Mixed-cation perovskite solar cells in space

<正>The metal halide perovskite materials demonstrate outstanding performance in photovoltaics because of their excellent optoelectronic properties [1-7]. The perovskite solar cells (PSCs) exhibiting outstanding efficiency [8,9], high power-per-weight [10], and excellent radiation resistance[11-13] are considered to be promising for developing the new-generation energy technology for space application.However, the extreme space environment would impose     

康威-麦斯威尔-泊松分布及其统计与概率性质

康威-麦斯威尔-泊松分布是一个有用的离散分布,它是扩展的两参数泊松分布,有关此分布的统计和概率性质被广泛研究和探索;文章以矩母函数为工具讨论了该分布的数字特征和矩,给出了参数点估计的隐式方程和费希尔信息矩阵;最后研究了参数的共轭分布、共轭分布的边际分布和条件分布.     

Improving imprinted shape cavities of molecularly imprinted sol–gel host matrix with minimal relaxation for sensing of creatinine

Journal of Sol-Gel Science and Technology - Molecularly imprinted polymer (MIP) is of great attention in biomimetic recognition systems due to its selective molecular recognition towards any guest...     

Harvesting of a phytoplankton–zooplankton model

Considering that some phytoplankton and zooplankton are harvested for food, a phytoplankton–zooplankton model with harvesting is proposed and investigated. First, stability conditions of equilibria and existence conditions of a Hopf-bifurcation are established. Our results indicate that over exploitation would result in the extinction of the population and an appropriate harvesting strategy should ensure the sustainability of the population which is in line with reality. Furthermore, the existence of bionomic equilibria and the optimal harvesting policy are discussed. The present value of revenues is maximized by using Pontryagin’s maximum principle subject to the state equations and the control constraints. We discussed the case of optimal equilibrium solution. It is found that the shadow prices remain constant over time in optimal equilibrium when they satisfy the transversality condition. It is established that the zero discounting leads to the maximization of economic revenue and that an infinite discount rate leads to complete dissipation of economic rent. Finally, some numerical simulations are given to illustrate our results.     

Novel shooting method with simple control strategy for fiber lasers

A novel shooting method with excellent simple control strategy is developed for solving the failure to convergence of the traditional shooting methods themselves in fiber lasers model. Compared with the published literature, the novel shooting method provides a clear physical understanding method for getting the threshold pump power and the exact results with given random functions in Yb³⁺-doped fiber lasers and Er³⁺-doped fiber lasers. Then, the results in Er³⁺-doped fiber lasers and Yb³⁺-doped fiber lasers demonstrate that the solutions using the novel shooting method has high accuracy of 10⁻⁸ W with several iteration steps, which have extended the applicable range of the end-pumped power even lower than 1 mW pump power. Furthermore, compared with 1480 nm pump for the threshold and slope efficiencies of the Er³⁺-doped fiber lasers, 978 nm fiber lasers can extend wider scope of application and be pump source in the coming future. Finally, the lower threshold and higher slope efficiency at 975 nm than those of 910 nm pump in Yb³⁺-doped fiber lasers, 975 nm pump laser provides for broad band excellent cladding pump source.     

The first pulsar discovered by FAST

<正>To assist with the commissioning [1] of the Five-hundredmeter Aperture Spherical radio Telescope (FAST), we performed a pulsar search, with the primary goal of developing and testing the pulsar data acquisition and processing pipelines. We tested and used three pipelines, two (P1 and P2 hereafter) searched for the periodic signature of pulsars     

Ni80Fe20 permalloy nanoparticles: Wet chemical preparation, size control and their dynamic permeability characteristics when composited with Fe micron particles

Ni₈₀Fe₂₀ permalloy nanoparticles (NPs) have been prepared by the polyol processing at 180 °C for 2 h and their particle sizes can be precisely controlled in the size range of 20-440 nm by proper addition of K₂PtCl₄ agent. X-ray diffraction results show that the Ni-Fe NPs are of FCC structure, and a homogeneous composition and a narrow size distribution of these NPs have been confirmed by scanning electron microscopy assisted with energy dispersion spectroscopy of X-ray (SEM-EDX). The saturation magnetization of ~440nm NPs is 80.8 emu/g that is comparable to that of bulk Ni₈₀Fe₂₀ alloys, but it decreases to 28.7 emu/g for ~20 nm NPs. The coercive force decreases from 90 to 3 Oe with decreasing NP size. The wide range of particle size is exploited to seek for high permeability composite particles. The planar type samples composed of the NiFe NPs exhibit low initial permeability due to the deteriorated magnetic softness and low packing density. However, when they are mixed with Fe micron particles, the initial permeability significantly increases depending on the mixing ratio and the NiFe NP size. A maximum initial permeability is achieved to be ~9.1 at 1 GHz for the Fe-10 vol%NiFe (~20 nmΦ), which is about three times that of pure Fe micron particles. The effects of Ni-Fe particle size, volume percentage and solvent on the static and dynamic permeability are discussed.     

物理气相沉积法制备TP/TFA纳米薄膜与光致发光特性探究

为了探究有机荧光材料在微纳尺寸上的荧光特性,采用低真空物理气相沉积方法制备了茶碱（TP）和2,3,5,6-四氟对苯二甲酸（TFA）有机纳米薄膜。通过对TP和TFA薄膜的荧光性质进行表征发现：与TP粉末相比薄膜的荧光发射峰由1个增加到4个,发射波长范围拓宽了100 nm,TFA的荧光发射峰之间的相对荧光强度发生了变化,与原料粉末相比在408 nm处的荧光发射峰蓝移了7 nm,362 nm处的荧光发射峰红移了3 nm。另外随着纳米薄膜厚度的逐渐增加,其荧光效率也逐渐增大。通过对TP和TFA纳米薄膜的表面形貌表征发现：随着薄膜厚度的增加,颗粒的聚集形态尺寸逐渐增大,从而验证了荧光效率随膜厚增加而逐渐提升的特性。     

Bifunctional Phosphine Ligand Enabled Gold‐Catalyzed Alkynamide Cycloisomerization: Access to Electron‐Rich 2‐Aminofurans and Their Diels–Alder Adducts

By using biphenyl‐2‐ylphosphines functionalized with a remote tertiary amino group as a ligand, readily available acetylenic amides are directly converted into 2‐aminofurans devoid of any electron‐withdrawing and hence deactivating/stabilizing substituents. These highly electron‐rich furans have rarely been prepared, let alone applied in synthesis, because of their high reactivities and low stabilities associated with the electron‐rich nature of the furan ring. In this work, these reactive furans smoothly undergo either in situ intermolecular Diels–Alder reactions to deliver highly functionalized/substituted aniline products or intramolecular ones to furnish carbazole‐4‐carboxylates in mostly good to excellent yields. This work offers general and expedient access to this class of little studies electron‐rich furans and should lead to exciting opportunities for their applications.