全文获取类型
收费全文 | 77107篇 |
免费 | 9629篇 |
国内免费 | 6892篇 |
专业分类
化学 | 37312篇 |
晶体学 | 641篇 |
力学 | 3082篇 |
综合类 | 328篇 |
数学 | 5955篇 |
物理学 | 20039篇 |
综合类 | 26271篇 |
出版年
2024年 | 362篇 |
2023年 | 1441篇 |
2022年 | 2617篇 |
2021年 | 2788篇 |
2020年 | 2639篇 |
2019年 | 2318篇 |
2018年 | 2100篇 |
2017年 | 2115篇 |
2016年 | 2993篇 |
2015年 | 3342篇 |
2014年 | 4131篇 |
2013年 | 4956篇 |
2012年 | 5885篇 |
2011年 | 5833篇 |
2010年 | 4334篇 |
2009年 | 4252篇 |
2008年 | 4535篇 |
2007年 | 4152篇 |
2006年 | 3607篇 |
2005年 | 3175篇 |
2004年 | 2480篇 |
2003年 | 1941篇 |
2002年 | 1844篇 |
2001年 | 1560篇 |
2000年 | 1499篇 |
1999年 | 2095篇 |
1998年 | 1874篇 |
1997年 | 1853篇 |
1996年 | 1727篇 |
1995年 | 1494篇 |
1994年 | 1344篇 |
1993年 | 1180篇 |
1992年 | 940篇 |
1991年 | 934篇 |
1990年 | 767篇 |
1989年 | 633篇 |
1988年 | 529篇 |
1987年 | 369篇 |
1986年 | 275篇 |
1985年 | 174篇 |
1984年 | 96篇 |
1983年 | 98篇 |
1982年 | 57篇 |
1981年 | 40篇 |
1980年 | 33篇 |
1979年 | 20篇 |
1977年 | 19篇 |
1976年 | 20篇 |
1975年 | 21篇 |
1972年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
The Iyengar Type Inequalities with Exact Estimations and the Chebyshev Central Algorithms of Integrals 总被引:3,自引:0,他引:3
Xing Hua WANG Shi Jun YANG 《数学学报(英文版)》2005,21(6):1361-1376
In this paper, both low order and high order extensions of the Iyengar type inequality are obtained. Such extensions are the best possible in the same sense as that of the Iyengar inequality. hzrthermore, the Chebyshev central algorithms of integrals for some function classes and some related problems are also considered and investigated. 相似文献
52.
53.
证明了当超越亚纯函数的级小于1时,其Norel例外值最多只有一个.由于存在任何级的整函数,因此一个例外值总可达到,故所得结果不能再改进。 相似文献
54.
灾害的破坏程度不仅取决于地震能量(受控于现代构造应力场的特征),同时也受岩溶塌陷,采空区塌陷等其他灾害的影响,故采用人工神经网络模型评价灾害危险性。借助地理信息系统软件,计算了唐山市各居住小区的建筑密度和建筑容积率,结合灾害危险性评价结果。确定了从防灾角度考虑的土地开发强度评价指标。应用Maplnfo自带二次开发语言MapBasic及Visual Basic进行二次开发,炳述了二次开发的步骤和过程。依据系统评价结果,对唐山市的城市规划布局和土地利用方向提出了几点建议。 相似文献
55.
Fei Chang Dongheng Zhang Haijian Yang Haibin Song 《Journal of organometallic chemistry》2004,689(5):936-946
The synthesized 1-aryliminomethylenylnaphthalen-2-ol derivatives reacted with nickel chloride to form bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes. All resultant compounds were structurally characterized by elemental analyses, IR and H NMR, and the structures of the formed complexes were elucidated by X-ray crystal structure analysis. The complexes show high catalytic activities for the vinyl polymerization of norbornene in the presence of methylaluminoxane. The catalytic activity variations have been followed by gas chromatography through monitoring the conversion of norbornene. 相似文献
56.
学生学习知识,一般来说,是从生动的具体的直观开始的,生动的直观能使学生获得关于事物生动而具体的感性认识。但是,感性认识并没有揭露事物的本质,人们对事物本质的认识要通过一系列的抽象来完成。 相似文献
57.
Finding finer functions for partially characterized proteins by protein-protein interaction networks
LI YanHui GUO Zheng MA WenCai YANG Da WANG Dong ZHANG Min ZHU ding ZHONG GuoCai LI YongJin YAO Chen WANG Jing 《科学通报(英文版)》2007,52(24):3363-3370
Based on high-throughput data, numerous algorithms have been designed to find functions of novel proteins. However, the effectiveness of such algorithms is currently limited by some fundamental factors, including (1) the low a-priori probability of novel proteins participating in a detailed function; (2) the huge false data present in high-throughput datasets; (3) the incomplete data coverage of functional classes; (4) the abundant but heterogeneous negative samples for training the algorithms; and (5) the lack of detailed functional knowledge for training algorithms. Here, for partially characterized proteins, we suggest an approach to finding their finer functions based on protein interaction sub-networks or gene expression patterns, defined in function-specific subspaces. The proposed approach can lessen the above-mentioned problems by properly defining the prediction range and functionally filtering the noisy data, and thus can efficiently find proteins’ novel functions. For thousands of yeast and human proteins partially characterized, it is able to reliably find their finer functions (e.g., the translational functions) with more than 90% precision. The predicted finer functions are highly valuable both for guiding the follow-up wet-lab validation and for providing the necessary data for training algorithms to learn other proteins. 相似文献
58.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007 相似文献
59.
Chin‐Ping Yang Ruei‐Shin Chen Kuei‐Hung Chen 《Journal of polymer science. Part A, Polymer chemistry》2003,41(7):922-938
To investigate the position and amount of the CF3 group affecting the coloration of polyimides (PIs), we prepared 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]hexafluoropropane ( 2 ) with four CF3 groups with 2‐chloro‐5‐nitrobenzotrifluoride and 2,2‐bis(4‐hydroxyphenol)hexafluoropropane. A series of soluble and light‐colored fluorinated PIs ( 5 ) were synthesized from 2 and various aromatic dianhydrides ( 3a – 3f ). 5a – 5f had inherent viscosities ranging from 0.80 to 1.19 dL/g and were soluble in amide polar solvents and even in less polar solvents. The glass‐transition temperatures of 5 were 221–265 °C, and the 10% weight‐loss temperatures were above 493 °C. Their films had cutoff wavelengths between 343 and 390 nm, b* values (a yellowness index) ranging from 5 to 41, dielectric constants of 2.68–3.01 (1 MHz), and moisture absorptions of 0.03–0.29 wt %. In a comparison of the PI series 6 – 8 based on 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane, 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]propane, and 2,2‐bis[4‐(4‐aminophenoxy)phenyl]propane, we found that the CF3 group close to the imide group was more effective in lowering the color; this means that CF3 of 5 , 7 , and 8f was more effective than that of 6c . The color intensity of the four PI series was lowered in the following order: 5 > 7 > 6 > 8 . The PI 5f , synthesized from diamine 2 and 4,4′‐hexafluoroisopropylidenediphthalic anhydride, had six CF3 groups in a repeated segment, so it exhibited the lightest color among the four series. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 922–938, 2003 相似文献
60.
双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响. 相似文献