Redox modulated hydrogelation of a self-assembling short peptide amphiphile

Hydrogels resulting from the self-assembly of small peptides are smart nanobiomaterials as their nanostructuring can be readily tuned by environmental stimuli such as pH,ionic strength and temperature,thereby favoring their practical applications.This work reports experimental observations of formation of peptide hydrogels in response to the redox environment.Ac-I 3 K-NH 2 is a short peptide amphiphile that readily self-assembles into long nanofibers and its gel formation occurs at concentrations of about 10 mmol/L.Introduction of a Cys residue into the hydrophilic region leads to a new molecule,Ac-I 3 CGK-NH 2,that enables the formation of disulfide bonds between self-assembled nanofibers,thus favoring cross-linking and promoting hydrogel formation.Under oxidative environment,Ac-I 3 CGK-NH 2 formed hydrogels at much lower concentrations(even at 0.5 mmol/L).Furthermore,the strength of the hydrogels could be easily tuned by switching between oxidative and reductive conditions and time.However,AFM,TEM,and CD measurements revealed little morphological and structural changes at molecular and nano dimensions,showing no apparent influence arising from the disulfide bond formation.     

基于KQGIS平台的城镇地籍更新调查数据库建设与关键技术研究

以北京苍穹KQGIS为建库平台,建立河南省罗山县城镇地籍更新调查数据库.介绍了其主要环节和关键技术.首先阐述了城镇地籍更新调查数据库建设工作,包括建库前数据的准备、数据格式转换、数据整理入库及成果提交等方面.之后研究分析建库过程中出现的关键技术问题,实现了地籍成果科学的存储与管理,达到快速查询、更新、统计、空间分析以及数据发布和资源共享等目的.     

团队建设的理据述评

团队建设理论主要有团队角色理论、人格理论、实践活动理论和人性假设理论。探讨这些理论,并在管理实践中加以正确运用,能够有效沟通内部,改善单位及其成员个人绩效,推动单位事业的发展和进步。     

Poly(4,8‐bis(2‐ethylhexyloxy)benzo[1,2‐b:4,5‐b′]dithiophene vinylene): Synthesis,optical and photovoltaic properties

A new benzodithiophene (BDT)‐based polymer, poly(4,8‐bis(2‐ethylhexyloxy)benzo[1,2‐b:4,5‐b′]dithiophene vinylene) (PBDTV), was synthesized by Pd‐catalyzed Stille‐coupling method. The polymer is soluble in common organic solvents and possesses high thermal stability. PBDTV film shows a broad absorption band covering from 350 nm to 618 nm, strong photoluminescence peaked at 545 nm and high hole mobility of 4.84 × 10^?3 cm²/Vs. Photovoltaic properties of PBDTV were studied by fabricating the polymer solar cells based on PBDTV as donor and PC₇₀BM as acceptor. With the weight ratio of PBDTV: PC₇₀BM of 1:4 and the active layer thickness of 65 nm, the power conversion efficiency of the device reached 2.63% with V_oc = 0.71 V, I_sc = 6.46 mA/cm², and FF = 0.57 under the illumination of AM1.5, 100 mW/cm². © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1822–1829, 2010     

构建人性的神话——试论他者视角下二战题材电影《南京! 南京!》和《硫磺岛家书》

《南京!南京!》和《硫磺岛家书》均采用了＂他者＂视角编织出人性神话。《南京!南京!》中的＂他者＂视角是国际化浪潮中电影的价值观与世界接轨的大胆尝试,而《硫磺岛家书》则是直接源自美国主流意识形态所倡导的人性观。这种普适性的人性视角忽略了具体历史文化环境中特殊的人性,规避了对沉重的历史真相的阐释,存在对日本文化的误读。     

河南省中学实施“体教结合”的影响因素分析

分析了影响河南省中学实施＂体教结合＂的因素。结果表明,多数学校对在中学实施＂体教结合＂是有共识的;各学校建立业余训练运动队的动机呈现多元化倾向;大部分学校有能力保证年度较系统的训练,但同时也存在不少问题。针对影响因素提出了合理化建议。     

高校体育弱势群体的成因与教学策略

从高校体育弱势群体的现状出发,运用文献资料法和逻辑推理法对体育弱势群体形成的原因进行了分析.研究表明:学生自身身体、生理、心理方面是内在原因;学校体育课程管理、体育教学内容和形式、体育教师、体育成绩评定等是外在原因.针对成因提出了采用适时进行思想教育、多种角度激励、精选教学内容、因材施教、采用多元化评价等教学策略,以维护高校体育弱势群体体育权益,体现体育教育公平.     

外磁场对铁磁双层膜自旋波能带的影响

研究了在外磁场作用下铁磁双层薄膜材料中自旋波的本征值问题.采用界面重参数化方法,在周期性边界条件下,严格求解系统的三种本征模,并给出横向自旋波取全部值的能带结构图,讨论了外磁场对自旋波能带的影响.     

Design and synthesis of a novel soft-hard donor ligand for solvent extraction of Th(IV) from nitric acid media

Journal of Radioanalytical and Nuclear Chemistry - A novel hard-soft donor ligand...