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51.
徐淮良  蒋占魁 《中国物理快报》2005,22(11):2798-2800
Radiative lifetimes of two short-lived levels (i.e. 4f^8 (TF6)6p^1/2 (6, 1/2)11/2,13/2) in Tb Ⅲ are measured by time-resolved laser-induced fluorescence (LIE) technique with a two-step excitation process. Free Tb Ⅲ ions are produced in a laser-induced plasma. Lifetime values are evaluated with a deconvolution procedure of the timeresolved fluorescence signal with the temporal shape of second-step excitation pulse (about 1 ns). The lifetimes of the 4f^8 (^7F6)6p^1/2 (6, 1/2)11/2 and 4f^8(^7F6)6p^1/2 (6, 1/2)13/2 levels are determined to be 1.9 (2) and 2.0 (2)ns, respectively.  相似文献   
52.
Three‐component photoinitiators comprised of an N‐arylphthalimide, a diarylketone, and a tertiary amine were investigated for their initiation efficiency of acrylate polymerization. The use of an electron‐deficient N‐arylphthalimide resulted in a greater acrylate polymerization rate than an electron‐rich N‐arylphthalimide. Triplet energies of each N‐arylphthalimide, determined from their phosphorescence spectra, and the respective rate constants for triplet quenching by the N‐arylphthalimide derivatives (acquired via laser flash photolysis) indicated that an electron–proton transfer from an intermediate radical species to the N‐arylphthalimide (not energy transfer from triplet sensitization) is responsible for generating the initiating radicals under the conditions and species concentrations used for polymerization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4009–4015, 2004  相似文献   
53.
Well‐defined diblock and triblock copolymers composed of poly(N‐isopropylacrylamide) (PNIPAM) and poly(ethylene oxide) (PEO) were successfully synthesized through the reversible addition–fragmentation chain transfer polymerization of N‐isopropylacrylamide (NIPAM) with PEO capped with one or two dithiobenzoyl groups as a macrotransfer agent. 1H NMR, Fourier transform infrared, and gel permeation chromatography instruments were used to characterize the block copolymers obtained. The results showed that the diblock and triblock copolymers had well‐defined structures and narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight < 1.2), and the molecular weight of the PNIPAM block in the diblock and triblock copolymers could be controlled by the initial molar ratio of NIPAM to dithiobenzoate‐terminated PEO and the NIPAM conversion. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4873–4881, 2004  相似文献   
54.
For properly chosen elastomer compounds, thermorheological characterization is combined with an examination of the variation of the wet sliding friction with temperature. A conceptual argument leads to the assumption that the wet sliding friction should maximize at the energy dissipation peak associated with the dynamic softening transition at a characteristic frequency determined by the sliding speed and the effective smallest surface asperity scale. The dynamic softening transition is characterized with the peak in tan δ/Gn, where tan δ is the loss tangent, G′ is the elastic modulus, and n is a constant between 0 and 1. The William–Landel–Ferry transform is uncritically applied for extrapolating the position of the peak in tan δ/Gn at high frequencies. Even based on the criterion of tan δ, the results obtained on a concrete surface indicate that the effective smallest asperity scale is of order of 100 μm. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2467–2478, 2004  相似文献   
55.
介绍了一种基于Apollo信号控制台的核四极矩共振(NQR)炸药探测方法,描述了系统的结构组成、工作原理和实现方法,并给出了对RDX的测试试验结果. 试验表明该方法可实现对RDX信号的探测.  相似文献   
56.
A New Triterpene from the Orchid Pholidota yunnanensis   总被引:2,自引:0,他引:2  
A new triterpene, 25-methylenecyclopholidonyl p-hydroxy-trans-cinnamate, was isolated from a orchid Pholidota yunnanensis. The structure elucidation and ^1H, ^13C-NMR assignments were achieved by spectral and chemical method.  相似文献   
57.
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae.  相似文献   
58.
一类二阶椭圆型微分方程振动性的判定   总被引:1,自引:0,他引:1  
利用积分平均和完全平方技巧,给出了一类二阶椭圆型微分方程所有解在R^n的一个外区域Ω上均振动的新的充分条件。  相似文献   
59.
蒸汽活化对钙基脱硫剂孔结构及固硫能力影响的实验研究   总被引:11,自引:1,他引:10  
本文用实验方法研究了在电站锅炉排烟温度条件下,水蒸汽对钙基脱硫剂的活化作用.实验结果表明,蒸汽活化使得脱硫剂孔结构发生了显著变化并明显改善了脱硫剂的固硫能力.这为进一步了解活化机理及开发省水,经济的排烟脱硫技术提供了依据.  相似文献   
60.
Based on the measured transverse mass spectra ofπr-, K-, and p at the RHIC energy s()NN = 130 GeV,di-omega productions from baryon-baryon reactions in hadronic matter are studied. Results about the (ΩΩ)0+ numbershow that the deeply bound state (ΩΩ)o+ can be observed at RHIC energies.  相似文献   
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