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131.
聚醚型脂肪族聚氨酯预聚体的制备 总被引:3,自引:0,他引:3
以HDI为异氰酸酯组分,制备聚醚型脂肪族聚氨酯预聚体。对聚醚脱水条件,反应温度和时间,以及预聚体的一些性能进行了探索。 相似文献
132.
研究了环氧乙烷与四氢呋喃的共聚.使用BF_3络合物为催化剂,1,4-丁二醇为共催化剂.找到了溶液聚合和本体聚合适宜的工艺条件.在此条件下,环齐聚物的生成量为8%左右.找到了方便易行的纯化方法,通过纯化可把聚醚的环齐聚物含量降到1%以下,有效地提高了产品的质量。 相似文献
133.
本文把Weiss等发展的计算平均第一通过时间(简称MFPT)的新方法推广到由非马尔科夫多值噪声驱动的过程.为了简化,本文只限于研究矩形分布这一情形.通过一个重要实例,对MFPT进行了具体计算,并得到了显式解析表示. 相似文献
134.
提出一种进行光学相减和学学微分的新方法,对离焦象与准确象的差即为物体图象的二阶微分做了证明.实验结果与理论分析吻合 相似文献
135.
Observation of spontaneous pattern with six-fold symmetry in disk-shaped ZnO complex microstructures
L.W. Yang Y.J. Gao X.L. Wu Y.M. Yang G.S. Huang Z.Y. Zhang P.K. Chu 《Applied Physics A: Materials Science & Processing》2007,89(1):173-176
Using a simple vapor phase transport technique, we have fabricated unique complex disk-shaped ZnO microstructures comprising
a small disk coaxially grown on a large one and observed spatially perfect six-fold symmetric patterns. The observed results
can be explained based on the spontaneous nanoindentation (NI) effect under the geometric constraints and the explanation
can be extended to fathom the growth mechanism of other highly symmetrical ZnO nanostructures. Our results indicate that NI
not only can elucidate the mechanical properties of surfaces and thin films but also is an effective approach to fabricate
ordered nanostructures with high precision on the location of the building blocks.
PACS 81.16.Rf; 81.07.-b; 81.05.Dz 相似文献
136.
A fluoroionophore sensor, N-[4-(1-pyrene)butyroyl]-L-tryptophan (PLT), has been reported. It can distinguish lead ion from other 12 metal ions via forming a pyrene dimer and it exhibits a very high sensitivity (0.15 microM) in aqueous solution (Chem. Commun., 2006, 2702). When the indole moiety in PLT was changed to benzene, in forming a new fluoroionophore of N-[4-(1-pyrene)butyroyl]-L-phenylalanine (PLP), it could not form a pyrene dimer in response to Pb(2+) in water. The present study describes the spectroscopic clarification of the intrinsic differences of the binding model between PLP and PLT in binding with Pb(2+). The model shows identical chelating bidentate coordination between COO(-) and Pb(2+) both in PLP-Pb and PLT-Pb; however, there is no indication of the interaction between the phenyl ring and the metal ion or the hydrogen bonding between amide groups in PLP-Pb. These differences in the binding model between PLP-Pb and PLT-Pb illustrate that the indole ring in PLT appears to play a crucial role in the high selectivity and sensitivity of PLT to lead(II) ion. 相似文献
137.
138.
Q.-Y. Shao A.-D. Li J.-B. Cheng H.-Q. Ling D. Wu Z.-G. Liu N.-B. Ming C. Wang H.-W. Zhou B.-Y. Nguyen 《Applied Physics A: Materials Science & Processing》2005,81(6):1181-1185
LaAlO3 (LAO) gate dielectric films were deposited on Si substrates by low-pressure metalorganic chemical vapor deposition. The interfacial structure and composition distribution were investigated by high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), secondary-ion mass spectroscopy (SIMS), and Auger-electron spectroscopy (AES). HRTEM confirms that there exists an interfacial layer between LAO and Si in most samples. AES, SIMS, and XPS analyses indicate that the interfacial layer is compositionally graded La–Al silicate and the Al element is severely deficient close to the Si surface. Electrical properties of LAO films were evaluated. No evident difference in electrical properties between samples with and without native SiO2 layers was observed. The electrical properties are discussed in terms of LAO growth mechanisms, in relation to the interfacial structure. PACS 73.40.Qv; 81.15.Gh; 77.55.+f; 68.35.-p 相似文献
139.
关于多线性振荡奇异积分在加权Hardy-型空间上的一致估计 总被引:1,自引:0,他引:1
本文对一类具有光滑位相函数的多线性振荡奇异积分算子建立了一致的加权(H^1(R^n),L^1(R^n))估计及一致的加权(HKp(R^n),Kp(R^n)估计。 相似文献
140.
Tao Jin Feng-Xian Jiang Xiao-Li Li Fang Wang Xiao-Hua Shen Rui-Qiang Zhang Hai-Shun Wu 《Applied Surface Science》2006,253(5):2708-2712
CoPt/Ag and [C/CoPt]n/Ag thin films have been prepared onto the glass substrates by magnetron sputtering. We investigated the evolution of texture and magnetic properties of CoPt/Ag and [C/CoPt]n/Ag films. The results show that C-doping plays an important role in improving (0 0 1) texture, improving the order parameter S, reducing the intergrain interactions, and making the magnetization reversal mechanism more close to Stoner-Wolfarth rotational mechanism. The growth mechanism of (0 0 1) texture also seems to be related strongly to the films thickness. Our results show that the highly (0 0 1)-oriented films with ordered fct phase have a significant potential for the perpendicular media of extremely high-density recording. 相似文献