An alternative multipolar expansion for intermolecular potential functions

We have derived a new multipolar expansion for intermolecular potential-energy functions with applications in molecular physics, theoretical chemistry, and mathematical physics. The new formulation employs a separation of radial and angular terms with a simple index structure that leads to computational efficiency and ease of physical interpretation. For the case of the Coulomb interaction, we compare the present formulation with two conventional multipole expansions: the Cartesian tensor and the irreducible spherical tensor expansions. The new formalism leads to efficient numerical algorithms that are useful for general applications beyond intermolecular potentials. In addition to the electrostatic Coulomb interaction, we illustrate the formalism with applications to special function theory and a bipolar expansion involved in potential theory.     

Fullerenes-extracted soot: a new adsorbent for collecting volatile organic compounds in ambient air

Fullerenes-extracted soot (FES) is the by-product of fullerenes production. Retention characteristics at different temperatures for 17 volatile organic compounds (VOCs) on FES are measured. The adsorption and desorption efficiencies for VOCs on FES adsorbent tubes range from 40.8 to 117%, most of them being 100+/-20%. The values are compared with Tenax GR, an adsorbent commonly used in environmental analysis. FES can be used as an adsorbent of low cost to collect VOCs in environmental samples.     

A potent and highly selective sulfotransferase inhibitor

In the present work, we have used a newly developed, fluorescence-based assay to screen a library of >30 000 compounds as potential beta-arylsulfotransferase-IV inhibitors. A total of 11 inhibitors were discovered. Most of the compounds discovered showed low micromolar inhibition, but one of the compounds showed potent inhibition (Ki = 96 nM). The most potent of these inhibitors was tested against a variety of other purine binding enzymes and showed remarkable specificity.     

Synthesis of a Mimicking Hybrid of Annonaceous Acetogenin with Steroid for Antitumoral Activity Investigation

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14‐Membered Cyclopeptides from Paliurus ramosissimus and P. hemsleyanus

Six 14‐membered cyclopeptide alkaloids, i.e., ramosines A–C, mucronine J, and lotusines A and D, were isolated from the roots of Paliurus ramosissimus, and an additional four, hemsines A–D, from the roots of P. hemsleyanus. Among these, ramosines A–C ( 1, 5 , and 6 , resp.) and hemsines A and B ( 7 and 8 , resp.) are new bases of the amphibine‐B type, and hemsines C and D ( 9 and 10 , resp.) are new integerrine‐type alkaloids. Additionally, ramosine C ( 6 ) represents the first 14‐membered cyclopeptide alkaloid possessing a substitution (? OH) at C(13′). Their structural elucidations were based on spectral analysis and molecular‐modeling studies. Pronounced solvent effects in the ¹H‐ and ¹³C‐NMR spectra of these two types of alkaloids were observed.     

沿海防护林优良适生树种造林效果研究

研究了沙质地沿海防护林优良适生树种木麻黄、湿地松和厚荚相思的生长特性及生态适应性。结果表明,立地类型与林分生长关系十分密切,泥炭性风积沙土最适宜这3个树种生长,水化性风积沙土和不均一性风积沙土相对不利于这3个树种生长。木麻黄、湿地松和厚荚相思在沿海沙质地的生长表现及对环境的适应性各有优劣,林木生长速度表现为厚荚相思最快,木麻黄次之,湿地松较慢;抗强风能力则是湿地松最好,木麻黄次之,厚荚相思较弱;海岸前沿耐潮湿海风能力表现为木麻黄最好,厚荚相思次之,湿地松较差。木麻黄目前仍然是沿海防护林海岸前沿不可替代的造林树种,湿地松抗风能力最强,而厚荚相思最能适应沿海沙质地干旱瘠薄的恶劣立地条件且生长迅速,对土壤改良效果良好。     

IMI及其微生物转化产物5-hydroxy IMI的HPLC分析

研究了烟碱类杀虫剂IMI及其微生物转化产物5-hydroxy IMI的反相高效液相色谱分析方法．采用Zorbox OSD反相柱，水和乙腈（75：25）（v／v）为流动相，流速为1mL／min，检测波长为269nm，IMI和5-hydroxy IMI得到较优分离．在0．5～50mg／L的浓度范围内，两种物质的色谱峰面积和浓度之间呈线性关系，IMI和5-hydroxy IMI的标准工作曲线分别为y=112．23x-1．7775和y=98．039x-17．508；相关系数为0．9999和0．9997．转化产物的样品中IMI和5-hydroxy IMI添加的回收率分别为99．3％和97．4％．     

建设企业信息门户的技术与实现

提出建设企业信息门户的技术方案，说明了WEB数据库应用方法争系统功能，并提出了门户站点安全性部署管理方法。     

一种结构紧凑的新型微带单脉冲天线阵

该文提出了一种新的“十”字型微带结构单脉冲天线和差网络。用这种网络成功地设计并加工了微带单脉冲阵列天线。这个天线阵由 4个 8× 8幅度为均匀分布的微带天线子阵组成。和差网络和天线阵处于同一平面 ,因而具有结构紧凑、简单 ,加工方便和成本低的优点。根据实测结果 ,水平方向的和方向图与差方向图均与理论预估吻合良好 ,表明和差网络的设计是成功的。如果天线阵的幅度分布按低副瓣设计 ,则也可以用在微带低副瓣天线阵上。分析和实测都表明 ,这种天线阵还具有比常规天线阵带宽更宽的优点。