分光技术在自由电子激光结合里德堡态氢原子飞行时间谱装置中的应用

本文描述了一种应用于自由电子激光结合高里德堡态氢原子飞行时间谱装置中的分光方法,以及该方法应用于小分子(如₂S)光解动力学研究中的必要性. 拉曼-α辐射(121.6 nm),用作H原子产物探测的激光,是在Kr/Ar气介质中利用四波混频产生的. 利用透镜对不同波长的光有不同的折射率,四波混频后的混合光在经过一片离轴的氟化锂透镜后,121.6 nm的激光将会与212.6和845 nm在空间上分开. 在激光到达反应中心前利用挡板挡住212.6和845 nm的激光,只让121.6 nm的光经过反应中心,从而消除212.6 nm激光产生的背景信号对实验的干扰. 结合自由电子激光,成功地研究了H₂S在122.95 nm波长下的光解动力学,采集到了产物时间飞行谱. 本文展示了转换得到的产物总平动能谱,解离机理与121.6 nm波长下的结果相似. 实验结果显示,该方法成功地解决了分子在VUV波段进行光解动力学研究的难题,消除了这些分子在紫外光波段因为强烈吸收而产生的背景信号.     

氮杂冠醚的研究Ⅱ.N-取代苯并氮杂冠醚的1H和13CNMR谱

本文研究了15种新合成的单、双N取代二苯并18冠6的¹H及¹³C NMR谱。结果表明,¹³C NMR谱的化学位移能显示分子的电荷分布,而¹H NMR谱的偶合常数则部份地反映了大环的构象。氮原子的杂入大环结构和取代基的改变对聚醚环上的电荷分布影响的结果说明,这些改变可能会对冠醚的络合作用发生影响。     

逆向环形分布射流迴流特性的数值计算

数值计算表明,逆向多环形分布射流可造成颗粒能直接进入,并能进行强烈的动量、能量交換的理想的迴流区结构。多环形结构可在大范围內造成所需尺寸的迴流区。逆向射流和主流速度比、环直径、射流直径和孔数、环的结构形式及离燃烧室进口的距离是影响迴流特性的主要参数。     

拱形试件动态断裂的动光弹分析

本文采用动光弹方法,分析了对带边裂纹的拱形三点弯曲试件在抢击加载条件下的瞬态反应。从多火花动光弹仪记录下来的16幅断裂过程的照片和微机输出的电火花光信号图上,得到了各时刻的等差线图形和裂纹长度。使用运动裂纹尖端附近的应力场解,去计算动应力强度因子。对环氧树脂材料,测定了动态应力强度因子与裂纹扩展速度之间的关系,并给出了当裂纹扩展速度达到410m/s时,为裂纹产生分叉的条件。     

On the stability of elastic curved bars

A general discussion about the stability of arbitrary elastic curved bars in space under combined actions of bending and twisting is given in this paper. A system of Eqs. (28)–(36) for perturbation functions near some equilibrium state is presented. With appropriate boundary conditions, the nontrivial solution corresponds to the critical state. Five examples are analysed in this paper. Some of them are new results and others are old problems treated using the new method.     

Leibniz Conformal Algebras of Rank Two

We classify all Leibniz conformal algebras of rank two.     

掺钼ZnO透明导电薄膜的太赫兹电磁波传输性质

采用直流磁控反应溅射方法,通过调节氧分压在玻璃基底上制备了不同载流子浓度的掺Mo的ZnO（ZMO）透明导电薄膜.应用太赫兹电磁波时域光谱技术研究了ZMO导电膜的太赫兹电磁波透射性质及介电响应,得到了与频率相关的电导率、能量吸收和薄膜折射率,实验结果与经典Drude模型相符很好.ZMO导电膜的太赫兹电磁波脉冲透射性质表明,通过调节ZMO薄膜的载流子浓度,该导电膜可作为应用于衬底和光学器件等太赫兹电磁波频率范围的宽带抗反射涂层. 关键词： 太赫兹电磁波光谱 薄膜电导率 宽带抗反射 透明导电薄膜     

The inlet effect on the drag factor of a sphere in a tube

The creeping motion Ground a sphere situated axisymmetrically near the entrance of asemi-infinite circular cylindrical tube is analyzed using infinite series solutions for thevelocity components. pressure and the stream function. Truncating the infinite series. thecorresponding coefficients in the series are determined by a collocation technique. The dragfactor and the stress distribution on the surface of the sphere are calculated for the sphere inmotion in quiescent fluid and for the flow with uniform velocity at the entrance past a rigidlyheld sphere. The results indicate that a sphere near the entrance which has a uniformentrance velocity profile will suffer larger drag than that in infinite tube.Theconvergence of the collocation technique is tested by numerical calculation. It is shown thatthe technique has good convergence properties.     

Effects of pressure on optical F-bands in rubidium halides

High pressure optical absorption measurements have been made on additively colored RbCl and RbBr at pressures up to 10 kbar and on electrolytically colored Rbl up to 4 kbar. The pressure dependence of the F-band produced in RbCl by x-irradiation in the s.c. phase is also reported. Effects of the pressure induced structure transformation in these salts are described. F-band pressure shifts are related to a semi-empirical treatment which takes account of relative ion sizes. A new Ivey law for F-centers in host crystals having the s.c. structure is presented. This relation is established using all available F-band data including those for salts transformed to the s.c. structure by the application of high pressure.     

钼铁硫原子簇化合物的合成与结构化学Ⅲ*以Fe(SR)6为桥的双立方烷化合物的磁学研究

以Fe(SR)₆为桥的系列钼铁硫双立方烷化合物(Et₄N)₄[(MoFe₃S₄(SR)₃)₂Fe(SR)₆],R=ph,o-tol,m-tol和p-tol的磁极矩和¹H-NMR数据作了报导和分析,并与类似的化合物作比较,讨论了它们的电子结构和磁结构。在类立方烷单元[MoFe₃S₄]中未配对电子有明显的离域性,过渡金属原子之间有很强的反铁磁偶合作用。整个分子形成三个基本上相互独立的磁性中心。