Ultrasound-promoted Lipase-catalyzed Enantioselective Transesterification of (R,S)-Glycidol

Enantioselective transesterification of glycidol with vinyl butyrate as an acyl donor was investigated in the presence of Bacillus subtilis lipase(BSL2) as catalyst. Comparison studies demonstrate the advantage of ultrasound over the conventional shaking for the enzymatic reaction in non-aqueous media. The effects of reaction conditions(ultrasound power, temperature, water activity and pH) on the activity and enantioselectivity were also investigated. Under the optimum conditions, the synthetic activity of BSL2 was 2.95 μmol·min?1·mg?1 and the enantioselectivity(E value) was 52.2. Compared with conventional shaking, ultrasound made the synthetic activity and the enantioselectivity increase 9.5-fold and 1.4-fold, respectively. Furthermore, the repeated use of BSL2 for five cycles resulted in no obvious loss of enzyme activity, suggesting that the enzyme is stable under low power ultrasound conditions.     

语料库自然标注信息与中文分词应用研究

以中文分词为应用目标, 将大规模语料库上存在的自然标注信息分为显性标注信息与隐性标注信息, 分别考察了它们的分布和对大数据集上语言计算的影响。结果表明, 两者都直接或间接地表达了作者对语言的分割意志, 因而对分词具有积极的影响。通过词语抽取测试, 发现在缺乏丰富显性标注信息的文本中, 来自语言固有规律的自然标注信息对字符串有着强大的分割性能。     

Acylation of Quercetin with a Novel Thermophilic Esterase as Biocatalyst

The regioselective acylation of quercetin catalyzed by a novel thermophilic esterase(APE1547)from the archaeon Aeropyrum pernix K1 was successfully conducted in organic solvents.The effects of acyl don...     

酚类天然产物Buxifoximes A的合成及生物活性

利用商品化试剂4-羟基苯甲酰甲醛水合物(3)为起始原料,与甲氧基胺盐酸盐经一步肟化反应,以79%的收率合成了酚类天然产物Buxifoximes A(1).同时还经已知反应步骤合成了Buxifoximes A的天然类似物2.初步的抗肿瘤生物活性测试表明,二者对MV4-11细胞表现出了优秀的抑制作用,同时探讨了构效关系.     

工业废料对含有机质水泥土强度影响的试验研究

结合试验,研究了磷石膏、粉煤灰等工业废料对含有机质土强度的影响,探讨了抗有机质影响的措施。试验表明,在水泥中掺适当的工业废料做加固土的固化剂,不仅可以节约工程造价,而且可以增加加固土的强度。     

基于CFD的活性炭烟气脱硫数值模拟

以移动床作为吸附装置,建立了反应器三维非稳态流动和传热的数学模型,将活性炭对烟气中SO2的吸附作为研究对象,利用CFD软件对移动床内的SO3浓度场、烟气速度场和压力场进行模拟计算,研究了烟气入口速度、烟气入口SO2浓度等因素对脱硫效率的影响。结果表明:反应器入口片脱硫效果明显,出口处脱硫效果减弱。为增大脱硫效果,应增大活性炭下移速度或降低烟气速度。     

第13届亚洲物理奥林匹克竞赛实验试题简介

第13届亚洲物理奥林匹克竞赛的2道实验试题为"摩擦系数"和"电磁感应".本文较全面地介绍了试题内容并给出了解答.     

1+1维Wolf-Villain模型奇异标度行为的数值模拟

采用Kinetic Monte Carlo(KMC)方法对描述分子束外延生长(MBE)的1+1维Wolf-Villain模型进行大尺寸和长生长时间的数值模拟研究,以消除渡越行为的影响.计算得到整体和局域标度指数.结果显示,在所模拟的空间和时间尺度范围内,1+1维Wolf-Villain模型仍呈现出固有奇异标度行为.这一结论与López等人最近的理论分析结果不一致.     

Station Model for Rail Transit System Using Cellular Automata

In this paper, we propose a new cellular automata model to simulate the railway traffic at station. Based on NaSch model, the proposed station model is composed of the main track and the siding track. Two different schemes for trains passing through station are considered. One is the scheme of ＂pass by the main track, start and stop by the siding track＂. The other is the scheme of ＂two tracks play the same role＂. We simulate the train movement using the proposed model and analyze the traffic flow at station. The simulation results demonstrate that the proposed cellular automata model can be successfully used for the simulations of railway traffic. Some characteristic behaviors of railway traffic flow can be reproduced. Moreover, the simulation values of the minimum headway are close to the theoretical values. This result demonstrates the dependability and availability of the proposed model.     

一种入侵检测系统快速模式匹配算法

模式匹配是应用于入侵检测系统中的的主要技术之一,匹配算法的好坏直接影响入侵检测系统的效率,本文在分析BM及其改进算法的基础上,提出了一种快速的BME算法.该算法结合了BMH算法和BMHS算法的优点,有效地减少了比较次数,加快了匹配速度.试验测试结果表明该算法能够有效提高网络入侵检测系统的效率.