离散式任意充磁角度Halbach永磁电机解析模型研究

Halbach电机因其自身优势在新型船舶推进、海洋洋流发电等方面受到广泛关注. 本文在假设铁磁材料线性和定子内表面光滑的条件下, 通过将任意充磁角度Halbach阵列等效为两组90° Halbach(或180° Halbach)阵列的矢量合成, 提出了一种分析离散式任意充磁角度Halbach永磁电机气隙磁场的解析方法; 通过对电机中磁标量势的傅里叶级数进行计算, 推导出了最简单的90° Halbach永磁电机在极坐标系下的气隙磁密表达式, 并在此基础上, 给出了任意充磁角度Halbach电机永磁体磁化强度在一个极下的表达式, 进而得出任意充磁角度Halbach电机气隙磁密的分布, 并分析了气隙磁密与电机极对数、永磁体厚度和充磁角度间的关系. 最后通过有限元和试验结果验证了本文方法的正确性. 关键词： 离散式Halbach电机 任意充磁角度 矢量等效 解析模型     

Pt/C催化剂中纳米Pt颗粒团聚效应的小角X射线散射

 应用小角X射线散射(SAXS)技术,对乙二醇合成法、浸渍还原法和微波加热法制备的Pt/C催化剂粉体内纳米Pt颗粒的团聚效应进行了研究,得到了不同方法制备的Pt颗粒及其团聚体的特征尺寸、体积分布、表面积变化、团聚程度等信息,并利用透射电镜（TEM）对3种样品进行了测试。实验结果表明:微波加热法制备的催化剂中,Pt颗粒较好地分散于C载体上,且Pt颗粒具有尺度小、分布范围窄、总表面积大和团聚体较少等特征;常规浸渍和乙二醇还原两种方法制备的催化剂中Pt颗粒大小分布相似,但乙二醇还原法制备的催化剂总表面积和团聚体尺度更大,数量也更多。     

Synthesis and thermal energy storage properties of the polyurethane solid–solid phase change materials with a novel tetrahydroxy compound

Based on the phase change theory, a novel tetrahydroxy compound (THCD) was designed and prepared. Depending on the spatial structure of the tetrahydroxy compound, a form-stable thermoplastic polyurethane solid–solid phase change material (TPUPCM) was synthesized via employing PEG as soft segments, while multi-benzene ring structure made by 4,4′-diphenylmethane diisocyanate and tetrahydroxy compound as hard segments. The composition and structure of THCD and TPUPCM, the TPUPCM’s the weight average molecular weight and number average molecular weight, dissolving and melting abilities, phase change behaviors, thermal performances and crystalline morphology were investigated by Fourier transform infrared spectrometer, ¹H nuclear magnetic resonance spectrometer, multiangle laser light scattering apparatus, differential scanning calorimentry, dynamic mechanical thermal analysis, thermogravimetry analysis system, wide-angle X-ray diffraction, polarizing optical microscopy. The results show that the solid–solid phase change material owns excellent phase change properties and a broad processing temperature range. The heating cycle phase change enthalpy is 137.4 J/g, and the cooling cycle phase change enthalpy is 127.6 J/g. The started decomposition temperature and the maximum decomposition temperature are at 323.5 and 396.2 °C, respectively. Furthermore, the solid–solid phase change material is dissolvable, meltable and can be processed directly, and has great potential applications in thermal energy storage.     

The global dimensions of crossed products and crossed coproducts

In this paper, we show that if H is a finite-dimensional Hopf algebra such that H and H^＊ are semisimple, then gl.dim（A#σH）=gl.dim（A）, where a is a convolution invertible cocycle. We also discuss the relationship of global dimensions between the crossed product A^#σH and the algebra A, where A is coacted by H. Dually, we give a sufficient condition for a finite dimensional coalgebra C and a finite dimensional semisimple Hopf algebra H such that gl.dim（C α H）=gl.dim（C）.     

Chemical equilibrium controlled synthesis of polyoxymethylene dimethyl ethers over sulfated titania

The chemical equilibrium and reaction kinetic behavior in the synthesis of polyoxymethylene dimethyl ethers(DMMn) were investigated over sulfated titania in order to reveal the decisive factor controlling the reaction. The results showed that the molar ratio of adjacent DMMn products in equilibrium solution had the same value, which depended absolutely on the reaction temperature. Meanwhile, the reactions had the same DMMn products distributions under varied reaction conditions. The equilibrium constants of the related step-wise reactions for DMMn formation were equal, which were calculated based on the bulk compositions of the reaction solution. And thus, the selectivity to DMMn was mainly controlled by the chemical equilibrium, i.e., thermodynamic control. In brief, the present results provide some guidance for future synthesis of DMMn.     

Effect of blue light radiation on curcumin-induced cell death of breast cancer cells

In the present study, we have successfully set up a novel blue light source with the power density of 9 mW/cm² and the wavelength of 435.8 nm and then the novel light source was used to investigate the effect of light radiation on curcumin-induced cell death. The cytotoxicity was investigated 24 h after the treatment of curcumin and blue light radiation together using MTT reduction assay. Nuclear chromatin was observed using a fluorescent microscopy with Hoechst33258 staining. The results showed blue light radiation could significantly enhance the cytotoxicity of curcumin on the MCF-7 cells and apoptosis induction. These findings demonstrated that blue light radiation could enhance curcumin-induced cell death of breast cancer cells, suggesting light radiation may be an efficient enhancer of curcumin in the management of breast cancer.     

Room temperature synthesis of water-repellent polystyrene nanocomposite coating

A stable superhydrophobic polystyrene nanocomposite coating was fabricated by means of a very simple and easy method. The coating was characterized by scanning electron microscopy and X-ray photoelectron spectrum. The wettability of the products was also investigated. By adding the surface-modified SiO₂ nanoparticles, the wettability of the coating changed to water-repellent superhydrophobic, not only for pure water, but also for a wide pH range of corrosive liquids. The influence of the drying temperature and SiO₂ content on the wettability of the nanocomposite coating was also investigated. It was found that both factors had little or no significant effect on the wetting behavior of the coating surface.     

Interaction mechanisms of U(VI) and graphene oxide from the perspective of particle size distribution

Graphene oxide (GO) is an ideal adsorbent due to excellent physicochemical properties. Humic acid (HA) is ubiquitous in aquatic and soil environment, which can affect the migration of metal ions. In this study, we investigated the sorption mechanisms of U(VI) onto GO surfaces in the presence of HA. pH dependent and ionic strength independent sorption process were observed and the concentration of HA is positively proportional to U(VI) sorption capacities. Results also suggest that a pre-mixing HA + U(VI) gave better results than a pre-mixing of GO + HA, which can be explained by the size distribution of different GO systems.