Independence of the brittle–ductile transition from the rubber particle size for impact‐modified poly(vinyl chloride)

A series of acrylic impact modifiers (AIMs) with different particle sizes ranging from 55.2 to 927.0 nm were synthesized by seeded emulsion polymerization, and the effect of the particle size on the brittle–ductile transition of impact‐modified poly(vinyl chloride) (PVC) was investigated. For each AIM, a series of PVC/AIM blends with compositions of 6, 8, 10, 12, and 15 phr AIM in 100 phr PVC were prepared, and the Izod impact strengths of these blends were tested at 23 °C. For AIMs with particle sizes of 55.2, 59.8, 125.2, 243.2, and 341.1 nm, the blends fractured in the brittle mode when the concentration of AIM was lower than 10 phr, whereas the blends showed ductile fracture when the AIM concentration reached 10 phr. It was concluded that the brittle–ductile transition of the PVC/AIM blends was independent of the particle size in the range of 55.2–341.1 nm. When the particle size was greater than 341.1 nm, however, the brittle–ductile transition shifted to a higher AIM concentration with an increase in the particle size. Furthermore, the critical interparticle distance was found not to be the criterion of the brittle–ductile transition for the PVC/AIM blends. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 696–702, 2006     

Chiral separation of synthetic vicinal diol compounds by capillary zone electrophoresis with borate buffer and beta-cyclodextrin as buffer additive.

The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory.     

中山大学校园传统建筑风格评析

本文研究对象为现存于广州中山大学（南校区）校园内建于1936年以前传统建筑。通过对这些建筑的分析，根据建筑风格的不同将中山大学传统建筑分为两个时期：折衷主义时期（1904-1928）和古典复兴主义时期（1928-1936），对这两个时期的建筑风格分别进行概括，并列举了一些代表性的建筑实例。     

Distributed and Parallel Component Library

Software component library is the essential part of reuse-based software development. It is shown that making use of a single component library to store all kinds of components and from which components are searched is very inefficient. We construct multi-libraries to support software reuse and use PVM as development environments to imitate Iargescale computer, which is expected to fulfill distributed storage and parallel search of components efficiently and improve software reuse.     

铜发光中心的分布和位错显微结构的关系

本文作者根据显著观测和发光光谱的测试结果表证实了在ＺｎＳ：Ｃｕ单晶中，蓝色铜发光中心及绿色铜发光中心的分布和位错线区域的横向与纵向的显著与纵向的显著结构有着固定的对应关系。     

智能CAD／CAM技术对建筑机械业的影响

本文首先介绍ＣＡＤ／ＣＡＭ的产生及发展。然后谈ＣＡＤ／ＣＡＭ对建筑机械业的影响。本主独道见解是：ＣＡＤ／ＣＡＭ技术对建筑机械业影响巨大，一个全新的计算机辅助建筑工程制造ＣＡＥＭ概念将产生。当ＣＡＥＭ实现时，建楼房将象儿童搭积木房子一样轻而易举。“安得广厦万千间，使得天下寒士尽欢颜”梦想会成真。     

用奇异摄动法设计线性二次型准最优直流控制系统

利用线性最优调节器理论可以设计出具有良好性能指标的晶闸管直流电机控制系统。这种设计方法优于传统的“双环系统”设计。然而,求解Riccati方程的计算量相当大。为寻求最佳加权Q阵,可能耗费许多时间。采用奇异摄动法设计准最优线性系统时,可以化高阶为低阶,从而简化计算工作量。本文利用奇异摄动理论设计了一个晶闸管直流电动机系统。已肯定本法适应于此类设计。本文还比较了不同设计方法所达到的动态性能。     

钢丝绳断丝定量检测中径向随机晃动误差的补尝

本文论述了钢丝绳断丝定量检测中径向随机晃动误差存在的必然性及该误差对定量检测的影响,基于模拟实验结果,给出了适用于多种类型钢丝绳的V_H-S数学关系式;提出了波形因素的概念与形式,并用软件实现了钢丝绳断丝定量检测中径向随机晃动误差的补偿。     

现代站立式背向滑步推铅球技术的探讨

站立式背向滑步推铅球,是近年来国内外田径大赛中出现的一项新技术。通过力学和解剖学两方面的分析,证明站立式技术具有节省体力、滑步速度快,动作加速连贯性强、有利于最后“鞭打”用力,兼有动作简单、容易掌握等特点,具有较高的实用和推广价值。     

河南省陆栖腹足类初报

整理自1984—1990年从河南省采集的陆栖腹足类标本,已鉴定30种,计前鳃亚纲,中腹足目Ⅰ科2属;肺螺亚纲,柄眼目12科22属。凡注有“*”者为河南省新纪录,注有“**”者为华北新纪录。标本均保存在河南师范大学、生物系。