龙门移动式双驱进给系统定位误差补偿方法

针对双驱进给系统结构的特性,提出了双轴定位误差建模与补偿方法.分析影响双驱进给系统定位精度的误差来源,建立基于双轴误差数据的龙门移动式双驱进给系统的速度-位置定位误差预测模型.采用开放式数控系统,提出基于交叉耦合的双驱进给系统定位误差补偿方法.在误差补偿过程中考虑双轴动态耦合特性与同步误差和单轴跟随误差耦合作用对误差补偿的影响,并进行误差补偿实验验证.实验结果表明所提出的误差补偿方法提高了龙门移动式双驱进给系统的定位精度和同步精度.     

Influence of withdrawal rate on the porosity in a third-generation Ni-based single crystal superalloy

The influence of withdrawal rate on the porosity in a third-generation Ni-based single crystal superalloy was investigated by a quantitative evaluation method. The results showed that the withdrawal rate obviously effected on the average area fraction, number and diameter of porosities except their radius ratios. In consideration of the microstructure observation for dendrite arms, an optimized withdrawal rate was obtained with a minimum porosity level as about 125 μm s~(-1). Simultaneously, a threshold value for the acceptance level of porosities might be set as about 0.1% in order to fulfill the requirements for Ni-based single crystal casting in laboratory scale. Finally, the formation reason of porosity was discussed and it was concluded that the feeding for the volume shrinkage of the last solidified eutectic liquids from the residual liquids and the isolating effect of the morphologies of dendrite arms might be two key factors in controlling the porosities level in Ni-based single crystal superalloy.     

Probing the Catalytic Center of TiO<Subscript>2</Subscript>/SO<Subscript>4</Subscript><Superscript>2−</Superscript> Solid Superacid Catalyst by X-Band In Situ High-Temperature EPR Spectroscopy

Paramagnetic centers of the solid superacid catalyst in the sulfated TiO₂ are prone to the electron paramagnetic resonance (EPR) spectroscopy. The induction of the catalytic-active sites in TiO₂ powder presubmerged in H₂SO₄ solution as a function of the calcinated temperature of 293–873 K is investigated by X-band in situ continuous-wave EPR measurements. Sulfated-acid sites composed of the Ti³⁺ ion are formed upon calcination. The overall experimental results show that the population of these sites goes uphill with the elevating temperature, reaches a maximum at ~623 K and decreases afterward to close zero. During the process, the decomposition of the TiO₂/SO₄ ²⁻ leads to the formation of Ti³⁺ species and then to the increasing EPR signal amplitude, and the consecutive decomposition of the sulfur at higher temperature (>650 K) to the diminishing signal. The X-ray diffraction indicates that the introduction of SO₄ ²⁻ stabilizes the geometric structure in the anatase phase.     

模糊神经网络分析方法用于心肌缺血诊断的研究

介绍一种神经网络－模糊推理协作系统。神经网络有很好的学习能力和准确拟合任意非线性函数的能力。模糊模型将专家知识转换到神经网络中，然后把它应用于诊断系统，从而使得心血管疾病（心肌缺血）的诊断准确率大大提高。     

Preliminary results of the study on wind erosion in the Qinghai-Tibetan Plateau using137Cs technique

The worldwide fallout of caesium-137 (¹³⁷Cs) associated with the nuclear weapon tests during the 1950s and 1960s has provided a valuable man-made tracer for studies of soil erosion and sediment delivery. But relatively few researchers have used it to estimate wind erosion. In this note, the¹³⁷Cs technique is introduced into the studies of wind erosion and its modern processes in the Qinghai-Tibetan Plateau. Two¹³⁷Cs reference inventories of 982.11 and 2 376.04 Bq · m⁻² were established preminarily, distributed in the south and middle-north parts of the studied area respectively. By analyzing the patterns of¹³⁷Cs depth profiles from sampling sites, the aeolian processes of erosion and deposition in nearly 40 years have been revealed, i.e. the shrub coppice dunes (S1) and semi-fixed dunefields (S3) experienced the alternation of erosion and deposition, while the grasslands (S4, S6 and S7) and dry farmlands (S5) suffered erosion only. By using¹³⁷Cs model, the average wind erosion rates for shrub coppice dune (S1), semi-fixed dune fields (S3), dry farmlands (S5) and grasslands (S4, S6 and S7) were estimated to be 84.14, 69.43, 30.68 and 21.84 t · ha¹ · a⁻¹ respectively, averaging 47.59 t · ha⁻¹ · a⁻¹ for the whole plateau, which can be regarded as of the medium erosion standard. These results derived from Cs for the first time have significant implications for the further research of wind erosion and desertification control in the Qinghai-Tibetan Plateau.     

活性炭负载钛酸四丁酯催化合成二乙二醇二苯甲酸酯

以活性炭负载钛酸四丁酯为催化剂,正丁醚为带水剂,采用直接酯化法合成二乙二醇二苯甲酸酯(DEDB);运用低温氮气吸附脱附(BET)与电子顺磁共振波谱(ESR)分析对催化剂进行表征,采用IR和1HNMR进行反应产物的表征;探讨原料比、带水剂用量、反应温度等因素对酯化率的影响。确定了活性炭固载钛酸四丁酯催化二乙二醇(DEG)和苯甲酸(BA)酯化的适宜工艺条件为:原料量比n(DEG)∶n(BA)=1∶2,带水剂占苯甲酸质量分数为20%,催化剂占苯甲酸质量分数为1.5%,反应温度200℃,反应时间6 h。催化剂可循环使用3次,具有较好的稳定性。     

Solid–Liquid Equilibrium for the Ternary System 2-Methyl-4-Nitroaniline + 2-Methyl-6-Nitroaniline + Ethyl Acetate: Determination and Modelling

The solid–liquid phase equilibria for the ternary system 2-methyl-4-nitroaniline + 2-methyl-6-nitroaniline + ethyl acetate was determined experimentally by the method of isothermal solution saturation at temperatures of (293.15, 303.15 and 313.15) K under the pressure of 101.2 kPa. Based on the obtained solubility data, the isothermal phase diagrams of the system were constructed. At each temperature, there are two pure solid phases formed, which correspond to pure 2-methyl-4-nitroaniline and pure 2-methyl-6-nitroaniline, which was confirmed by Schreinemakers’ wet residue method and X-ray powder diffraction. The crystallization regions of pure 2-methyl-4-nitroaniline and pure 2-methyl-6-nitroaniline increased with decreasing temperature. The crystalline region of 2-methyl-4-nitroaniline was larger than that of 2-methyl-6-nitroaniline at a fixed temperature. The solubility data were correlated with the NRTL and Wilson models. The values of the root-mean-square deviations are 5.01 × 10^?3 for the NRTL model, and 6.43 × 10^?3 for the Wilson model. The solid–liquid equilibria, phase diagrams and the thermodynamic models for the ternary system can provide the foundation for separating 2-methyl-6-nitroaniline or 2-methyl-4-nitroaniline from its mixtures.     

心率变异性检测系统的研究

以１６位单片机８０９８作为核心处理芯片，采用宏汇编语言编写程序软件，设计并制作了一台短时心率变异性测定仪．在其数学处理过程中，应用了混沌理论和小波变换技术．该测定仪具有体积小、重量轻、集成度高、抗干扰能力强、稳定性好及安全可靠等特点．它完全可以替代国外同类产品而用于临床检测     

通用防引导型计算机病毒软件

从引导型病毒破坏机理入手，根据磁盘结构特征，进行分析设计出了一种消除软盘、硬盘中的引导型病毒的通用计算机防毒软件．实际运用表明，该软件能有效的消除各种引导型病毒，特别是，对编辑、出版、印刷等行业，以及办公室自动化的微机防毒极其有用，是微机人员防病、杀毒、防止病毒传染的利器．此外．笔者所编程序，是直接对磁盘引导区进行分析操作的一种机器语言，它对于读者了解计算机磁盘结构，编写计算机程序，无疑是一个典型的范例．