A Novel Catalyst for Liquid Phase Hydrogenation of m-Dinitrobenzene to m-Phenylenediamine

A novel lanthana-promoted nickel catalyst supported on silica for the liquid phase hydrogenation of m-dinitrobenzene to m-phenylenediamine was prepared by an incipient wetness sequential impregnation method. It was found that Ni-La/SiO2 catalyst exhibited high activity and stability for m-dinitrobenzene hydrogenation. Over this catalyst, the conversion of m-dinitrobenzene and the yield of m-phenylenediamine were up to 97.1% and 93.5%, respectively,at 373 K and 2.6 MPa hydrogen pressure after reaction for 1 h.     

Furostanol saponins with inhibitory action against COX-2 production from Tupistra chinensis rhizomes

Two furostanol saponins were obtained from the n-butanol fraction of methanol extract from Tupistra chinensis rhizomes,a folk medicine of Shennongjia Forest District of Hubei Province.Their structures were determined as (25S)-26-O-(β-D-glucopyranosyl)- furost-1β,3β,22α,26-tetrol-3-O-β-D-glucopyranosyl-(1→4)-β-D-glucopyranosyl-(1→2)-β-D-glucopyranoside (1) and (25R)- 26-O-(β-D-glucopyranosyl)-furost-1β,3β22α,26-tetrol 3-O-β-D-glucopyranosyl-(1→4)-β-D-glucopyranosyl-(1→2)-β-D-glu- copyranoside (2),on basis of chemical and spectroscopic evidences.1 and 2 displayed marked inhibitory action towards COX-2 production in macrophages of the rat abdomen induced by LPS at 20μg/mL.     

Synthesis and Properties of Polyetherketones Containing Sulfide and Phthalazinone

High molecular weight copoly(ether ketone)s (PEK) based on 4-(4-hydroxyphenyl)-1-phthalazinone (DHPZ)/4,4′-thiobisphenol (TBP)/4,4′-diflourodiphenylketone (DFK) were prepared by nucleophilic substitution polycondensation. The copolymers were characterized by FT- and ^1H-NMR. Thermal properties and solubility of copolymers were studied.     

氧化锡表面的原子簇模型计算

Cluster models of SnO2(110) face and oxygen vacancies and oxygen adsorption on its surface have been calculated by EHMO method. The results show that a tin atom with a coordination number of four is the adsorption center, because the total energy of cluster model becomes lower when an oxygen atom adsorpts on the tin atom with a coordination number of four. The tin atom with this coordination number gains and loses electrons more easily than tin atoms with a coordination number of five. All tin atoms in the cluster of SnO2(110) face are Sn4+.     

WebGIS及三维可视化技术在供水管网中的应用

分析当前供水管网管理信息系统中存在的两个问题,提出一套基于WebGIS和三维可视化技术的解决方案,采用MapXtreme实现网络化,用OpenGL技术实现三维可视化。     

拉伸羊毛分子结构的显微红外光谱分析

应用显微镜偏振红外光谱法分析了拉伸羊毛纤维大分子结构的变化，通过对特征谱带的分析，得到了羊毛大分子链段结构和大分子构象随拉伸率的变化情况；由此可知，显微红外光谱具有很高的灵敏度，应用偏振显微红外光谱可以准确地对纤维大分子结构的变化进行分析和表征。     

基于Web的考试系统设计及其技术实现

讨论了基于Web的考试系统的主要功能及其设计方案,分析了在线考试系统的相关技术,指出了该系统能较好地解决远程教育中的考试问题,真正实现无纸化的在线考试,具有较强的应用价值.     

政府资本投资与经济不确定性

对Benhabib 和Farmer的不确定模型做了部分修改,通过动态最优化的方法,得出了一个二维系统,并分析了系统的稳定性,结果表明:政府的过度投资将导致经济系统的不确定性.     

确定双曲型方程未知系数的反问题

本文在有界区域上讨论了一雏线性双曲型方程的初边值问题. {p(x)ux)x q(x)u(x,t) r(x)s(t), (x,t) ∈Ωu(x,0) =f1(x), u1(x,0) =f2(x), 0≤ x ≤ lαtu(0,t) β1ux(0,t)= g1 (t), α2u(l,t) β2ux(l,t)= g2(t), 0≤ x ≤ T 其中αi2 βi2≠0,i=1,2,由给定的平行附加条件u(x,t)=f3(x),确定未知函数r(x)的反问题,得到了反问题解的存在性和唯一性.