~(14)N ENDOR Study on Bis(2-Hydroxylphenyl Ketoxime)-~(63)Cu(Ⅱ) Complex

The ENDOR spectrum of ~(14)N-~(63)Cu-HAP complex in DMSO/EtOH (5:1) freezing solution at 20 K has been studied using orientational selective method in this paper. The anisotropic superhyperfine coupling tensor and qusdrupole coupling tensor of ligand ~(14)N nucleus, and the superhyperfine coupling tensor of various ~1H nuclei have been measured precisely. Comparing the superhyperfine coupling tensor of ~(14)N-nucleus with previous work shows that the analytical method of spectrum is reasonable and the data are reliable in our previous work.     

Synthetic enantiopure aziridinomitosenes: preparation, reactivity, and DNA alkylation studies

An enantiocontrolled route to aziridinomitosenes had been developed from l-serine methyl ester hydrochloride. The tetracyclic target ring system was assembled by an internal azomethine ylide cycloaddition reaction based on silver ion-assisted intramolecular oxazole alkylation and cyanide-induced ylide generation via a labile oxazoline intermediate (62 to 66). Other key steps include reductive detritylation of 26, methylation of the N-H aziridine 56, oxidation of the sensitive cyclohexenedione 68 to quinone 70, and carbamoylation using Fmoc-NCO. Although the aziridinomitosene tetracycle is sensitive, a range of protecting group manipulations and redox chemistry can be performed if suitable precautions are taken. A study of DNA alkylation by the first C-6,C-7-unsubstituted aziridinomitosene 11a has been carried out, and evidence for DNA cross-link formation involving nucleophilic addition to the quinone subunit is described.     

Uniform Rice-like CdS Particles Prepared from Water-in-oil Microemulsions

IntroductionNano-sized semiconductors are of great interestdue to their special optical and electronic proper-ties[1,2].As one of the mostimportantⅡ—Ⅵsemicon-ductors,CdS has importantapplications in many fields,such as the solar cell field,non linear o…     

Advanced Current Collectors for Alkali Metal Anodes

High-energy-density batteries are in urgent need to solve the ever-increasing energy storage demand for portable electronic devices, electric vehicles, and renewable solar and wind energy systems. Alkali metals, typically lithium(Li), sodium(Na) and potassium(K), are considered as the promising anode materials owing to their low electrochemical potential, low density, and high theoretical gravimetric capacities. However, the problem of dendrite growth of alkali metals during their plating/stripping process will lead to low Coulombic efficiencies, a short lifespan and huge volume expansion, eventually hindering their practical commercialization. To resolve this issue, a very effective approach is engineering the anodes on structured current collectors. This review summarizes the development of the alkali metal batteries and discusses the recent advances in rational design of anode current collectors. First, the challenges and strategies of suppressing alkali-metal dendrite growth are presented. Then the special attention is paid to the novel current collector design for dendrite-free alkali metal anodes. Finally, we give conclusions and perspective on the current challenges and future research directions toward advanced anode current collectors for alkali metal batteries.     

Ni的掺入对复合氧化物LaFeO3的结构及性质的影响

合成子Ｎｉ替代铁酸稀土复合氧化物ＬａＦ３１－ｘＮｉｘＯ３（ｘ＝０．１－０．６），对样品进行了ＸＲＤ、ＩＲ及Ｍｏｓｓｂａｕｅｒ谱测试，结果表明：ｘ＝０＼１，０＼２，０＼３的样品为正交相，ｘ＝０．５，０．６的样品为菱方相；伴随相结构从正交向菱方结构的转变，ＩＲ谱上Ｆｅ（Ｎｉ）－Ｏ键伸振动谱带向高频移动近２０ｃｍ＾－１，Ｍｏｓｓｂａｕｅｒ谱测试表明Ｆｅ均处于＋３自旋态，Ｎｉ离子以＋３价进入晶格。     

菏泽以"曹"名地考

周建曹国之先，今菏泽域内便有一个曹邑。曹姓子民在此经营开拓，繁衍生息。五六百年后，武王灭纣，始封曹国，因之，菏泽以“曹”名地当始于商初。     

Cook-Seiford函数的若干推广

用例子指出Cook-seiford函数所得的群排序的不唯一性，并利用计算机模拟实验说明这种情况出现的几率较大，提出Cook-Seiford函数的两种推广：加权的Cook-Seiford函数和基于Minkowski距离的Cook-Seiford函数；解决了Cook-Seiford函数结果不唯一的问题．推广的Cook-Seiford函数还可以用来进行多属性决策．     

万州区城镇弱势群体现状调查与分析

本文在深入调查研究的基础上，分析了在三峡工程建设和三峡移民搬迁的背景下，万州区弱势群体结构、形成原因、心态等方面所具有的特殊性，并针对其特殊性提出了建立移民社会保障体系等措施。     

谈谈多媒体课件教学的三大误区

在肯定多媒体课件教学在当今现代教育技术中的作用和优势的同时，剖析了现阶段多媒体课件在教学中的应用现状及存在的问题，探讨了如何正确应用多媒体课件教学这一先进教学手段以获得良好的教学效果。     

混合层高度变化趋势及其代表值的探讨

利用长江下游某地的气象资料探讨了混合层高度的时刻、月份和季节变化规律，并得出结论：用2：00、8：00、14：00、20：00时刻的气象资料对年日平均有很好的代表性，用4、7、10、12月份对春、夏、秋、冬也有较好的代表性。