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71.
运用全站仪放样及对边测量功能,在已知控制点上设站,方便、快捷、精确的进行线路的纵、横断面测量。 相似文献
72.
本文报道热丝化学气相沉积法(HFCVD)生长金钢石薄膜的喇曼散射结果。选取多种峰型,对金钢石薄膜喇曼谱(110-1800cm-1)采用最小二乘法进行非线性拟合,得到最佳拟合模型,其计算得到的拟合曲线怀实验谱图符合得较好。该模型揭示,石墨D峰(1355cm-1)是金刚石薄膜喇曼谱中不可缺少的一个组份,并且结合石墨D峰和金刚石喇曼的空间相关线型,可以解释金刚石喇曼区特殊峰形的物理机制,拟合参量的进一步 相似文献
73.
The Hamiltonian formulation of the usual complex quantum mechanics in the theory of generalized quantum dynamics is discussed.
After the total trace Lagrangian, total trace Hamiltonian and two kinds of Poisson brackets are introduced, both the equations
of motion of some total trace functionals which are expressed by total trace Poisson brackets and the equations of motion
of some operators which are expressed by the without-total-trace Poisson brackets are obtained. Then a set of basic equations
of motion of the usual complex quantum mechanics are obtained, which are also expressed by the Poisson brackets and total
trace Hamiltonian in the generalized quantum dynamics. The set of equations of motion are consistent with the corresponding
Heisenberg equations.
Project supported by Prof. T.D. Lee’s NNSC Grant, the National Natural Science Foundation of China, the Foundation of Ph.
D. Directing Programme of Chinese University, and the Chinese Academy of Sciences. 相似文献
74.
以2-(3,4-环己基类二氧-5-异丙基)苯基乙醇(2)和3-异丙氧基-5,5-二甲基-1,3-环己烯酮(4)为原料,利用羰基α-位的烷基化反应和分子内的Friedel-Carfts反应为关键步骤,经9步反应,合成了多氧芳香型三环二萜类天然产物Salvinolone。 相似文献
75.
电镀烧结法制备Ti/SnO2-Sb2O4电极的研究 总被引:1,自引:0,他引:1
The Ti/SnO2-Sb2O4 electrode has been prepared by the electroplate-sinter method. The effect of SbCl3 adding amount and sintering temperature on its electrode lifetime and oxygen evolution potential were investigated by means of EDX, SEM and XRD analysis. The results indicated that the electrode appeared the best performance when the SbCl3 adding amounts was 0.2g and the sintering temperature was 550℃. In optimized conditions Ti substrate was entirely covered by SnO2-Sb2O4 and the combinations among them were tight. Due to the use of electroplate method, the electrical conductivity, the oxygen evolution potential and the electrode lifetime were increased, so the elec-tro-catalytic activity and the electrochemical stability of the prepared electrode were found to be superior. 相似文献
76.
77.
78.
Jun Fan Wei‐Guang Zhang Min‐Yu Tan Yu Tang Wei‐Sheng Liu Ning Tang Kai‐Bei Yu 《中国化学》2004,22(6):508-511
The La(III) complex with a new amide‐type tripodal ligand,2,2′.2″‐nitrilotris{[(2′‐benzylaminofomyl)‐phenoxylethyl)amine (L), was synthesized and characterized by X‐ray crystallographic analysis. Crystal data: C48H55.50LaN7O18.75, Mr=1169.40, monoclinic. space group, P21/n, a= 1.0644(3) nm. b=2.3889(5) nm, c= 2.1917(5) nm, β=90.65°, V=5.573(2) nm3, Z=1, Dc=1.394 g°cm?3, R1=0.0487, wR [1>2s?(I)]=0.1266. The results reveal that each La(III) ion binds to 9 oxygen atoms, three of which belong to carbonyl groups from three tripodal ligands and six to three bidentate nitrate groups and a two‐dimensional sheet of 4.82 networks is assembled by metal‐ligand coordination interaction. L, a heptadentate compound, merely acts as a tridentate bridging spacer due to its steric hindrance and links the La(III) ions as three‐connected nodes. 相似文献
79.
有机化合物在光窗上的结焦严重地影响激光引发化学反应及光学原位实时探测。本文报道在1,2-二氯丙烷反应系统中,光窗结焦现象同时存在于激光引发反应及热反应过程中,对光窗在300℃条件 下的结焦机理研究表明,少量氧气在光窗结焦过程中起关键作用。结焦前驱体的红外光谱研究表明,前驱体的可能结构为1-丙炔-1,3-二醇的缩聚体。该化合物极易通过缩聚反应形成更大的分子,最终导致光 窗结焦。对系统及反应物进行彻底除氧,光窗结焦现象大为改善。 相似文献
80.
Zhang YL Qin WW Liu WS Tan MY Tang N 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(10):2153-2157
An amide-based open-chain crown ether ligand and its complexes with europium and terbium were synthesized. The complexes were characterized by elemental analysis, infrared spectra and conductivity. The europium and terbium ions were found to coordinate to the C=O oxygen atoms and pyridine nitrogen atoms. The fluorescence properties of these complexes in DMF and CH3OH/CHCl3 were studied. Under the excitation of UV light, these complexes exhibit characteristic fluorescence of europium and terbium ions. The solvent factors influencing the fluorescent intensity are discussed. 相似文献