Bipyridinophane‐containing conjugated polymers modulated with an intramolecular aromatic C?H/π interaction

Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and ¹H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, Mn²⁺, and Ag⁺ ions. In contrast, only Cu²⁺, Co²⁺, and Ni²⁺ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu²⁺, Co²⁺, and Ni²⁺ ions toward P7 are of the order of 10⁶ M^?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006     

The prediction of the peak width at half height in HPLC

The prediction of the peak width at half height is an important aspect in the optimization of the chromatographic operating conditions. In this paper, a linear relationship, between the peak widths at half height and the retention values with various isocratic elution is observed. In gradient elution, however, the relationship between the peak widths at half height and the so-called invented retention values that correspond to the mobile phase composition by eluting the solute from the column end is developed. We believe that there is almost the same band width at half height inside the column (in unit of length) for different solutes. The peak width at half height in the chromatogram (in unit of time) is mainly determined by the capacity factor of the solute when it is eluted from the column end. The larger the capacity factor of a solute eluted from the column end, the more slowly will be the solute eluted from the column end and the wider will be the peak width at half height. It is possible to predict the peak width at half height in various isocratic and gradient elutions by using this linear relationship.     

Fibonacci,Lucas序列与高阶Bernoulli多项式

本文给出了包含Ｆｉｂｏｎａｃｃｉ序列｛Ｆｎ｝、Ｌｕｃａｓ序列｛Ｌｎ｝及高阶Ｂｅｒｎｏｕｌｌｉ多项式Ｂｎ（Ｋ）（ｘ）的一些恒等式。     

高级语言直接操作数据库文件的技术

介绍在Ｃ语言程序设计中直接操作数据库文件的基本概念与实现技术，包括对库文件存贮结构的分析、读取库文件结构信息与读写、删除、恢复，添加的记录等基本方法。该技术的基本思想与技术对其它高级语言程序设计也是适合的。     

黄磷废水处理系统中氰降解菌的筛选

首次对含有氰化物的黄磷废水进行了氰降解菌筛选优化,共得耐氰菌20株,其中有9株的降氰率在90％以上,且AB2001003菌株降氰率在97.1％以上.该菌能在72 h内使含CN~-50mg·L~(-1)的黄磷废水降至0.5 mg·L~(-1)以下,达到国家一级排放标准.该菌的最佳生长pH7.7,最佳温29℃.     

￣（45）Ca跨膜流动测定技术用于中药钙拮抗作用的研究

应用￣（４５）Ｃａ跨膜流动测定技术研究钙拮抗剂ｖｅｒａｐａｍｉｌ、中药西红花（ＣｒｏｃｕｓＳａｔｉｖｕｓＬ．）、“地奥心血康”（ＤＡＸＸＫ）、川红花（ＣａｒｔｈａｍｕｓｔｉｎｃｔｏｒｉｕｓＬ．）及银杏叶（ＧｉｎｋｇｏｂｉｌｏｂａＬ．）等对大鼠主动脉￣（４５）Ｃａ跨膜内流的作用，以确定其对细胞膜Ｃａ￣（２＋）通道影响。实验结果表明：西红花、川红花、ＤＡＸＸＫ对平滑肌细胞膜上电压依赖Ｃａ￣（２＋）通道（ＰＤＣ）和受体操纵Ｃａ￣（２＋）通道（ＲＯＣ）都有阻滞作用，并以西红花的阻滞作用最强；而银杏叶对细胞膜Ｃａ￣（２＋）通道无阻滞作用。     

关于细集料砂当量指标的探讨

通过加土的方法得到不同泥土含量的集料，进行砂当量试验，并用不同砂当量值的集料制成成心性稀浆封层混合料进行湿轮磨耗试验，试验结果表明，砂当量与集料中的泥土含量存在良好的线性关系，是评价细集料洁净程度的有效方法，试验中集料级配和取样均匀程度会对试验结果产生一定影响，砂当量低的集料会使改性剂无法发 对心性稀浆封层混合料的改性效果，建议用于心性稀浆封层的的细集料砂当量不低于60％。     

用微弹轰击法将GUS基因导入香蕉茎尖组织细胞

用在弹轰击法将外源ＤＮＡ导入香蕉（Ｍｕｓａ，ｓｐｐ）茎尖细胞，以ＧＵＳ基因作为报告基因，用Ｘ－Ｇｌｕｃ浴液对ＧＵＳ基因表达产物进行组织化学鉴定。样品材料细胞中发现有明显的蓝色斑点，而对照则没有。实验说明用微弹轰击法可以将外源基因导入香蕉茎尖组织并在其中成功表达，这为香蕉的外源基因导入工作提供了新的有效途径．     

多项式理想准素分解的算法

讨论了多项式理想准素分解的算法,对于理想坐标变换中关键的“一般位置”的计算,给出了一个确定算法,并建立了特别规范Groebner基的概念,利用这一概念及文中提供的相应算法,可以方便地计算理想的维数,进而使用降维的方法来得到高维理想的准素分解。     

Orthogonally linear polarized lasers(Ⅰ)--principle and devices

Two kinds of orthogonally polarized lasers, i.e. Zeeman dual-frequency lasers and four-frequency ring lasers (laser gyros) have been developed since the invention of lasers, in which circularly polarized lights oscillate. This paper summarizes recent progress of the study on orthogonally linear polarized lasers with the standing wave cavity. Firstly, the expression of producing orthogonally linear polarized lights in standing wave cavity, i.e. laser frequency splitting, is given. Almost all the birefringence effects made in laser cavity are used to produce orthogonally linear polarized lights. The effect includes quartz crystal birefringence effect, calcite birefringence effect,stress (photo-elastic) birefringence effect and electro-optical birefringence effect. Secondly, several physical phenomena of orthogonally linear polarized lasers are discovered such as aberrance of frequency splitting curves caused by optical activity of quartz crystal, order-passing of longitudinal modes with frequency splitting and strong modes competition. Finally, because the traditional Zeeman dual frequency laser cannot output frequency difference larger than 3 MHz, the approaches of obtaining larger frequency difference are studied. The sequential results, several kinds of orthogonally polarized lasers, are described, such as birefringence dual frequency lasers outputting a frequency difference from 40 MHz to hundreds of megahertz, birefringence-Zeeman dual frequency lasers outputting a frequency difference from 1 MHz to hundreds of megahertz, the LD pumped YAG birefringence dual frequency laser outputting frequency difference of several gigahertz, and the lasers whose longitudinal mode spacing is c/4L instead of c/2L.