Acanthosphere-like gold microstructures (AGMs) were synthesized using a facile, two-step, seed-mediated method and butanediyl-1,4-bis(dimethylhexadecylammonium bromide) (16-4-16) as a structure-directing agent. The morphologies and sizes of the products were controlled during the synthesis process by adjusting the concentrations of 16-4-16, the AgNO3 feed, HAuCl4, ascorbic acid, the amount of Ag seeds and the types of gemini surfactants used through systematic inquiry; particle sizes ranging from 130 to 800 nm were well prepared. Correspondingly, the morphology of the products changed between regular and irregular AGMs, and the products presented a number of new morphologies, such as open-mouthed submicrostructures and ribbon nanowires. In particular, with the increase in the 16-4-16 concentration, the structural morphology of the thorns clearly changed from a tip to a lamellar structure. A UV-vis spectroscopic analysis indicated that the localized surface plasmon resonance (LSPR) peak of the AGMs could be adjusted by changing the above factors, which extended from 500 to 1350 nm in the near-infrared (NIR) region, enabling a tremendous potential for using the AGMs as platforms for various biomedical applications. Based on the intermediate products, we propose a two-stage growth mechanism for the AGMs in which their solid cores and tips are generated successively. Surface-enhanced Raman scattering (SERS) measurements indicate that the AGMs can serve as sensitive SERS substrates; a SERS detection limit of 5 × 10?7 M is presented for rhodamine B molecules.
Non-equilibrium molecular dynamics (NEMD) simulations are employed to investigate the longitudinal thermal conductivity of non-orthogonal extended X-junction (EX-junction) of single-walled carbon nanotubes (SWCNTs). Different from standard junctions of SWCNTs, two distinct jumps in the temperature profile around the EX-junction are observed, which are responsible for the larger temperature gradient and reduction in thermal conductivity when compared to standard X-junction. Quantum corrected results show that the longitudinal thermal resistance of the X-junction and EX-junction decreases monotonically with increasing temperature which makes the longitudinal thermal conductivity of the tube with junction less sensitive to temperature above 400 K comparing with the individual pristine tube. The origin of the significant decrease of thermal conductivity of EX-junction is discussed through phonon spectra analysis. 相似文献
0 IntroductionThe security of most commonly used cryptographicschemesis essentially based onthree families of compu-tational problems :the integer factoring problem(RSAprob-lem) ,the Diffie-Hell man problemand the discrete logarithmproblem,andthe elliptic curve variants thereof .Inthe middleof 1990s , Shor[1], Bonehet al[2]presented some remarkablequantumalgorithms which can solveinteger factoring problemand discrete logarithmproblemover any group including Ga-lois fields and elliptic curve… 相似文献
0 IntroductionDigital signatureis a key technique to provide datainteg-rity andsource authenticationcapabilities to enhance da-ta trustworthiness in trusted computing platform. Most cur-rent digital signature schemes are based on complex mathe-matical problems , such as integer factoring, discrete log-arithm,and discrete logarithm on elliptic curves . The hard-ness of these underlying mathematical problems is really un-certain at present . Merkle treeis a method used for authenti-cation and di… 相似文献
