多孔氧化铝膜的制备及其光学性质

提出了一种制备具有周期结构金属薄膜的新方法--阳极氧化法制备多孔氧化铝膜.以草酸为电解液,制备出了几种表面孔径不同的多孔氧化铝膜,并在其表面镀银制得样品.用场发射扫描电镜观察多孔氧化铝膜的表面形貌,并采用光谱仪测定了样品的透射光谱.研究发现,由于表面等离子激元波(surface plasmon polaritons, SPPs)的作用,在可见光波段观察到了透过率异常增强现象.     

Formal analysis on an extended security model for database systems

In order to develop highly secure database systems to meet the requirements for class B2, the BLP （Bell-LaPudula） model is extended according to the features of database systems. A method for verifying security model for database systems is pro- posed. According to this method, an analysis by using Coq proof assistant to ensure the correctness and security of the extended model is introduced. Our formal security model has been verified secure. This work demonstrates that our verification method is effective and sufficient.     

大型水利枢纽砼运输浇筑系统的GPSS模型及仿真研究

本文应用系统仿真原理和GPSS(General Purpose Simulation System——通用仿真系统)仿真语言构造了大型水利枢纽混凝土工程的运输浇筑系统的GPSS模型，并通过计算机运行对该系统进行了仿真研究，得出了具有一定实用价值的结果，为大型水利枢纽的可行性研究、设计、施工提供了参考．     

内燃机缸内过程的一种多维数学模型

利用任意拉格朗日－欧拉法，求解具有缸头中心无气阀气口进排气模拟功能的内燃机缸内三维流动，喷雾和燃烧过程控制方程，为对比不同湍流模型对模拟结果的影响，除采用Ｋ－ε模型外，还首次引入传统代数应力模型对缸内流动进行模拟，计算结果表明；本文的多维模型，对内燃机燃烧过程的模拟结果是合理的，对进气过程的计算结果与实测结果基本吻合，对平顶活塞及带坑活塞缩过程的模拟结果，显示了两种湍流模型的差异。     

基于自适应遗传算法的拟态蜜罐演化策略

借鉴生物遗传进化现象,将遗传算法引入拟态蜜罐系统中,提出了基于自适应遗传算法的拟态蜜罐演化策略,详细讨论了拟态蜜罐系统演化中特征形式化编码、遗传算子设计、适应度函数、演化触发控制与终止条件等关键问题,设计实现了具有自适应遗传演化功能的拟态蜜罐原型系统并进行了原型测试,实验数据表明了基于自适应遗传算法的拟态蜜罐演化策略具有良好的自适应性和有效性.     

钻孔挤压分支桩的应用与试验研究

桩基工程设计，直接影响上部结构的安全及整个工程的造价。通过钻孔挤压分支桩在阜阳商厦三期工程中的应用及试验研究表明，在同一场地、单桩竖向极限承载力相同的条件下，用钻孔挤压分支桩代替钻孔灌注桩，单位体积混凝土的竖向极限承载力标准值可提高１．３１倍，桩基节约投资２７０万元。由此可见，在大柱网、大承载力柱桩基工程中，钻孔挤压分支桩更能充分发挥其优越性。     

激光诱导击穿光谱(LIBS)法微损快速检测党参中Pb

中药材重金属元素快速检测对污染监控及人们健康具有重要意义。激光诱导击穿光谱技术(Laser Induced Breakdown Spectroscopy, LIBS)属于一种快速检测方法,研磨压片等预处理方法相对样品消解已有所简化,但破坏了样品的物理性质,且不能满足中药材大宗品种、大批量检测需求。若进一步简化样品预处理,将更加凸显LIBS快速检测的优势。本文建立了激光诱导击穿光谱技术(LIBS)快速微损检测中药材样品重金属元素定标方法。线性相关系数R2为0.7764,建立的微损定标曲线线性可用于切片党参LIBS快速检测,对待测党参切片样品检测平均相对误差为3.74%,与电感耦合等离子体质谱法(ICP-MS)对比,相关系数R2为0.7957,验证了LIBS技术微损检测的可行性。制备的党参参考定标样品可多次重复用于待测样定标和仪器标定等。实验对待测党参样品仅进行切片处理,避免了研磨、压片等预处理,更加充分地体现LIBS快速检测的优势,为LIBS技术应用于中药材重金属元素快检等领域提供了一种新方法。     

A general electron donor–acceptor complex for photoactivation of arenes via thianthrenation

General photoactivation of electron donor–acceptor (EDA) complexes between arylsulfonium salts and 1,4-diazabicyclo[2.2.2]octane with visible light or natural sunlight was discovered. This practical and efficient mode enables the production of aryl radicals under mild conditions, providing an unrealized opportunity for two-step para-selective C–H functionalization of complex arenes. The novel mode for generating aryl radicals via an EDA complex was well supported by UV-vis absorbance measurements, nuclear magnetic resonance titration experiments, and density functional theory (DFT) calculations. The method was applied to the regio- and stereo-selective arylation of various N-heterocycles under mild conditions, yielding an assembly of challengingly linked heteroaryl–(hetero)aryl products. Remarkably, the meaningful couplings of bioactive molecules with structurally complex drugs or agricultural pharmaceuticals were achieved to display favorable in vitro antitumor activities, which will be of great value in academia or industry.

General photoactivation of EDA complexes between arylsulfonium salts and 1,4-diazabicyclo[2.2.2]octane was discovered. This practical mode enables the generation of aryl radicals for C–H functionalization of arenes.     

An Image Compression Encryption Algorithm Based on Chaos and ZUC Stream Cipher

In order to improve the transmission efficiency and security of image encryption, we combined a ZUC stream cipher and chaotic compressed sensing to perform image encryption. The parallel compressed sensing method is adopted to ensure the encryption and decryption efficiency. The ZUC stream cipher is used to sample the one-dimensional chaotic map to reduce the correlation between elements and improve the randomness of the chaotic sequence. The compressed sensing measurement matrix is constructed by using the sampled chaotic sequence to improve the image restoration effect. In order to reduce the block effect after the parallel compressed sensing operation, we also propose a method of a random block of images. Simulation analysis shows that the algorithm demonstrated better encryption and compression performance.     

一种摆动式柔性尾部的仿生机器鱼

提出了一种摆动式柔性尾部的仿生机器鱼设计方案,着重解决了机器鱼摆动式推进的问题.在该方案中,应用曲柄摇杆原理,采用了特殊的四连杆摆动机构,结合柔性尾部实现了机器鱼的摆动式推进;巧妙应用了霍尔位置传感器,检测摆杆临界位置,实现了鱼尾位置判断,进而控制鱼尾来转向;研制了以气缸为压缩泵的气路沉浮机构作为"鱼鳔",能使机器鱼进行沉浮动作.实验显示这种机器鱼达到了预期的功能,在水下作业、军事侦察、娱乐等领域有一定的研究应用价值.