全文获取类型
收费全文 | 14930篇 |
免费 | 1747篇 |
国内免费 | 1549篇 |
专业分类
化学 | 7127篇 |
晶体学 | 157篇 |
力学 | 423篇 |
综合类 | 116篇 |
数学 | 1165篇 |
物理学 | 3616篇 |
综合类 | 5622篇 |
出版年
2024年 | 57篇 |
2023年 | 215篇 |
2022年 | 431篇 |
2021年 | 444篇 |
2020年 | 438篇 |
2019年 | 485篇 |
2018年 | 363篇 |
2017年 | 376篇 |
2016年 | 500篇 |
2015年 | 644篇 |
2014年 | 850篇 |
2013年 | 1013篇 |
2012年 | 1183篇 |
2011年 | 1213篇 |
2010年 | 992篇 |
2009年 | 1020篇 |
2008年 | 1083篇 |
2007年 | 991篇 |
2006年 | 854篇 |
2005年 | 711篇 |
2004年 | 566篇 |
2003年 | 421篇 |
2002年 | 403篇 |
2001年 | 352篇 |
2000年 | 281篇 |
1999年 | 365篇 |
1998年 | 294篇 |
1997年 | 247篇 |
1996年 | 231篇 |
1995年 | 213篇 |
1994年 | 185篇 |
1993年 | 146篇 |
1992年 | 149篇 |
1991年 | 124篇 |
1990年 | 96篇 |
1989年 | 79篇 |
1988年 | 59篇 |
1987年 | 51篇 |
1986年 | 38篇 |
1985年 | 30篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
971.
A stable superhydrophobic polystyrene nanocomposite coating was fabricated by means of a very simple and easy method. The coating was characterized by scanning electron microscopy and X-ray photoelectron spectrum. The wettability of the products was also investigated. By adding the surface-modified SiO2 nanoparticles, the wettability of the coating changed to water-repellent superhydrophobic, not only for pure water, but also for a wide pH range of corrosive liquids. The influence of the drying temperature and SiO2 content on the wettability of the nanocomposite coating was also investigated. It was found that both factors had little or no significant effect on the wetting behavior of the coating surface. 相似文献
972.
Wang Yanan Liu Xia Huang Yongshun Hayat Tasawar Alsaedi Ahmed Li Jiaxing 《Journal of Radioanalytical and Nuclear Chemistry》2017,311(1):209-217
Graphene oxide (GO) is an ideal adsorbent due to excellent physicochemical properties. Humic acid (HA) is ubiquitous in aquatic and soil environment, which can affect the migration of metal ions. In this study, we investigated the sorption mechanisms of U(VI) onto GO surfaces in the presence of HA. pH dependent and ionic strength independent sorption process were observed and the concentration of HA is positively proportional to U(VI) sorption capacities. Results also suggest that a pre-mixing HA + U(VI) gave better results than a pre-mixing of GO + HA, which can be explained by the size distribution of different GO systems.
相似文献973.
选取自然资源环境、经济环境、基础设施环境、社会服务环境、人口劳动力环境和社会文化环境6个子系统的18个指标构建了城市投资环境指标体系,以陕西省下属的10个地级市为研究对象,采用因子分析的方法,对陕西省城市投资环境进行了实证分析。 相似文献
974.
We studied the evolution of cooperation in the prisoner’s dilemma game on a square lattice where the size of the interaction neighborhood is considered. Firstly, the effects of noise and the cost-to-benefit ratio on the maintenance of cooperation were investigated. The results indicate that the cooperation frequency depends on the noise and cost-to-benefit ratio: cooperation reaches a climax as noise increases, but it monotonously decreases and even vanishes with the ratio increasing. Furthermore, we investigated how the size of the interaction neighborhood affects the emergence of cooperation in detail. Our study demonstrates that cooperation is remarkably enhanced by an increase in the size of the interaction neighborhood. However, cooperation died out when the size of the interaction neighborhood became too large since the system was similar to the mean-field system. On this basis, a cluster-forming mechanism acting among cooperators was also explored, and it showed that the moderate range of the neighborhood size is beneficial for forming larger cooperative clusters. Finally, large-scale Monte Carlo simulations were carried out to visualize and interpret these phenomena explicitly. 相似文献
975.
根据效应分层原理,低阶效应比高阶效应更重要.在这种情况下,以别名集的结构为基础,提出了最小低阶效应混杂准则对2n-m设计进行排序.研究了新准则与其它最优性准则,即最大分辨度、最小低阶混杂、纯净效应和最大估计容量准则的联系.给出了具有16和32个水平组合的最小低阶效应混杂设计. 相似文献
976.
977.
Liang-Deng Nie Fei-Feng Wang Wei Ding Xiao-Xin Shi Xia Lu 《Tetrahedron: Asymmetry》2013,24(11):638-642
A novel azide-free asymmetric synthesis of oseltamivir phosphate 1 (Tamiflu®) starting from Roche’s epoxide is described. Roche epoxide 2 was converted into N-acetyl aminoalcohol 3 in 95% yield via a BF3·OEt2-catalyzed epoxide-opening with acetonitrile as a nucleophile. Compound 3 was then transformed into a methanesulfonate 4 in 98% yield. Compound 4 was converted into aziridine 5 in 91% yield. Aziridine 5 was subsequently converted into oseltamivir phosphate 1 via two paths (a and b). In the path a, compound 5 underwent aziridine-opening with diallylamine as a nucleophile to afford compound 7 in 93% yield; compound 7 could then be converted into oseltamivir phosphate 1 in 88% yield. In path b, compound 5 underwent aziridine-opening with isopropyl 2,2,2-trichloroacetimidate as a nucleophile to afford compound 8 in 94% yield, which was then converted into oseltamivir phosphate 1 in 82% yield. 相似文献
978.
979.
980.
Isothermal fatigue (IF) tests were performed on H13 tool steel subjected to three different mechanical strain amplitudes at a constant temperature to determine the effects of mechanical strain amplitude on the microstructure of the steel samples. The samples' extent of damage after IF tests was compared by observation of their cracks and calculation of their damage parameters. Optical microscopy (OM) and scanning electron microscopy (SEM) were used to observe the microstructure of the samples. Cracks were observed to initiate at the surface because the strains and stresses there were the largest during thermal cycling. Mechanical strain accelerated the damage and softening of the steel. A larger mechanical strain caused greater deformation of the steel, which made the precipitated carbides easier to gather and grow along the deformation direction, possibly resulting in softening of the material or the initiation of cracks. 相似文献