Synthesis and characterization of white‐light‐emitting polyfluorenes containing orange phosphorescent moieties in the side chain

Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C^2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C^2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007     

甲醇催化脱氢制甲酸甲酯反应中Cu－ZnO－ZrO_2／SiO_2催化剂的特性

Ｃｕ－ＺｎＯ－ＺｒＯ２／ＳｉＯ２催化剂对甲醇催化脱氢制甲酸甲酯的反应具有良好的活性和选择性．应用连续微反、差示热分析、Ｘ射线衍射、程序升温还原、Ｘ射线光电子能谱分析和红外光谱等技术，对该催化剂的活性中心本质、ＺｎＯ及ＺｒＯ２的助催化作用、可能的反应机理以及催化剂的失活原因进行了探讨．     

一种快速余弦变换在心电图数据压缩中的应用

用离散余弦变换(DCT)的一种快速算法按“方差准则”实现心电图(ECG)数据压缩.这种算法减少了乘法次数且结构简单.采用分段变换的方法,能有效地进行心电图数据压缩.     

字节全加器及其在无线电测控系统中的应用

对全加器概念进行了推广，并在此基础上给出了使用字节全加器网络的无线电抗干扰算法。通过在实际的无线电测控系统中的应用，结果表明该算法具有良好的无线电抗干扰效果。     

狄拉克（Dirac）与当代物理学

从量子力学、真空、大数假说、磁单极子诸方面，阐述了坎拉克的治学思想和研究方法的特点及其对当代物理学所做出的重大贡献．     

灭滴灵治疗智齿冠周炎的临床观察

本文对１０００例智齿冠周炎的患者采用三种治疗方法．其中一种单独给予口服灭滴灵，一种给予肌注青霉素．另一种则采用灭滴灵十肌注青霉素治疗．结果显示：三种治疗方法的疗效无显著差异．而灭滴灵有口服方便，安全，副作用少之优点．     

否定毛细永动机的唯象理论

本文从毛细现象自身所满足的规律、弯曲液面所具有的性质着手，给出了一种否定毛细永动机的唯象理论。     

高新技术开发区网络管理系统的设计

根据高新技术产业开发区的特点，提出了一系列有针对性的软、硬件设计。