Apparatus for High-Resolution Solid Hydrogen Matrix Isolation Spectroscopy and Its Application

Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W₀(0) (ν=0←0, J=6←0) line around 2410 cm⁻¹ of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO² co-deposited with hydrogen on a BaF₂ cold plate at liquid-helium temperature was studied.     

Synthesis and characterization of wholly aromatic poly(azomethine)s containing donor–acceptor triphenylamine moieties

N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl₃), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (T_gs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (Φ_F) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007     

浅谈科学计算可视化在教育领域的应用

通过对科学计算可视化技术的分析，探讨了科学计算可视化应用于教育的机理和方法。并给出了具体的应用实例。     

高Tc超导材料Bi_2Sr_2CuO_6和Bi_2Sr_2CaCu_2O_8的晶格振动对称性分析

本文运用群论方法,对高T_c Bi 系超导体中的Bi_2Sr_2CuO_(?)和Bi_2Sr_2CaCu_2O_8的晶格振动模进行了系统的对称性分类.给出了其布里渊区中(?)点,X 点和△线振动模式的对称分解和对称化基.     

菏泽地区大型野生真菌调查续报

本文对菏泽地区大型野生真菌做了进一步的调查,发现了一些食用和药用真菌,经鉴定分类,计有7属20种。     

外气的旋频曲线的实验研究

“旋转曲线”是旋子模型及旋子流假说的重要内容，该曲线在气功外气的研究中占有重要地位。本文从实验的角度证实了旋频曲线的存在，证明了意念对外气的调制作用．     

鸡公山自然保护区药用,食用大型真菌资源调查

本文报导了鸡公山自然保护区药用、食用大型真菌资源，其中药用１５种，食用２３种，药用兼食用２５种，并对如何开发利用这些资源提出了合理建议。     

现代控制论中能控性定理证明方法之比较

就目前在现代控制论科教书中关于战性定常系统的状态能控性的几种常用证明方法提出异议，阐述看法并进行比较。     

新型桥梁施工挂篮XG—A的研究与应用

根据修建海沙大桥工程的需要,专门研制了一种超轻型滑动斜拉式的新型桥梁施工挂篮XG—A.该挂篮自重轻、效率高是目前国内较先进的桥梁施工设备.     

西安市利用陕北天然气的规划与方案

本文概述了西安市天然气供应现状，详细说明了利用陕北天然气规划指导思想、工程规模、供气范围、建设期限和用户发展规划，科学地论述了压力级制和储气量的确定，明确了资金来源、用款计划和材料的采用，重点突出、条理清楚．通过这篇文章，使我们能够全面了解到西安市综合利用陕北天然气的计算和未来发展方向，值得一读．