首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   180498篇
  免费   13226篇
  国内免费   8163篇
化学   81815篇
晶体学   1397篇
力学   7929篇
综合类   578篇
数学   24979篇
物理学   51585篇
综合类   33604篇
  2023年   2043篇
  2022年   3110篇
  2021年   3389篇
  2020年   3421篇
  2019年   3033篇
  2018年   4227篇
  2017年   4241篇
  2016年   5235篇
  2015年   5103篇
  2014年   6194篇
  2013年   8785篇
  2012年   12133篇
  2011年   11931篇
  2010年   8615篇
  2009年   8110篇
  2008年   8387篇
  2007年   7946篇
  2006年   7507篇
  2005年   10572篇
  2004年   9336篇
  2003年   6834篇
  2002年   4637篇
  2001年   4587篇
  2000年   3879篇
  1999年   4370篇
  1998年   3507篇
  1997年   3382篇
  1996年   3459篇
  1995年   2916篇
  1994年   2821篇
  1993年   2486篇
  1992年   2503篇
  1991年   2121篇
  1990年   1970篇
  1989年   1740篇
  1988年   1424篇
  1987年   1205篇
  1986年   953篇
  1985年   1021篇
  1984年   794篇
  1983年   657篇
  1982年   629篇
  1981年   583篇
  1980年   543篇
  1979年   527篇
  1978年   503篇
  1977年   490篇
  1976年   525篇
  1975年   491篇
  1974年   476篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
ON INTERACTION OF SHOCK AND SOUND WAVE (I)   总被引:1,自引:1,他引:0  
This paper studies the interaction of shock and gradient wave (sound wave) of solutions to the system of inviscid isentropic gas dynamics as a model for the corresponding problems for nonlinear hyperbolic systems. The problem can be reduced to a boundary value problem in a wedged dormain, By using the method of constructing asymptotic solutions and Newton‘siteration process it is proved that if a weak shock hits a gradient wave, then the grandient wave will split into two gradient waves, while the shock continuses propagating. In this paper the author reduces the problem to a standard form and constructs asymptotic solution of the problem. The existence of the genuine solution will he given in the following paper.  相似文献   
982.
Two homologous series of mesogenic materials which incorporate a 1,4-tetrafluorophenylene moiety and a terminal cyano- or nitro-substituent have been synthesized by using palladiumcatalysed coupling procedures. The compounds exhibit nematic and/or smectic A phases.  相似文献   
983.
We calculate the spin fluctuation spectra of VN and NbN in the relevant frequency- and wave vector regime. Significant quantitative differences between the dynamical spin susceptibilities of both substances are found. While in the case of VN their amplitudes are large, especially towards the Brillouin zone boundary and for frequencies below 1 eV, enhancement effects in NbN are of minor importance.  相似文献   
984.
High spin states of the odd-odd162Lu nucleus have been studied via147Sm(19F,4nγ)162Lu reaction at 95 MeV beam energy. Level scheme for yrast band based onπ[h11/2 v[i13/2] quasiparticle configuration was established up to I π = (23?) for the first time. This band shows the signature inversion in energy before backbending generally appeared in this mass region. It is stressed that the signature splitting in162Lu is larger than that in the160Tm nucleus.  相似文献   
985.
Precipitate-forming chemical reactions have been studied in chemically cross-linked poly(vinyl alcohol) gel medium. One of the reactive components was incorporated into the gel, the other was allowed to diffuse into it. Depending on the experimental conditions the reaction-diffusion process often results in patterns of different type. Experiments performed in tubes and in thin layers were carried out in order to investigate the effects of various factors (cross-linking density, swelling degree as well as the concentrations of the outer and inner electrolytes) on the morphologies of the precipitate patterns. It was found that precipitation occurs not only in the Liesegang bands, but also between bands. Beside Liesegang-type structures, tree-like patterns have been observed, showing a characteristic periodicity in the density profile obtained by digitalized image analyses.  相似文献   
986.
 采用同步辐射X光源和能散法,对CsBr粉末样品进行高压原位X光衍射实验。由金刚石对顶压砧高压装置(DAC)产生高压,用已知状态方程的Pt粉末作内标,由Pt的衍射数据确定样品压力,最高压力达64.4 GPa。实验结果表明:室温常压下原始CsBr样品是具有简单立方结构的晶体,其晶格常数α=0.428 5 nm。高压下CsBr的结构有所变化,在51.3~58.4 GPa的压力范围内,(110)线和(211)线发生劈裂,从而形成了四方相。  相似文献   
987.
本定义了次preortho-紧性,证明了一个空间X是次亚紧的当且仅当乘积X×βX是次preorgho-紧 的,这改进了Y.Yajima近来的一个定理。  相似文献   
988.
双(十二烷基亚磺酰)乙烷溶剂萃取钯及其机理的研究   总被引:2,自引:0,他引:2  
李焕然  许洪民 《分析化学》1994,22(7):702-705
本文研究用双(十二烷基亚磺酰)乙烷萃取钯的性能,在KI存在下从7mol/L盐酸介质中用含有BDSE的氯仿能定量萃取钯,有机的钯可被硫脲或氨溶液反萃继之用TMK-TritonX-100光度法测定,研究了萃取的最佳条件及干扰情况,斜率法测得萃合物组成为Pd:I:BDSE=1:2:1,红外光谱证实萃合物中BDSE的二个亚砜以硫原子与钯配位,萃合物为异位体络合物,提出了选择性萃取分离钯的新方法。  相似文献   
989.
本文阐述了用H3PO4、HF、HNO3及HClO4消化土壤及水系沉积物样品。其中磷酸的作用是避免在样品消化过程中硼的挥发损失。应用电感耦合等离子体发射光谱(简称ICP-AES)同时测定样品中全硼及其它微量、常量元素的含量。该法具有高的准确度及精密度。方法快速、简便、适合土壤和沉积物的多元素测定。  相似文献   
990.
This study was performed under the joint TRMC/INER program for the determination of low level85Kr and133Xe concentrations in the environmental air samples. Based on cryogenic adsorption of krypton and xenon on charcoal followed by chromatographic separation from other gases, the85Kr and133Xe recovered from 200 liters of atmospheric air can be determined by either on-line gas flow proportional counter or liquid scintillation counting. The recovery yields of krypton and xenon examined by using85Kr and133Xe tracers were nearly 100%. The minimum detectable activity of85Kr and133Xe by gas flow proportional counting is about 7.40 Bq. The method is satisfactory for environmental monitoring applications under abnormal conditions of nuclear facilities. However, for lower level environmental85Kr and133Xe measurements, the liquid scintillation counting method can be applied due to their extremely low detection limits (i.e. 0.107 Bq and 0.093 Bq for85Kr and133Xe, respectively). Using this method, the measurable limits of concentrations are 0.535 Bq/m3 and 0.466 Bq/m3 for85Kr and133Xe, respectively.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号