网络资源建设的思考

在现在的教育教学活动过程中,以网络教育形式来传递教育教学信息,愈发显得重要。以网络基础开展的教育教学活动中,资源建设对整个教学的进展起着至关重要的作用     

Novel aromatic polyamides bearing pendent diphenylamino or carbazolyl groups

Two new diamines, 2,4‐diaminotriphenylamine ( 3 ) and N‐(2,4‐diaminophenyl)carbazole ( 4 ), were synthesized via the cesium fluoride‐mediated aromatic substitution reactions of 1‐fluoro‐2,4‐dinitrobenzene with diphenylamine and carbazole, followed by palladium‐catalyzed hydrazine reduction. Amorphous and soluble aramids having pendent diphenylamino and carbazolyl groups were prepared by the phosphorylation polycondensation of aromatic dicarboxylic acids with diamines 3 and 4 , respectively. The aramids derived from diamine 3 had sufficiently high molecular weights to permit the casting of flexible and tough films. They exhibited excellent mechanical properties and moderately high softening temperatures in the 221–298 °C range. However, the reactions of diamine 4 with aromatic diacids gave relatively lower molecular weights products that could not afford flexible films. For a comparative purpose, the parent aramids derived from m‐phenylenediamine and aromatic diacids were also prepared and characterized. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3302–3313, 2004     

基于LDAP协议实现统一的网络管理研究

基于网络上信息存储方式的不统一及其所面临的困难 ,结合复旦大学校园网的特点 ,在深入研究LDAP协议的基础上 ,给出了一套跨协议认证的解决方案 ,提出了关于同步问题的两个模型和基于CSN方法的实现办法     

2‐Cyanoprop‐2‐yl dithiobenzoate mediated reversible addition–fragmentation chain transfer polymerization of acrylonitrile targeting a polymer with a higher molecular weight

The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. ¹H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007     

试述招标机制在企业中的运用

随着社会主义市场经济体制的建立、健全和日益完善，招标机制成为企业经营管理的客观需要，阐述了招标机制在企业中的具体运用，提出了在运用招标机制的过程中应注意的几个问题。     

计算机基础课教学网站开发和建设方案

文章针对计算机基础所面临的不断变化和持续增长 的需求，提出了计算机基础课教学网站的建设方案，介绍了网站的总体结构和创建网站时所使用的主要工具的方法，以及动态WEB的实现技术。     

用ISM分析某集团公司关键性经营战略因素

针对A集团公司经营发展中的问题，采用问卷调查方式，咨询了该公司20位中上层领导。总结出了7个重要因素。应用ISM方法分析这些因素，得出相应的解释结构模型，使影响该集团发展由浅入深的因素层次化。文中认为低层矛盾得以解决，公司深层能力才能得到提高，表层问题也自然迎刃而解，公司才能加速发展。     

Bipyridinophane‐containing conjugated polymers modulated with an intramolecular aromatic C?H/π interaction

Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and ¹H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, Mn²⁺, and Ag⁺ ions. In contrast, only Cu²⁺, Co²⁺, and Ni²⁺ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu²⁺, Co²⁺, and Ni²⁺ ions toward P7 are of the order of 10⁶ M^?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006     

沈从文《边城》解读

在《边城》中，作家沈从文一方面以记忆中的湘西世界为原型建构了他的田园乌托邦，但另一方面，又通过人物命运中的一些偶然性事件的设计，使之同时被解构了。作者内心深处的沉忧隐痛之情也因此在字里行间浮现了出来。本文试从作者对偶然性事件的特殊安排角度来具体分析这种沉忧隐痛之情的根源及其它所产生的独特审美意蕴。     

TLC549 A/D转换电路在EDA实验系统上的实现

介绍了TLC5 4 9带串行控制的 8位、4 0MHz单通道模数转换器的设计方法。常用的A D转换器件多数是并行输出 ,应用电路成熟 ,而带串行控制的转换器的设计方法少见。本文提出的串行控制单通道模数转换器设计方法在EDA实验系统上得到了验证 ,对相关电路设计具有一定参考价值