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NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
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The adsorption of asymmetrical triblock copolymers from a non-selective solvent on solid surface has been studied by using Scheutjens-Fleer mean-field theory and Monte Carlo simulation method on lattice model. The main aim of this paper is to provide detailed computer simulation data, taking A8-kB20Ak as a key example, to study the influence of the structure of copolymer on adsorption behavior and make a comparison between MC and SF results. The simulated results show that the size distribution of various configurations and density-profile are dependent on molecular structure and adsorption energy. The molecular structure will lead to diversity of adsorption behavior. This discrepancy between different structures would be enlarged for the surface coverage and adsorption amount with increasing of the adsorption energy. The surface coverage and the adsorption amount as well as the bound fraction will become larger as symmetry of the molecular structure becomes gradually worse. The adsorption layer becomes thicker with increasing of symmetry of the molecule when adsorption energy is smaller but it becomes thinner when adsorption energy is higher. It is shown that SF theory can reproduce the adsorption behavior of asymmetrical triblock copolymers. However, systematic discrepancy between the theory and simulation still exists.The approximations inherited in the mean-filed theory such as random mixing and the allowance of direct back folding may be responsible for those deviations. 相似文献
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南京地区第四系主要地层类型及分层探讨 总被引:4,自引:0,他引:4
南京地区地形地貌复杂,第四系分布变化大,在归纳南京地区第四纪沉积环境的基础上,总结了不同地貌和地质单元的地层层序特征。根据地层的成因和工程性质,结合国家规范中的地层分类原则,提出了统一分层的方法和统一的地层代号,将该地区第四系划分为填土、新近沉积土、一般沉积土和老沉积土等4个大层和若干亚层,同时提供了各层土的基本物理力学性质、典型剖面。对今后的勘察研究提出了建议。 相似文献
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The equivalent geometrical configurations of linear ordered orthogonal arrays are determined when their strengths are 3 and 4. Existence of such geometrical configurations is investigated. They are also useful in the study of (T, M, S)-nets. 相似文献
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Since its discovery in 1946, NMR has become a valuable tool in physics, chemistry, biology, and medicine. With the invention of NMR logging tools that take the medical MRI or laboratory NMR equipment and turn it inside-out, the application of sophisticated laboratory techniques to determine formation properties in situ is now available. The capability has opened a new era in formation evaluation just as the introduction of NMR has revolutionized the other scientific areas. 相似文献
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本文对梯形水平折梁(0≤α<∏2)和矩形水平折架(α=∏2)用最小余能原理进行了内力分析,并导出了相应的计算公式,可在工程结构设计中采用 相似文献
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