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851.
采用MP2/6-311 G(2df)和B3LYP/6-311 G(2df)方法讨论了ClNCX→ClXCN(X=O,S,Se)异构化过程,解释了实验上更容易探测到ClNCO,ClSCN和ClSeCN的原因.对异构化过程进行了电子密度拓扑分析,讨论了异构化过程中化学键的断裂和生成规律,找到了反应中的T -型和环型过渡结构. 相似文献
852.
采用多元线性回归方法对常用元素的结构参数及其标准电极电位对定量结构性质相关(QSPR)模型进行研究,结果显示,电负性、电离能等结构参数与元素标准电极电位之间有较好的线性相关性. 相似文献
853.
Y.-D Feng Y.-S. Wang Z.-M. Zhang 《Archive of Applied Mechanics (Ingenieur Archiv)》2003,73(5-6):337-347
Summary A 2D time-domain Boundary Element Method (BEM) is applied to solve the problem of transient scattering of plane waves by an inclusion with a unilateral smooth contact interface. The incident wave is assumed strong enough so that localized separations take place along the interface. The present problem is indeed a nonlinear boundary value problem since the mixed boundary conditions involve unknown intervals (separation and contact regions). In order to determine the unknown intervals, an iterative technique is developed. As an example, we consider the scattering of plane waves by the cross section of a circular cylinder embedded in an infinite solid. Numerical results for the near field solutions are presented. The distortion of the response waves and the variation of the interface states are discussed.
The financial support by the China National Natural Science Foundation under Grant No. 19872001 and No. 59878004 is gratefully acknowledged. The second author is also grateful to the support of the National Science Fund for Distinguished Young Scholars under Grant No. 10025211. 相似文献
854.
855.
Ke-Zhi Li Jian Wei He-Jun Li Yu-Lei Zhang Chuang Wang Dang-She Hou 《Applied Surface Science》2007,253(18):7365-7368
Well-aligned carbon nanotubes (CNTs) of high quality were synthesized by pyrolysis of phenolic resin at 800 °C in anodic alumina oxide (AAO) pores under argon protection. The innocuous source materials and safe operational conditions permit this method to synthesize well-aligned CNTs in large-scale and low cost. The formation mechanism of the synthesized CNTs is also proposed in this work by a series of visual sketches and is proved with obvious evidence. Firstly, phenolic resin nanotubes form in the template pores through the evaporation of solvent. Heat treatment then transfers these tubes into CNTs. 相似文献
856.
All homothetic self-similar solutions of the Brans-Dicke scalar field in three-dimensional spacetime with circular symmetry
are found in closed form. 相似文献
857.
Peng Ping Wenshou Wang Xuesi Chen Xiabin Jing 《Journal of Polymer Science.Polymer Physics》2007,45(5):557-570
Poly(ε‐caprolactone)‐based segmented polyurethanes (PCLUs) were prepared from poly(ε‐caprolactone) diol, diisocyanates (DI), and 1,4‐butanediol. The DIs used were 4,4′‐diphenylmethane diisocyanate (MDI), 2,4‐toluenediisocyanate (TDI), isophorone diisocyanate (IPDI), and hexamethylene diisocyanate (HDI). Differential scanning calorimetry, small‐angle X‐ray scattering, and dynamic mechanical analysis were employed to characterize the two‐phase structures of all PCLUs. It was found that HDI‐ and MDI‐based PCLUs had higher degree of microphase separation than did IPDI‐ and TDI‐based PCLUs, which was primarily due to the crystallization of HDI‐ and MDI‐based hard‐segments. As a result, the HDI‐based PCLU exhibited the highest recovery force up to 6 MPa and slowest stress relaxation with increasing temperature. Besides, it was found that the partial damage in hard‐segment domains during the sample deformation was responsible for the incomplete shape‐recovery of PCLUs after the first deformation, but the damage did not develop during the subsequent deformation. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 557–570, 2007 相似文献
858.
一、教材分析
1.地位与作用
自由落体运动是自然界中广泛存在的物体自由下落运动的理想化模型,是一种典型的匀变速直线运动。自由落体运动有其广泛性和特殊性,对自由落体运动进行深入具体的研究,有利于学生更深刻地理解前面所学的匀速直线运动的规律。 相似文献
859.
Fengping Yu Junpo He Xiaojun Wang Guangzheng Gao Yuliang Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(17):4013-4025
A combination of nitroxide‐mediated radical polymerization and living anionic polymerization was used to synthesize a series of well‐defined graft (co)polymers with “V‐shaped” and “Y‐shaped” branches. The polymer main chain is a copolymer of styrene and p‐chloromethylstyrene (PS‐co‐PCMS) prepared via nitroxide‐mediated radical polymerization. The V‐shaped branches were prepared through coupling reaction of polystyrene macromonomer, carrying 1,1‐diphenylethylene terminus, with polystyryllithium or polyisoprenyllithium. The Y‐shaped branches were prepared throughfurther polymerization initiated by the V‐shaped anions. The obtained branches, carrying a living anion at the middle (V‐shaped) or at the end of the third segment (Y‐shaped), were coupled in situ with pendent benzyl chloride of PS‐co‐PCMS to form the target graft (co)polymers. The purified graft (co)polymers were analyzed by size exclusion chromatography equipped with a multiangle light scattering detector and a viscometer. The result shows that the viscosities and radii of gyration of the branched polymers are remarkably smaller than those of linear polystyrene. In addition, V‐shaped product adopts a more compact conformation in dilute solution than the Y‐shaped analogy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4013–4025, 2007 相似文献
860.