Preparation, characterization and application in deep catalytic ODS of the mesoporous silica pillared clay incorporated with phosphotungstic acid

Mesoporous silica pillared clay (SPC) materials with different contents of H(3)PW(12)O(40) (HPW) heteropoly acid were synthesized by introducing HPW into clay interlayer template in an acidic suspension using sol-gel method. Samples with similar HPW loadings were also prepared by impregnation method using SPC as the support. The results of the characterizations showed that HPW was dispersed more homogeneously in the encapsulated samples than in the impregnated samples. The encapsulated materials exhibited better catalytic performance than the impregnated samples in oxidative desulfurization of dibenzothiophene-containing model oil. The sulfur removal reached up to 98.6% for the model oil under the experiential conditions.     

Exact thresholds for low-density parity-check codes over the binary erasure channel

A simple method for determining the threshold of irregular LDPC codes over the binary erasure channel (BEC) under message-passing decoding is proposed. An exact formula for calculating the threshold of irregular LDPC codes over the BEC is proved. This generalizes the known result on the threshold of regular LDPC codes to irregular LDPC codes. Moreover, our new method can avoid the computation of the inverse of the degree distribution function for irregular LDPC codes. Numerical results demonstrate the correctness of our proposed method.     

判定有限域上不可约多项式及本原多项式的一种高效算法

 提出了一个判定有限域上任一多项式是否为不可约多项式、本原多项式的高效的确定性算法。分析了多项式次数与其不可约因式之间的内在联系,给出了有限域上任意n次多项式是否为不可约多项式、本原多项式的一个充要条件。通过利用欧几里得算法,该判定仅需做O((log ₂ ⁿ)n³)次域上乘法,属于多项式时间,易于硬件实现。为扩频通信与序列密码寻找和利用不可约多项式构造线性反馈移位寄存器提供了一种有效算法。     

高效分选废旧光伏电池板中铜与硅

为了提高废旧光伏电池板中铜(Cu)与硅(Si)的分选效率,寻求高压静电分选的最佳效率因素.通过单因素影响实验,探究了电压(U)、转辊转速(n)、电晕电极间距(S)和电晕电极角度(θ)对Cu与Si分选效率的影响;利用Minitab软件进行全因子实验设计,筛选并确定了影响因素中对Cu和Si的分选效率有显著影响的主效应和交互作用,并通过响应优化对Cu的分选效率进行了优化,得到Cu的最佳参数为U=20 kV、n=65 r/min、S=90 mm、θ=-10°.在最佳参数条件下,进行了验证实验,Cu分选效率达到了97.91%,得到了良好的优化效果.     

22-轮SMS4的差分分析

SMS4是中国官方公布的第一个商用分组密码标准,使用差分方法分析了18轮的SMS4差分特征,并在此基础上攻击了22-轮的SMS4,攻击过程需要2117个选择明文,2112字节的存储空间,而时间复杂度为2123次22-轮加密。此结果是目前对SMS4差分分析的最好结果。     

甲烷在氧化钼系催化剂上的选择氧化

以MoO_3-SiO_2为主催化剂,研究了助剂Fe、Co的催化作用。Fe的加入,提高了催化剂对甲烷的脱氢能力,从而提高生成HCHO的选择性;Co的掺入与Mo形成CoMoO_4相,改善了MoO_3在含水气氛中的稳定性。考察了空气作氧化剂取代N_2O进行CH_4选择氧化的可能性。反应过程中水的加入抑制了深度氧化反应的进行,使生成HCHO选择性提高。     

轻钢组合楼盖面内刚度和承载力计算方法研究

为研究冷弯薄壁型钢组合楼盖的面内刚度和承载能力,采用ABAQUS软件建立楼盖有限元模型,通过轻钢楼盖面内滞回试验结果进行验证.研究不同参数对楼盖模型面内刚度和承载力的影响规律,结果表明:改变楼盖梁尺寸、楼盖梁腹板开孔面积和间距以及扁钢带和刚性支撑件的布置方式对楼盖面内刚度和承载力影响较小,减小自攻螺钉连接间距和组合楼盖的长宽比能提高组合楼盖的面内刚度和承载力,在20～40 mm范围内改变楼板厚度对组合楼盖面内刚度和承载力存在一定影响.基于组合楼盖的破坏模式和受力机理,楼盖的面内极限承载力可通过单颗自攻螺钉连接的承载力和楼盖两侧自攻螺钉连接的数量进行估算.基于退化四折线模型,建立组合楼盖面内刚度的计算方法,为轻钢楼盖的工程设计与应用提供理论依据.     

几种信阳毛尖茶的化学成分研究

以信阳地区栽种茶树品种为材料,研究不同茶树品种和采摘时间茶叶中主要化学成分含量差异.结果表明:水溶性总糖含量(%)在同期春季茶样中差异不显著,含量范围为(8.69~9.62),冬茶中最高(20.90);总黄酮含量(%)在茶树品种间差异显著(P0.05),信阳本地种2最高(9.65);总游离氨基酸含量(%)在茶树品种间的差异极显著(P0.01),信阳本地种1(2.96)本地种2(1.86)福鼎大白茶(0.35),随采摘时间变化显著,且氨基酸种类及其含量差异不同;茶多酚总量(%)在春季茶样中含量范围为7.17~8.38,冬茶中含量最低(0.59),但单酚类物质含量(%)在茶树品种间差异较大,其中没食子酸、表儿茶素和表没食子儿茶素含量随采摘时间变化显著,而冬茶中除没食子酸含量比同种春茶增加81.69%外,其他单酚物质含量均显著下降;生物碱含量(%)在茶树品种间差异明显,随采摘时间延后而下降.     

Single crystalline 3C-SiC whiskers used for electrochemical detection of nitrite under neutral condition

Ionics - A new kind of nitrite sensor based on 3C-SiC whisker electrode was fabricated to electrochemically determine nitrite. Powder X-ray diffraction, field emission scanning electron microscope,...     

Structural elucidation of rat biliary metabolites of corynoxeine and their quantification using LC‐MSn

Corynoxeine (COR) is one of 4 bioactive oxindole alkaloids in Uncaria species. In this work two phase I metabolites, namely 11‐hydroxycorynoxeine (M1) and 10‐hydroxycorynoxeine (M2), and two phase II metabolites, namely 11‐hydroxycorynoxeine 11‐O‐β‐d ‐glucuronide (M3) and 10‐hydroxycorynoxeine 10‐O‐β‐d ‐glucuronide (M4), were detected in rat bile after oral dose of COR (0.105 mmol/kg), by optimized high‐performance liquid chromatography–tandem mass spectrometry (LC‐MSⁿ) with electrospray ionization in positive ion mode. Structures of M1–4 were determined by LC‐MSⁿ, nuclear magnetic resonance, circular dichroism and high‐resolution MS spectra. COR and its metabolites in rat bile were quantified by LC‐MSⁿ. The LC‐MSⁿ quantification methods for COR and its metabolites yielded a linearity with coefficient of determination ≥0.995 from 5.0 × 10^?10 to 5.0 × 10^?7 m . The recoveries of stability tests varied from 96.80 to 103.10%. Accuracy ranged from 91.00 to 105.20%. Relative standard deviation for intra‐day and inter‐day assay was <5.0%. After the oral dose 0.14% of COR was detected in rat bile from 0 to 8 h, in which in total 97.8% COR biotransformed into M1–4. M1 and M2 yielded 48.1 and 49.7%, which successively glucuronidated to M3 and M4 at 47.2 and 43.8%, respectively. Copyright © 2014 John Wiley & Sons, Ltd.