子空间格代数的模

本文讨论了子空间格代数模中的有限秩算子,得到了一些结果,这些结果包含了格代数中已有的结论.     

冰-水-气生成天然气水合物的实验研究

设计了冰 水 气生成天然气水合物的实验装置 ,并对冰 水 气在冰点以下生成的天然气水合物进行了初步实验 ,得出了在冰点以下关于天然气水合物的生成条件、生成速率等方面的结论 .研究结果对实现天然气水合物的开发利用 ,深入研究青藏高原多年冻土区天然气水合物的形成规律 ,及未来开发冻土区天然气水合物的资源等 ,均有参考价值     

Ag-NORs多态性及其在动物遗传育种研究中的应用

对动物的Ag-NORs多态性作了系统的论述了,同时阐述了Ag-NORs多态性作为遗传标记在动物遗传育种研究中的应用情况。     

结合专业特色的大学物理课程教学改革探索

制定大学物理课程的授课计划不仅仅要关注物理学知识体系的系统性,同时要注重与后续专业课程的结合,因材施教;根据学生的专业课程内容和特点,结合学生需求精选教学内容,让学生感受到学以致用．教师要精心进行教学设计,将物理学理论和专业课程知识巧妙衔接,同时还要引导学生重视大学物理学提供的科学研究的基本训练．结合专业特色的大学物理教学改革实践,不仅突出了大学物理课程基础理论的重要性,而且还激发了学生对大学物理学习的兴趣和对专业研究的动力．     

和平解放西藏60年成就与变迁的启迪

和平解放60年来,西藏各行业的建设与发展取得辉煌成就。广大人民的生产、生活得到了极大的改善。文章结合西藏发展的历史轨迹与成就,概述西藏和平解放60年变迁的恢弘历程和中共中央治理西藏、发展西藏的历史,论述60年变迁的启迪,以增强西藏各族人民群众坚持走有中国特色、西藏特点发展路子的信心与决心。     

Dual-Site Activation Coupling with a Schottky Junction Boosts the Electrochemiluminescence of Carbon Nitride

Robust electrochemiluminescence (ECL) of carbon nitride (CN) requires efficient electron-hole recombination and the suppression of electrode passivation. In this work, Au nanoparticles and single atoms (Au_SA+NP) loaded on CN serve as dual active sites that significantly accelerate charge transfer and activate peroxydisulfate. Meanwhile, the well-established Schottky junctions between Au NPs and CN act as electron sinks, effectively trapping over-injected electrons to prevent electrode passivation. As a result, the porous CN modified with Au_SA+NP exhibits an enhanced and stable ECL emission, with a minimal relative standard deviation of 0.24 %. Furthermore, the designed ECL biosensor based on Au_SA+NP-CN shows a remarkable performance in detecting organophosphorus pesticides. This innovative strategy has the potential to offer new insights into strong and stable ECL emission for practical applications.     

Synthesis and Characterization of β‐Diketiminate Aluminum Compounds and Their Use in the Ring‐Opening Polymerization of ε‐Caprolactone

Four aluminum alkyl compounds, [CH{(CH₃)CN‐2,4,6‐MeC₆H₂}₂AlMe₂] ( 1 ), [CH{(CH₃)CN‐2,4,6‐MeC₆H₂}₂AlEt₂] ( 2 ), [CH{(CH₃)CN‐2‐iPrC₆H₄}₂AlMe₂] ( 3 ), and [CH{(CH₃)CN‐2‐iPrC₆H₄}₂AlEt₂] ( 4 ), bearing β‐diketiminate ligands [CH{(Me)CN‐2,4,6‐MeC₆H₂}]₂ (L¹H) and [CH{(Me)CN‐2‐ⁱPrC₆H₄}]₂ (L²H) were obtained from the reactions of trimethylaluminum, triethylaluminum with the corresponding β‐diketiminate, respectively. All compounds were characterized by ¹H NMR and ¹³C NMR spectroscopy, single‐crystal X‐ray structural analysis, and elemental analysis. Compounds 1 – 4 were found to catalyze the ring‐opening polymerization (ROP) of ε‐caprolactone (ε‐CL) with good activity.     

Single-Atom Iron Boosts Electrochemiluminescence

The traditional luminol–H₂O₂ electrochemiluminescence (ECL) sensing platform suffers from self-decomposition of H₂O₂ at room temperature, hampering its application for quantitative analysis. In this work, for the first time we employ iron single-atom catalysts (Fe-N-C SACs) as an advanced co-reactant accelerator to directly reduce the dissolved oxygen (O₂) to reactive oxygen species (ROS). Owing to the unique electronic structure and catalytic activity of Fe-N-C SACs, large amounts of ROS are efficiently produced, which then react with the luminol anion radical and significantly amplify the luminol ECL emission. Under the optimum conditions, a Fe-N-C SACs–luminol ECL sensor for antioxidant capacity measurement was developed with a good linear range from 0.8 μm to 1.0 mm of Trolox.     

Synthesis of a novel class of cyclodextrin-based nanotubes

The synthesis and characterization of a novel class of structurally well-defined nanotubes from β-cyclodextrin are described. These new hosts were formed using disulfide linkages that substitute all the primary hydroxyl groups of a β-cyclodextrin. A deep and rigid hydrophobic channel with a size of more than 1.5 nm is found in the molecules. Because of their unique geometry and the potential biodegradability of the disulfide bond, this class of molecules could find broad applications in biology and other areas of research.     

基于聚硫堇和层层组装碳纳米管/HRP的过氧化氢传感器研究

将电聚合和层层组装方法有效结合构筑了聚硫堇（PTH）电子介体修饰的碳纳米管（CNTs）/辣根过氧化物酶（HRP）多层膜无试剂H2O2传感器.利用电化学阻抗谱对CNTs/HRP多层膜的组装过程进行监测,用循环伏安法和计时电流法研究了该HRP电极的电化学行为.探讨了酶组装层数、工作电位、pH值和碳纳米管对电极响应的影响.该...