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11.
Xiaohua He Hailiang Zhang Deyue Yan Xiayu Wang 《Journal of polymer science. Part A, Polymer chemistry》2003,41(18):2854-2864
A series of side‐chain liquid‐crystalline (LC) homopolymers of poly[6‐(4‐methoxy‐4′‐oxy‐azobenzene) hexyl methacrylate] with different degrees of polymerization were synthesized by atom transfer radical polymerization (ATRP), which were prepared with a wide range of number‐average molecular weights from 5.1 × 103 to 20.6 × 103 with narrow polydispersities of around 1.17. Thermal investigation showed that the homopolymers exhibit two mesophases, a smectic phase, and a nematic phase, and the phase‐transition temperatures of the homopolymers increase clearly with increasing molecular weights. A series of novel LC coil triblock copolymers with narrow polydispersities was synthesized by ATRP, and their thermotropic phase behavior was investigated with differential scanning calorimetry and polarized optical microscopy. The LC coil triblocks were designed to have an LC conformation of poly[6‐(4‐methoxy‐4′‐oxy‐azobenzene) hexyl methacrylate] with a wide range of molecular weights from 3.5 × 103 to 1.7 × 104 and the coil conformation of poly(ethylene glycol) (PEG) (number‐average molecular weight: 6000 or 12,000) segment. Their characterization was investigated with 1H NMR, Fourier transform infrared spectra, and gel permeation chromatography. Triblock copolymers exhibited a crystalline phase, a smectic phase, and a nematic phase. The phase‐transition temperatures from the smectic to nematic phase and from the nematic to isotropic phase increased, and the crystallization of PEG depressed with increasing molecular weight of the LC block. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2854–2864, 2003 相似文献
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Hydroxyapatite coating on porous silicon substrate obtained by precipitation process 总被引:2,自引:0,他引:2
Chen Shaoqiang Zhu Ziqiang Zhu Jianzhong Zhang Jian Shi Yanling Yu Ke Wang Weiming Wang Xiaohua Feng Xiao Luo Laiqiang Shao Li 《Applied Surface Science》2004,230(1-4):418-424
Hydroxyapatite Ca10(PO4)6(OH)2 (HAP) is known as a bioactive and biocompatible material, HAP coatings were used to improve the biocompatible of substrate by many researcher, In this work, HAP thin films on porous silicon (PS) substrates have been prepared by aqueous precipitation method with rapid thermal annealing (RTA) processes. The HAP films had been prepared under the annealing temperature ranging from 300 to 1000 °C. By the measurement of X-ray diffraction (XRD), it was found that for the crystallinity optimization, the heat-treatment at 850–950 °C for 1 h would be favorable. Atomic force microscopy (AFM) and scanning electron microscope (SEM) measurements reveal a dense and smooth surface of the HAP film, and tightly adherence of the coating on porous silicon substrate after sintered. Thus, by this method, porous silicon could be increased its bioactivity and so that could be used in the biomedical area. 相似文献
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研究了C60分别在有机玻璃(PMMA)和正己烷中的吸收光谱,发现C60在有机玻璃中的吸收峰同在正己烷中相互对应,同时前者的吸收峰相对于后者峰宽变大,峰位产生红移,分析了产生这种现象的原因。 相似文献
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快速响应的温敏性聚(N-异丙基丙烯酰胺)水凝胶 Ⅰ.以CaCO_3为成孔剂制备方法、表征及动力学研究 总被引:1,自引:0,他引:1
以不同粒径的CaCO3粒子为成孔剂 ,合成了快速响应的温敏性聚 (N 异丙基丙烯酰胺 ) (PNIPA)水凝胶 .利用扫描电镜观察到水凝胶具有特殊的孔状结构 ,得到水凝胶的孔径大小为几十微米左右 .动力学研究表明 ,该水凝胶在温敏膨胀或收缩时 ,具有快速的响应速率 ,在 10min内的失水率可达 90 % .比较了干凝胶和4 0℃下失水后的凝胶两种不同状态下水凝胶的膨胀曲线 ,发现两者的溶胀动力学曲线明显不同 ,前者的曲线有拐点 .同时发现与失水收缩速率相比 ,水凝胶具有较慢的吸水膨胀速率 . 相似文献
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Asymmetric syntheses of (2S,3S)-3-(tert-butoxycarbonyl)-2-piperidinecarboxylic acid (1b), (3R,4S)-4-(tert-butoxycarbonyl)-3-piperidinecarboxylic acid (2b), and their corresponding N-Boc and N-Cbz protected analogues 8a,b and 17a,b are described. Enantiomerically pure 1b has been synthesized in five steps starting from L-aspartic acid beta-tert-butyl ester. Tribenzylation of the starting material followed by alkylation with allyl iodide using KHMDS produces the key intermediate 5a in a 6:1 diastereomeric excess. Upon hydroboration, the alcohol 6a is oxidized, and the resulting aldehyde 7 is subjected to a ring closure via reductive amination, providing 1b in an overall yield of 38%. Optically pure 2b has been synthesized beginning with N-Cbz-beta-alanine. The synthesis involves the induction of the first stereogenic center using Evans's chemistry and sequential LDA-promoted alkylations with tert-butyl bromoacetate and allyl iodide. Further elaboration by ozonolysis and reductive amination affords 2b in an overall yield of 28%. 相似文献