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51.
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A new electroactive polynuclear inorganic compound of rare earth metal, gadolinium hexacyanoferrate (GdHCF), was prepared and characterized using the techniques of FTIR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectrometry, X-ray photoelectron spectroscopy (XPS), ICP atomic emission spectroscopy, and EDX. The results of ICP atomic emission spectroscopy, EDX, and TGA indicated that the prepared GdHCF sample had a stoichiometry of NaGdFe(CN)6·12H2O (when GdHCF was prepared in NaCl solution). The FTIR spectrum of GdHCF showed that there were two types of water molecules in the structure of GdHCF: one was the interstitial water (5 H2O), which resulted from the association of water due to H-bonding, and the other was water coordinated with Gd (7 H2O). The results obtained using XPS showed that the oxidation state of Fe and Gd in the GdHCF sample was +2 and +3, respectively. GdHCF was immobilized on the surface of spectroscopically pure graphite (SG) electrode forming the GdHCF/SG electrode, and the solid-state electrochemistry of the resultant electrode was studied using cyclic voltammetry. The cyclic voltammetric results indicated that the GdHCF/SG electrode exhibited a pair of well-defined and stable redox peaks with the formal potential of E0′=(197±3) mV. The effects of the concentration of the supporting electrolyte on the electrochemical characteristics of GdHCF were studied, and the results showed that the value of E0′ increased linearly with the activity of the cationic ion of the supporting electrolyte (lgaNa+), with a slope of 54.1 mV, which may become a novel method for determining the activity of Na+ in solution. Further experimental results indicated that GdHCF had electrocatalytic activities toward the oxidation of dopamine (DA) and ascorbic acid (AA), and the electrocatalytic current increased linearly with the concentration of DA (or AA) in the range of 1.0–10.0 mmol·L?1 (for DA) or 0.5–20.0 mmol·L?1 (for AA). 相似文献
53.
在分析微型热管的功能、技术要求及其加工工艺的基础上,设计了微型热管犁削-拔拉用成型刀具和系列模具.该刀具可使定位装夹方便,加工的热管直径尺寸稳定;模具保证了热管的外径尺寸并可方便地根据要求改变外径尺寸,热管外表面质量好,内部具有更加优良的毛细结构.刀具采用高速钢,模具采用45钢. 相似文献
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Zi‐Niu Wu 《国际流体数值方法杂志》2005,48(5):541-564
The widely used locally adaptive Cartesian grid methods involve a series of abruptly refined interfaces. In this paper we consider the influence of the refined interfaces on the steady state errors for second‐order three‐point difference approximations of flow equations. Since the various characteristic components of the Euler equations should behave similarly on such grids with regard to refinement‐induced errors, it is sufficient enough to conduct the analysis on a scalar model problem. The error we consider is a global error, different to local truncation error, and reflects the interaction between multiple interfaces. The steady state error will be compared to the errors on smooth refinement grids and on uniform grids. The conclusion seems to support the numerical findings of Yamaleev and Carpenter (J. Comput. Phys. 2002; 181: 280–316) that refinement does not necessarily reduce the numerical error. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
56.
以电脑刺绣机原始针杆机构和挑线机构为研究对象,在保持原有针杆运动规律和挑线杆运动规律的前提下,运用机构创新设计理论,分析电脑刺绣机针杆机构和挑线机构的可能选型.为研制新型电脑刺绣机针杆机构和挑线机构奠定了理论基础. 相似文献
57.
《高等数学》是大学中重要课程,笔者把洛必达法则在教学中遇到的问题给一个阐述,同时对洛必达法则重点!难点给出举例说明。 相似文献
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以一维有缺陷混凝土板为研究对象,分别采用Leverberg-Marcluardt和径向基神经网络算法,对缺陷的深度与厚度进行识别,从而实现对混凝土板内部缺陷的三维重构,称为红外CT模拟.两类神经网络算法的识别结果表明:Leverberg-Marcluardt神经网络较径向基神经网络具有更好的收敛精度与计算效率. 相似文献
60.