首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   38244篇
  免费   4856篇
  国内免费   4553篇
化学   18378篇
晶体学   279篇
力学   1221篇
综合类   308篇
数学   2645篇
物理学   9425篇
综合类   15397篇
  2024年   180篇
  2023年   676篇
  2022年   1075篇
  2021年   1252篇
  2020年   1200篇
  2019年   1106篇
  2018年   1059篇
  2017年   1004篇
  2016年   1493篇
  2015年   1653篇
  2014年   2076篇
  2013年   2509篇
  2012年   2841篇
  2011年   2917篇
  2010年   2278篇
  2009年   2372篇
  2008年   2528篇
  2007年   2324篇
  2006年   2124篇
  2005年   1871篇
  2004年   1467篇
  2003年   1335篇
  2002年   1461篇
  2001年   1231篇
  2000年   1118篇
  1999年   1058篇
  1998年   765篇
  1997年   732篇
  1996年   712篇
  1995年   559篇
  1994年   524篇
  1993年   398篇
  1992年   378篇
  1991年   278篇
  1990年   253篇
  1989年   233篇
  1988年   196篇
  1987年   123篇
  1986年   106篇
  1985年   71篇
  1984年   23篇
  1983年   27篇
  1982年   13篇
  1981年   11篇
  1980年   11篇
  1979年   4篇
  1975年   3篇
  1973年   4篇
  1957年   6篇
  1936年   3篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
A novel algorithm, alternatively minimizing coupled vector (COV) resolution error and PARAFAC error algorithm, is proposed in this paper. This algorithm can overcome the problem of slow convergence and is insensitive to the estimation of component number, such problems are unavoidable while using the traditional parallel factors analysis (PARAFAC) algorithm. In other words, this algorithm is capable of improving the computing speed and providing accurate resolutions provided that the number of factors used in the computation is no less than that of the actual underlying ones. The characteristic performances were demonstrated with a novel fluorescence data array.  相似文献   
52.
0 IntroductionDue to the success of Internet technology and the emer-gence of wide band network,downloading encoded dig-ital audiovisual content files via HTTP,FTP,etc ,had gainedfavor amongInternet users because of thei mmediate access todesired content . Digital Right Management (DRM) system,can satisfy the content provider by encrypting digital audiovi-sual content andli miting access to onlythose people who haveacquired a proper license to play backthe content[1].DRMas defined bythe …  相似文献   
53.
李燚 《长春师范学院学报》2003,22(2):142-142,F003
本文对某些高校任命非专业出身者为图书馆馆长的做法阐述了不同的看法,简述了存在问题的弊端及解决问题的对策,并提出了制定相关图书馆法的必要性。  相似文献   
54.
通过对长春市园林木本地被植物应用的调查研究表明,目前长春市园林绿化常见木本地被植物共有21种:其中,木质藤本地被植物有4种,隶属2科,3属;矮灌木地被植物有10种,隶属5科7属;整形木本地被植物有7种,隶属4科6属。本文介绍了木本地被植物的园林应用及生态型,并提出发展长春市园林地被植物的建议。  相似文献   
55.
56.
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007  相似文献   
57.
利用精炼的C语言进行程序设计,定量模拟狭义相结论的运动时钟变慢,并对处于两种不同时空观的时钟运行进行对比,使得时间膨胀效应变得直观。  相似文献   
58.
简要介绍了生命科学研究的新突破,包括人类嗅觉谜团被解开,激活自愈机能治疗肝炎,运用基因重组或剔除基因治疗癌症获重大进展等.  相似文献   
59.
60.
Two new phenyl‐ and naphthyl‐substituted rigid‐rod aromatic dicarboxylic acid monomers, 2,2′‐diphenylbiphenyl‐4,4′‐dicarboxylic acid ( 4 ) and 2,2′‐di(1‐naphthyl)biphenyl‐4,4′‐dicarboxylic acid ( 5 ), were synthesized by the Suzuki coupling reaction of 2,2′‐diiodobiphenyl‐4,4′‐dicarboxylic acid dimethyl ester with benzeneboronic acid and naphthaleneboronic acid, respectively, followed by alkaline hydrolysis of the ester groups. Four new polyhydrazides were prepared from the dicarboxylic acids 4 and 5 with terephthalic dihydrazide (TPH) and isophthalic dihydrazide (IPH), respectively, via the Yamazaki phosphorylation reaction. These polyhydrazides were amorphous and readily soluble in many organic solvents. Differential scanning calorimetry (DSC) indicated that these hydrazide polymers had glass transition temperatures in the range of 187–234 °C and could be thermally cyclodehydrated into the corresponding oxadiazole polymers in the range of 300–400 °C. The resulting poly(1,3,4‐oxadiazole)s exhibited Tg's in the range of 252–283 °C, 10% weight‐loss temperature in excess of 470 °C, and char yield at 800 °C in nitrogen higher than 54%. These organo‐soluble polyhydrazides and poly(1,3,4‐oxadiazole)s exhibited UV–Vis absorption maximum at 262–296 and 264–342 nm in NMP solution, and their photoluminescence spectra showed maximum bands around 414–445 and 404–453 nm, respectively, with quantum yield up to 38%. The electron‐transporting properties were examined by electrochemical methods. Cyclic voltammograms of the poly(1,3,4‐oxadiazole) films cast onto an indium‐tin oxide (ITO)‐coated glass substrate exhibited reversible reduction redox with Eonset at ?1.37 to ?1.57 V versus Ag/AgCl in dry N,N‐dimethylformamide solution. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6466–6483, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号