医用加速器二极磁铁的非单一工作模式电源控制器设计

近年来,离子治疗技术在国内外发展迅速.为满足加速器调试和不同治疗方案对医用回旋加速器装置的不同束流能量要求,二极磁铁电源要求工作在可相互切换的直流、有序触发和周期脉冲三种模式.使用中国科学院近代物理研究所自主研发的集成盒装式控制器,实现了对电源的控制和保护功能.为了适应调试和治疗两种不同场合的需求,控制器还支持本地和远...     

聚丙烯酸芴酯的电化学氧化交联反应及其表征

合成了侧链带有芴的聚丙烯酸芴酯(PFM),在含40%三氟化硼乙醚的二氯甲烷混合电解质溶液中,直接阳极氧化PFM获得了自支撑交联网状的聚(聚丙烯酸芴酯)(CPFM)薄膜.通过UV-Vis、FTIR和1H-NMR对CPFM结构进行了表征.荧光光谱表明得到的聚合物薄膜CPFM在415nm附近处具有强的荧光发射峰,表明聚丙烯酸结构的引入没有影响聚芴的蓝色发光性能并有利于提高聚合物薄膜的力学性能.TGA表明得到的CPFM薄膜具有良好的热稳定性。     

链霉菌M1033葡萄糖异构酶的分离纯化及其性质的研究

链霉菌M1033菌株所产的葡萄糖异构酶培养液经二级(NH_4)_2SO_4沉淀、DEAE-Sephadex A50,Sephadex-G150柱层析分离纯化,可得到电泳均一的纯酶。该酶的全分子量为91000左右,由两个相同的亚基组成。其pI为4.3,经糖染色后证明并非糖蛋白;最适反应温度70℃,在该温度下分别以D-木糖和D-葡萄糖为底物,测得最适pH分别为8.0和8.3。该酶为金属激活酶。Co~(2 )和Mg~(2 )对该酶有激活作用,Ca~(2 )则使之几乎失活。金属离子的激活作用随底物而异。动力学研究表明,该酶对D-木糖有更大的亲和性。     

超滤法处理脱毛废水

本文介绍了用聚砜（ＰＳ）和聚氯乙烯（ＰＶＣ）超过滤膜对灰矸脱毛废水进行超滤处理。试验结果表明，超过滤技术对灰矸脱毛废水的处理提供了有效方法。     

气提浓缩仪分析水中痕量挥发性有机物研究

本文描述了气提浓缩仪的设计及操作程序用于对水中痕量挥发性有机物的测定。分析物被气提吸附于TenaxGC柱上,然后直接脱附到毛细管气相色谱柱上进行分析,并用FID或MS鉴定。本文除对色谱条件进行优化外,对气提时间和脱附温度等分析操作条件也进行了研究。检测下限为0.01-0.30PPb,峰面积检测精度优于6.9％,对16种化合物的回收率优于74％。     

矿区活动断裂空间形态EH4探测

为了查明地质动力区划确定的活动断裂的存在与地下分布状态对煤与瓦斯突出的影响,利用质动力区划方法对鹤岗兴安井田区域内活动断裂进行划分,建立了板块构造学和矿井工程实际的联系。通过野外考察选取了对兴安矿煤与瓦斯突出影响严重的Ⅲ-1和Ⅳ-3活动断裂为研究对象,进行EH4电导率剖面测量,最终确定了两条活动断裂的空间分布状态。研究表明活动断裂控制着煤与瓦斯突出的区域性分布,EH4活动断裂电导率测量提供了活动构造探测新方法,对矿井动力灾害危险性预测和井下开采具有指导意义,可以在矿井实际工程中应用推广。     

Dual nanocatalysts co-decorated three-dimensional,laser-induced graphene hybrid nanomaterials integrated with a smartphone portable electrochemical system for point-of-care non-enzymatic glucose diagnosis

Non-enzymatic biosensors based on various nanomaterials with large surface-volume ratios and high catalytic efficiencies have been proposed to compensate for the non-stability and high cost of enzymatic biosensors. However, the construction of a stable, highly sensitive, flexible, three-dimensional (3D), microstructured, non-enzymatic biosensor integrated with a smartphone-based portable system has been challenging. Herein, highly conductive laser-induced graphene (LIG) array with a honeycomb-like 3D microstructure co-decorated with copper(I) oxide and gold nanocatalysts was developed via simple and green electro-deposition and chemical reduction approaches for a miniaturized electrochemical flexible non-enzymatic biosensor. SEM, XRD, Raman and XPS analyzations indicated that the Cu₂O and Au nanocatalysts co-decorated three-dimensional, laser-induced graphene hybrid nanomaterials were developed successfully. The signal of the biosensor was improved by more than 10 fold compared to the LIG alone due to the co-decorated with copper(I) oxide and gold nanocatalysts. The fabricated electrochemical biochip was integrated with a smartphone-based microstation for glucose monitoring, presenting a larger linear interval of 1–20 mM with an excellent sensitivity of 236 μA/mM/cm² and a relatively low detection limit of 0.31 μM. Noticeably, the biochip could measure blood sugar on curved surfaces and still deliver stable sensing signals after being bent back-and-forth 25 times. The novel biosensor is a potentially valuable flexible electronic device. The hybrid nanomaterials developed in this work may be applicable to other biosensing, catalytic, and energy devices (supercapacitors and batteries).     

Polyaddition of Azide‐Containing Norbornene‐Based Monomer through Strain‐Promoted 1,3‐Dipolar Cycloaddition Reaction

The azide–alkyne “click” reaction has been well known in the past decade, however, another kind of 1,3‐dipolar cycloaddition, the azide–alkene reaction is not fully explored in polymer science to date. This contribution reports, for the first time, the discovery of a polyaddition of norbornene based monomer (NC11N₃) containing both strained double bond and azide moieties. The reaction product is characterized by Fourier transform infrared spectroscopy (FTIR), NMR, gel permeation chromatography (GPC), and mass spectrometry (MS), which confirmed the mechanism that is through cycloaddition of azide to strained double bond on norbornene ring to form triazoline linkage. The reaction can proceed at room temperature as indicated by the increase of molecular weight and viscosity during storage. Monomer, dimer, trimer, tetramer, etc., and species with loss of N₂ due to lability of triazoline moiety are identified in the mixture of reaction product. As a unique feature, elimination of N₂ in the five‐membered ring of triazoline affords a chance to form highly reactive materials, such as with aziridine, which can be a very powerful tool in chemical functionalizations, and find promising applications in reactive polymer resin industries.

     

Uniform decay rates for nonlinear viscoelastic Marguerre-von Kármán equations

In this paper, we consider a model of nonlinear viscoelastic shallow shell that is referred to as the full Marguerre-von Kármán under the presence of long-time memory. We show that the energy functional associated with the system decays exponentially to zero as time goes to infinity.