzite structures and the transport of charge carriers between them.     

A monotonicity property of the composition of regularized and inverted-regularized gamma functions with applications

The gamma function and its various modifications such as the (upper) incomplete, regularized and inverted-regularized incomplete gamma functions are of importance in both theory and applications. In this note we observe an ‘if and only if ’ relationship between a certain axiom of insurance risk management and a monotonicity property of the composition of regularized and inverted-regularized incomplete gamma functions, assuming that the risks follow gamma distributions. We derive the monotonicity property by utilizing the above noted relationship and a probabilistic technique. The aforementioned insurance axiom, called consistent no-undercut, is explained in detail and related to several techniques of analysis.