Effect of end groups on complexation kinetics between cyclodextrins and guest polymers

α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006     

β-桉烯和其衍生物的合成及其抗生育活性

本文叙述了倍半萜类化合物——β-桉烯、衍生物Neointermedeol以及1,2,3,4,7,8-六氢-5,8-二甲基-3-异丙烯基萘的合成。初步药理筛选结果表明,这三个化合物均具有一定的抗生育活性。化合物还未见报道,它的化学结构在本文得到证实。     

多维测量结果不确定度评价方法初探

为解决以多维矢量形式存在被测对象的测量质量评定问题,该文应用测量不确定度理论和多元概率统计方法,将测量不确定度理论进行了向多维的拓展;对多维情况下的测量不确定度传播律进行了推导;论述了多维不确定度的表示方法及空间几何意义;提出了以多维不确定度比较不同测量结果质量的方法;并给出了常用多维测量方法,如等精度独立多维测量和不等精度独立多维测量的不确定度评定方法。理论分析及仿真算例表明,所提出的理论具有较完备的体系,能够满足测量实际中常用多维测量方法的不确定度评定需求。     

The Response of Debris-Flow Events to Solar Proton Flares （Ⅰ）

By analyzing the observation data from Dongchuan Debris Flow Observation and Research Station and historical data from year 1965 to 1990 gotten from National Astronomical Ob-servatories/Yunnan Observatory,the responding of debris flow in Jiangjia Ravine to Solar Proton Flare is studied. The following conclusion can be drawn. Solar Proton Flare,as one of most im-portant astronomical factors,affects the activity of debris flow in Yunnan. Generally,from 1965 to1990,the more active Solar Pro-ton Flare is,the greater the probability of high frequency and large runoff of debris flow is. On the contrary,the less active Solar Pro-ton Flare is,the greater the probability of low frequency,small runoff,and low sediment transport of debris flow is.     

养殖池塘沉积物的重金属分布及污染特征

浙江省淅西北地区淡水养殖池塘沉积物重金属调查研究表明，养殖池塘沉积物中7种重金属元素分布不均衡，差异也较大，除Hg和Cr元素外，其余重金属元素已大大超过土壤本底值．虽然其实测含量都未超出国家规定的标准值范围，但沉积物中重金属元素对养殖水环境、养殖品种存在的潜在污染与危害值得关注．污染指数评价显示，养殖池塘沉积物中主要污染物质为Cu和Cr，而Hg、Pb污染程度相对较轻．     

Controlled/living polymerization of 2‐(diethylamino)ethyl methacrylate and its block copolymer with tert‐butyl methacrylate by atom transfer radical polymerization

Polymerization of 2‐(diethylamino)ethyl methacrylate (DEAEMA) via homogeneous atom transfer radical polymerization under various reaction conditions is described. The effects of the initiators and solvents were examined. With 1,1,4,7,10,10‐hexamethyl triethylenetetramine/copper(I) chloride/p‐toluenesulfonyl chloride as the ligand/catalyst/initiator system in methanol, poly(DEAEMA) with a polydispersity index as low as 1.07 was synthesized. Kinetic studies demonstrated the polymerization was very well controlled and exhibited the living characteristic of the process. Well‐defined block copolymers of DEAEMA and tert‐butyl methacrylate (tBMA) were successfully synthesized. The copolymers could be synthesized with equally good results by starting with either p(DEAEMA) or p(tBMA) as the macroinitiators. However, only the macroinitiators terminated with chlorine should be used. The corresponding macroinitiators with bromine as a transferable group did not yield well‐defined copolymers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2688–2695, 2003     

高师英语职业技能教育改革

高师院校肩负着培养基础教育师资的重任。衡量师资素质的重要标准之一，是教师职业素质与技能掌握、运用的程度。因而职业技能教育是高师教育中一个重要组成部分。本文通过对高师院校英语职业技能教育的反思，以及对基础教育发展需求分析，提出从可持续发展、教育的内在价值与创新教育的三个层面探讨高师英语职业技能教育改革。     

模糊集技术在网络信息过滤系统中的应用研究

本文将模糊模式识别引入到校园网信息过滤系统中，通过网页内容识别和分级技术将各种不同网站进行分类，过滤和禁止有害网络信息，从而达到校园网的信息“净化”目的。     

改善大学生耐久力的实验研究

针对大学生心肺功能弱，体力差的这一普遍问题，本文通过调查和长跑教学实验，找出问题产生的根源，提出运用点面兼顾的教学方案、灵活多变的教学方法和循循善诱的心理引导等手段，提高学生的练习兴趣，达到增强其心肺功能和耐久力的目的。     

CRP复合材料板复合型裂纹扩展方向预测理论研究

本文对碳纤维增强的复合材料板裂纹扩展方向预测理论进行了研究。介绍了最新发展起来的复合材料Z断裂理论 ,并通过试验证明了新理论的正确性