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61.
Recently molecular dynamics simulations were performed for polyethylene in the inclusion complex with perhydrotriphenylene. The system contained ninety molecules of perhydrotriphenylene, arranged in six stacks of fifteen molecules each, and one molecule of n-tetracontane, C40H82. The internal CH2-CH2 bonds in n-tetracontane have a very strong preference for the trans state. Nevertheless, the chain exhibits a high degree of internal flexibility. This motion produces a characteristic pattern in δ|ψ N + i ψi| vs. N, where ψi describes the instantaneous angle of a C-H bond vector at carbon atom i about the axis defined by the channel, and δ denotes the fluctuation. The pattern expected for δ|ψ N + i ψi| vs. N is derived for the case where the rapid internal motion is produced by a twiston. It is compared with the results from the simulation and from the expectation for the case where the rapid motion arises from uncorrelated internal fluctuations within the trans state at each CH2-CH2 bond. 相似文献
62.
Wayne E. Baker 《The Journal of mathematical sociology》2013,37(2):191-223
In the classic blockmodel formulation, a social network among members of a population with n actors and k relations (types of tie) is arrayed as k n X n matrices. Though this is a three‐dimensional data structure, it is typically reduced to a two‐way analysis. In this paper, a three‐way procedure for analyzing multigraph data is developed. Specifically, in addition to applying the rule of structural equivalence to collapse actors, it is also applied to the relations (the third dimension), and structurally equivalent sets of relations are collapsed. The result is a three‐dimensional blockmodel (image) of social structure that is a more parsimonious representation of social structure than the classic two‐dimensional blockmodel images. The three‐dimensional approach is illustrated by application to three case studies: Homan's Bank Wiring Room, Sampson's monastery, and a local economy of hospital services. The structural equivalence approach to relations is further explored by applying it to the individual‐level Liking and Antagonism relations and their compounds (of length four or less) in the Bank Wiring Room. This application demonstrates that the structural equivalence approach can be used to identify equality equations for primitive and compound relations. 相似文献
63.
Sook Voon Yap Robert M. Ranson Wayne M. Cranton Demosthenes C. Koutsogeorgis Gary B. Hix 《Journal of luminescence》2009,129(5):416-422
This research is aimed at developing an optical sensor for remotely measuring human skin temperature in electromagnetically hostile environments, such as within a magnetic resonance imaging (MRI) scanner. In this feasibility study, various concentrations of europium-doped lanthanum oxysulphide (La2O2S: Eu—0.1-15 mol% (m/o)) and terbium-doped lanthanum oxysulphide (La2O2S: Tb—0.005-50 m/o) have been investigated in terms of crystallinity, photoluminescent (PL) spectral and decay time characteristics. For both phosphors, X-ray diffraction (XRD) has shown that as dopancy increases, the (1 0 0) and (0 0 2) reflections merge and there is a reduction in the c-axis parameter as well as the crystallite size. Photoluminescent characterisation (337 nm excitation) has also shown a dependency to dopant concentration through variance of peak intensity. Temperature dependent decay time measurements were carried out over a low temperature range 5-60 °C. Optimum brightness of these temperature dependent lines is achieved at concentrations of 1 and 10 m/o for La2O2S: Eu and La2O2S: Tb respectively. However, optimum temperature dependency is achieved at lower concentration for La2O2S: Eu, specifically at 0.1 m/o. In comparison to conventional phosphor temperature dependent characteristic, La2O2S: Tb showed an increase in decay time with respect to temperature for concentrations above 2 m/o. 相似文献
64.
Francis E. Burstall Udo Hertrich-Jeromin Wayne Rossman 《Comptes Rendus Mathematique》2010,348(11-12):661-664
We propose a Lie geometric point of view on flat fronts in hyperbolic space as special Ω-surfaces and discuss the Lie geometric deformation of flat fronts. 相似文献
65.
A substantial concentration-dependent red shift of the absorption and emission spectra (77 K) of [Ru(bpy)(2)(POMe-P,O)](2+) (1) (POMe = (2-methoxyphenyl)diphenylphosphine) is reported. NMR experiments show this shift to be due to equilibration of 1 with an aquo complex (1b) (K(eff) = (6 +/- 3) x 10(-3)) that forms upon displacement of the coordinated ether in the hemilabile POMe ligand. The excited-state lifetimes of 1 and 1b at 77 K in solid 2:1 ethanol/acetone solution are tau = 2.13 +/- 0.02 and 1.95 +/- 0.02 mus, respectively. The preparation and X-ray crystal structure of a related complex, [Ru(bpy)(2)(PO(i)Pr-P)(OH(2))](PF(6))(2) (2b) (PO(i)Pr-P = (2-(2-propoxy)phenyl)diphenylphosphine), is also reported. In solution, this species exists as an equilibrium mixture of complexes that cannot be readily separated. This species also has concentration-dependent absorption spectra in 2:1 ethanol/acetone solution, with a significant red shift (20 nm) at lower concentrations. 相似文献
66.
Invariant Manifolds and the Long-Time Asymptotics of the Navier-Stokes and Vorticity Equations on R2
We construct finite-dimensional invariant manifolds in the phase space of the Navier-Stokes equation on R 2 and show that these manifolds control the long-time behavior of the solutions. This gives geometric insight into the existing results on the asymptotics of such solutions and also allows us to extend those results in a number of ways. 相似文献
67.
Noncovalent engineering of carbon nanotube surfaces by rigid,functional conjugated polymers 总被引:8,自引:0,他引:8
Chen J Liu H Weimer WA Halls MD Waldeck DH Walker GC 《Journal of the American Chemical Society》2002,124(31):9034-9035
We report a new nonwrapping approach to noncovalent engineering of carbon nanotube surfaces by short, rigid functional conjugated polymers, poly(aryleneethynylene)s. Our technique not only enables the dissolution of various types of carbon nanotubes in organic solvents, which represents the first example of solubilization of carbon nanotubes via pi-stacking without polymer wrapping, but could also introduce numerous neutral and ionic functional groups onto the carbon nanotube surfaces. 相似文献
68.
We demonstrate generalized ellipsometry for precise measurement of the principal indices of refraction, the extinction coefficients, and the orientations of the crystal a, b, and c axes of orthorhombic absorbing materials. Stibnite (Sb(2)S(3)) single crystals cut approximately parallel to (100), (010), (001), and (313) are studied at a representative wavelength of 589 nm. The (313) surface is sufficient for retrieval of all optical constants. The expected effects of surface over-layer formation are removed numerically. We propose generalized ellipsometry as a powerful tool for measurement of anisotropic optical function spectra of biaxial materials. 相似文献
69.
本书全面论述了传输、管理和控制位面的技术,介绍了一些有用的、现行的和下一代电讯网络技术的参考信息。四位作者均在电信学研究、产品开发等方面具有20年以上的经验。 相似文献
70.
Zohreh T. Farahbakhsh Christian Altenbach Wayne L. Hubbell 《Photochemistry and photobiology》1992,56(6):1019-1033
In stoichiometric amounts, the spin label N-tempoyl-(p-chloromercuribenzamide) reacts rapidly with one cysteine residue in membrane-bound bovine rhodopsin. This residue is distinct from the two reactive cysteines previously used as attachment sites for spectroscopic labels, and is on the external surface of the protein near the cytoplasmic membrane/aqueous interface. The spin-labeled side chain has revealed a light-induced conformational change in membrane-bound rhodopsin that is apparently not associated with protein aggregation. The changes are reversible upon the addition of 11-cis retinal, and the magnitude of the change is dependent on the identity of the phospholipid in the surrounding bilayer. Alteration of lipid composition has a much larger effect on bleached rhodopsin than rhodopsin itself, indicating that the former is more readily deformable in response to changes in bilayer properties. This is consistent with the loss of 11-cis retinal binding energy in opsin compared to rhodopsin. These results provide direct structural evidence that the conformation of a membrane protein can be modulated by the lipid properties. 相似文献