苯并18-冠-6配合物[K(B18-C-6)]SCN的合成与结构分析

苯并 18 -冠 - 6 (B18- C- 6 )与 K2 [Cd(SCN) 4 ]反应 ,得到了 [K(B18- C- 6 ) ]SCN配合物。通过元素分析、红外光谱、单晶 X射线衍射进行了结构分析。该配合物为单斜晶系 ,空间群 P2 (1) / c,晶体学数据 :a=0 .996 0(3) nm,b=2 .5 0 97(7) nm,c=0 .8374 (2 ) nm,β=10 6 .5 19(5 )°,V=2 .0 0 6 7(10 ) nm3 ,Z=4 ,F(0 0 0 ) =86 4,R1=0 .0 4 2 9,w R2 =0 .0 5 75。结构分析表明 ,该配合物由一个 [K(B18- C- 6 ) ]配阳离子和一个 SCN阴离子组成 ,配合物的两个分子通过 K+ - π相互作用形成一维链状结构     

改革物理实验课教学,提高实验课的教学质量

根据多年的物理实验教学经验，阐明了物理实验教学改革应重视的问题，并提出了几点改进措施。     

牛顿第二定律实验中的误差分析

本文是通过对加速度的实验值和理论值进行比较和分析，给出误差的合理范围。     

一类广义Liénard系统的正半轨线与特征曲线相交的条件

获得了广义Li啨ｎａｒｄ系统dxdt =p(y) -F(x) ,　 dydt =-g(x)q(y)过平面上任意一点的正半轨线与特征曲线p(y) =F(x)相交的充分条件 .     

同轴双无衍射光的理论与实验

提出同轴双无衍射光的概念。如果两束汇聚角略有不同的同轴无衍射光同时存在，则它们相互之间叠加干涉后产生一种纵向呈周期变化的光场结构，这是一种新的光束空间分布，这种光束在横向仍是一种同心环光斑，可用于精密对准。而在不同纵向位置，这些同心环的强度分布是不同的，且是周期性变化的。同轴双无衍射光的轴向周期性可用于沿光束传播方向的定位。文中提出了双环缝法、分段圆锥透镜法、正弦相位环光栅法等实现同轴双无衍射光的理论与实验方法，分析了同轴双无衍射光的横向与纵向传播的衍射光斑特性，理论计算与实验测量的结果基本相符合。     

良序套张量积的代数中的强不可约算子

设Ｈ为复的可分无限维Ｈｉｌｂｅｒｔ空间，称有界线性算子Ｔ为强不可约的，如果与Ｔ可交换的幂等算子只有０和Ｉ．王宗尧、蒋春澜、纪有清等人证明了在任何一个套的套代数中都存在大量的强不可约算子，并且找到了它们的酉轨道闭包．本文考虑有限个套的张量积的代数中强不可约算子的存在性问题。证明了：对复平面上任何一个连通完备集σ、总存在一个对角算子Ｎ和它的一个范数可以任意小的紧摄动Ｔ＝Ｘ＋Ｋ，使得Ｔ是一个强不可约算子、Ｔ在有限个良序套的张量积的代数中，并且σ（Ｔ）＝σｌｒｅ（Ｔ）＝σ（Ｎ）＝σｌｒｅ（Ｎ）＝σ进一步，文章还对具有单点谱的算子和良序套与正交补为良序套的张量积的代数进行了讨论，得到了一些结果．     

电磁相分离法制备自生表层复合材料

采用电磁相分离法制备出以初生富铁相（AlSiFeMn复杂金属间化合物）为增强相，表层硬度为HB62．25，基体硬度为HB59．00的Al-11.70%Si-1.20?-1.50%Mn合金自生表层复合材料，增强相的显微硬度为HV 842。87，大小为20－80μm，该表层复合材料同基体材料相比，耐磨性提高了57．41％，所用方法工艺过程简单，成本低，为解决材料在服役环境中不同部位，不同性能的问题提供了新途径。     

Synthesis and characterization of white‐light‐emitting polyfluorenes containing orange phosphorescent moieties in the side chain

Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C^2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C^2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007     

高温高密度Z-pinch等离子体自适应式平面丝阵负载制备技术研究

 在Z-pinch实验中，加速器两电极间距会因抽真空而发生改变从而导致平面丝阵负载的丝分布发生变化，为了解决这个问题，采用弹簧预压缩的方法，制备出了平面丝阵负载，经实验室模拟检测和物理实验的实际应用证明，平面丝阵负载不但能适应电极方向呈任何方向放置的靶室，还能自动适应靶室电极间距因抽真空而发生的变化。在实验过程中丝阵可以保持绷紧的状态，满足了物理实验的要求。     

Asymptotic distributions of nonparametric regression estimators for longitudinal or functional data

The estimation of a regression function by kernel method for longitudinal or functional data is considered. In the context of longitudinal data analysis, a random function typically represents a subject that is often observed at a small number of time points, while in the studies of functional data the random realization is usually measured on a dense grid. However, essentially the same methods can be applied to both sampling plans, as well as in a number of settings lying between them. In this paper general results are derived for the asymptotic distributions of real-valued functions with arguments which are functionals formed by weighted averages of longitudinal or functional data. Asymptotic distributions for the estimators of the mean and covariance functions obtained from noisy observations with the presence of within-subject correlation are studied. These asymptotic normality results are comparable to those standard rates obtained from independent data, which is illustrated in a simulation study. Besides, this paper discusses the conditions associated with sampling plans, which are required for the validity of local properties of kernel-based estimators for longitudinal or functional data.