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991.
针对第一阶模态主参激共振条件下的大范围直线运动梁系统,利用稳定性分析、中心流形定理和规范型理论等解析方法,给出了梁系统的初始平衡解和静态分岔解及其稳定性情况. 相似文献
992.
Hydrogels resulting from the self-assembly of small peptides are smart nanobiomaterials as their nanostructuring can be readily tuned by environmental stimuli such as pH,ionic strength and temperature,thereby favoring their practical applications.This work reports experimental observations of formation of peptide hydrogels in response to the redox environment.Ac-I 3 K-NH 2 is a short peptide amphiphile that readily self-assembles into long nanofibers and its gel formation occurs at concentrations of about 10 mmol/L.Introduction of a Cys residue into the hydrophilic region leads to a new molecule,Ac-I 3 CGK-NH 2,that enables the formation of disulfide bonds between self-assembled nanofibers,thus favoring cross-linking and promoting hydrogel formation.Under oxidative environment,Ac-I 3 CGK-NH 2 formed hydrogels at much lower concentrations(even at 0.5 mmol/L).Furthermore,the strength of the hydrogels could be easily tuned by switching between oxidative and reductive conditions and time.However,AFM,TEM,and CD measurements revealed little morphological and structural changes at molecular and nano dimensions,showing no apparent influence arising from the disulfide bond formation. 相似文献
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995.
Youjun He Yi Zhou Guangjin Zhao Jie Min Xia Guo Bo Zhang Maojie Zhang Jing Zhang Yongfang Li Fengling Zhang Olle Inganäs 《Journal of polymer science. Part A, Polymer chemistry》2010,48(8):1822-1829
A new benzodithiophene (BDT)‐based polymer, poly(4,8‐bis(2‐ethylhexyloxy)benzo[1,2‐b:4,5‐b′]dithiophene vinylene) (PBDTV), was synthesized by Pd‐catalyzed Stille‐coupling method. The polymer is soluble in common organic solvents and possesses high thermal stability. PBDTV film shows a broad absorption band covering from 350 nm to 618 nm, strong photoluminescence peaked at 545 nm and high hole mobility of 4.84 × 10?3 cm2/Vs. Photovoltaic properties of PBDTV were studied by fabricating the polymer solar cells based on PBDTV as donor and PC70BM as acceptor. With the weight ratio of PBDTV: PC70BM of 1:4 and the active layer thickness of 65 nm, the power conversion efficiency of the device reached 2.63% with Voc = 0.71 V, Isc = 6.46 mA/cm2, and FF = 0.57 under the illumination of AM1.5, 100 mW/cm2. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1822–1829, 2010 相似文献
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研究了在外磁场作用下铁磁双层薄膜材料中自旋波的本征值问题.采用界面重参数化方法,在周期性边界条件下,严格求解系统的三种本征模,并给出横向自旋波取全部值的能带结构图,讨论了外磁场对自旋波能带的影响. 相似文献
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Pheophorbide a (Pa) from Chinese herbal medicine Scutellaria Barbata and Silkworm excreta has been proved to be potential photosensitizer. The present study investigated the cytotoxicity of ovarian cancer cells
induced by LED-activated Pa using light microscopy with the SRB staining. We further investigated the apoptosis of the cells
6 h after LED-activated Pa using of the flow cytometer with PI staining and nuclear staining. The results showed that LED-activated
Pa remarkably caused cell death of ovarian cancer cells. The condensation of chromatin, nuclear fragmentations, and 12.3%
of cells containing subdiploid levels of DNA were found in the ovarian cancer cells after the treatment of LED-activated Pa.
These data demonstrated that LED-activated Pa could cause significant cytotoxicity and apoptosis of ovarian cancer cells. 相似文献