首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   23911篇
  免费   2969篇
  国内免费   2688篇
化学   11306篇
晶体学   172篇
力学   882篇
综合类   151篇
数学   1907篇
物理学   5961篇
综合类   9189篇
  2024年   93篇
  2023年   425篇
  2022年   768篇
  2021年   844篇
  2020年   776篇
  2019年   804篇
  2018年   654篇
  2017年   661篇
  2016年   924篇
  2015年   1059篇
  2014年   1352篇
  2013年   1572篇
  2012年   1819篇
  2011年   1831篇
  2010年   1396篇
  2009年   1478篇
  2008年   1512篇
  2007年   1363篇
  2006年   1203篇
  2005年   1071篇
  2004年   849篇
  2003年   730篇
  2002年   828篇
  2001年   686篇
  2000年   578篇
  1999年   664篇
  1998年   501篇
  1997年   456篇
  1996年   424篇
  1995年   352篇
  1994年   319篇
  1993年   286篇
  1992年   206篇
  1991年   228篇
  1990年   195篇
  1989年   165篇
  1988年   158篇
  1987年   86篇
  1986年   60篇
  1985年   53篇
  1984年   32篇
  1983年   20篇
  1982年   25篇
  1981年   11篇
  1979年   7篇
  1978年   6篇
  1977年   5篇
  1976年   4篇
  1972年   4篇
  1957年   3篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
191.
Introduction A welded structure must be inspected to guarantee that the weld quality meets the design requirements to as- sure safety and reliability. However, X-ray image analyses and defect recognition are very complex. Most difficulties lie in finding …  相似文献   
192.
Thymus immunosuppressive pentapeptide (TIPP) is a novel anti-inflammatory peptide with high efficacy and low toxicity. This study aims to establish a selective LC-MS/MS method for analyzing the analyte TIPP in biological samples, laying the foundation for further PK and PD studies of TIPP. Protein precipitation was conducted in acetonitrile supplemented with 2% formic acid and 25 mg/mL dithiothreitol as a stabilizer, which was followed by backwashing the organic phase using dichloromethane. The chromatographic separation of TIPP was achieved on a C18 column with a gradient elution method. During positive electrospray ionization, TIPP was analyzed via multiple-reaction monitoring. The linear relationships between the concentration of TIPP and peak area in murine plasma cell lysates, supernatants, and the final cell rinse PBS were established within the ranges of 20–5000 ng/mL, 1–200 ng/mL, 10–200 μg/mL, and 0.1–20 ng/mL, respectively (r2 > 0.99). Validated according to U.S. FDA guidelines, the proposed method was proved to be acceptable. Such a method had been successfully applied to investigate the pharmacokinetics of TIPP in mice via subcutaneous injection. The plasma half-life in mice was 5.987 ± 1.824 min, suggesting that TIPP is swiftly eliminated in vivo. The amount of TIPP uptake by RBL-2H3 cells was determined using this method, which was also visually verified by confocal. Furthermore, the effective intracellular concentration of TIPP was deduced by comparing the intracellular concentration of TIPP and degrees of inflammation, enlightening further investigation on the intracellular target and mechanism of TIPP.  相似文献   
193.
对苏步青教授在文[1]中介绍的改良后的Hurwitz方法再作一些改进,先对Wirtinger引理进行推广,再用推广后的Wirtinger不等式很自然而简洁地推出了等周不等式.  相似文献   
194.
主要研究了Hilbert空间H上全体幂等算子关于左星序的性质, 其中左星序(left-star order)A*≤B定义为A*A=A*B且R(A)⊆R(B)。设A和B是幂等算子, 给出了A*≤B的等价条件和算子矩阵形式表示。同时, 当A*≤B时, 讨论了星序的上、下确界A∧B和A∨B的存在性及其表示。  相似文献   
195.
We systematically measure the superconducting(SC) and mixed state properties of high-quality CsV_3 Sb_5 single crystals with T_c~3.5 K.We find that the upper critical field H_(c2)(T) exhibits a large anisotropic ratio of H_(c2)~(ab)/H_(c2)~c~9 at zero temperature and fitting its temperature dependence requires a minimum two-band effective model.Moreover,the ratio of the lower critical field,H_(c1)~(ab)/H_(c1)~c,is also found to be larger than 1,which indicates that the in-plane energy dispersion is strongly renormalized near Fermi energy.Both H_(c1)(T) and SC diamagnetic signal are found to change little initially below T_c~3.5 K and then to increase abruptly upon cooling to a characteristic temperature of ~2.8 K.Furthermore,we identify a two-fold anisotropy of in-plane angular-dependent magnetoresistance in the mixed state.Interestingly,we find that,below the same characteristic T~2.8 K,the orientation of this two-fold anisotropy displays a peculiar twist by an angle of 60° characteristic of the Kagome geometry.Our results suggest an intriguing superconducting state emerging in the complex environment of Kagome lattice,which,at least,is partially driven by electron-electron correlation.  相似文献   
196.
197.
Coordination hosts based on flexible ligands have received increasing attention due to their inherent adaptive cavities that often show induced-fit guest binding and catalysis like enzymes. Herein, we report the controlled self-assembly of a series of homo/heterometallic coordination hosts (Me4enPd)2n(ML)n [n = 2/3; M = Zn(ii)/Co(ii)/Ni(ii)/Cu(ii)/Pd(ii)/Ag(i); Me4en: N,N,N′,N′-tetramethylethylenediamine] with different shapes (tube/cage) from a flexible tetraazacyclododecane-based pyridinyl ligand (L) and cis-blocking Me4enPd(ii) units. While the Ag(i)-metalated ligand (AgL) gave rise to the formation of a (Me4enPd)4(ML)2-type cage, all other M(ii) ions led to isostructural (Me4enPd)6(ML)3-type tubular complexes. Structural transformations between cages and tubes could be realized through transmetalation of the ligand. The buffering effect on the ML panels endows the coordination tubes with remarkable acid–base resistance, which makes the (Me4enPd)6(ZnL)3 host an effective catalyst for the CO2 to CO32− conversion. Control experiments suggested that the integration of multiple active Zn(ii) sites on the tubular host and the perfect geometry match between CO32− and the cavity synergistically promoted such a conversion. Our results provide an important strategy for the design of adaptive coordination hosts to achieve efficient carbon fixation.

A series of coordination hosts were prepared and their applications in CO2 fixation were studied.  相似文献   
198.
幽默是文学的一种表现形式,其产生的原因有很多。合作原则是语用学的重要原则之一,很多幽默的产生源于对合作原则的违反。文章从语用学角度,通过大量实例,探讨违反合作原则产生的幽默效果。  相似文献   
199.
通用多边形覆盖算法及图形分解软件袁为民(南洋信息与控制工程公司)关键词算法,多边形覆盖,掩膜图形分解中留法分类号TP3171文献回顾和算法简述针对集成工艺中所涉及的掩膜图形的多样性和复杂性,本文提出一种通用性较强的多边形覆盖算法,并已实现为图形分解软...  相似文献   
200.
面向网格简化的STL拓扑信息快速重建算法   总被引:10,自引:0,他引:10  
以STL模型为研究对象,针对网格简化要求的显式、完整拓扑关系,提出了一种快速构建拓扑信息的新算法.在优化选取拓扑信息构建顺序的基础上,一方面针对各种几何元素的特点选取有效的数据结构,在数据组织层次上保证顶点归并的效率和几何元素的检索效率;另一方面,充分利用顶点与其邻接点和邻接面的关系,将边归并的比较范围控制在顶点的邻域,并在全局遍历时选择数据规模最小的顶点.算法具备优良的时间效率性,提高了网格简化预处理的效率.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号