全文获取类型
收费全文 | 249224篇 |
免费 | 31787篇 |
国内免费 | 20097篇 |
专业分类
化学 | 115385篇 |
晶体学 | 1839篇 |
力学 | 11707篇 |
综合类 | 979篇 |
数学 | 21018篇 |
物理学 | 68918篇 |
综合类 | 81262篇 |
出版年
2024年 | 1027篇 |
2023年 | 4388篇 |
2022年 | 7044篇 |
2021年 | 7719篇 |
2020年 | 7701篇 |
2019年 | 6839篇 |
2018年 | 6424篇 |
2017年 | 6139篇 |
2016年 | 9135篇 |
2015年 | 9480篇 |
2014年 | 12268篇 |
2013年 | 14922篇 |
2012年 | 17635篇 |
2011年 | 18135篇 |
2010年 | 12886篇 |
2009年 | 12969篇 |
2008年 | 14062篇 |
2007年 | 12995篇 |
2006年 | 11648篇 |
2005年 | 10274篇 |
2004年 | 7832篇 |
2003年 | 6259篇 |
2002年 | 5883篇 |
2001年 | 5450篇 |
2000年 | 5353篇 |
1999年 | 7831篇 |
1998年 | 7233篇 |
1997年 | 7212篇 |
1996年 | 7057篇 |
1995年 | 6099篇 |
1994年 | 5562篇 |
1993年 | 4756篇 |
1992年 | 4184篇 |
1991年 | 3738篇 |
1990年 | 3154篇 |
1989年 | 2655篇 |
1988年 | 2156篇 |
1987年 | 1506篇 |
1986年 | 1107篇 |
1985年 | 713篇 |
1984年 | 407篇 |
1983年 | 269篇 |
1982年 | 235篇 |
1981年 | 162篇 |
1980年 | 111篇 |
1979年 | 61篇 |
1978年 | 34篇 |
1976年 | 39篇 |
1974年 | 50篇 |
1957年 | 50篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Nonlinear Dynamics - In order to solve the constrained-input problem and reduce the computing resources, a novel event-triggered optimal control method is proposed for a class of discrete-time... 相似文献
22.
Kobayashi M. Zhang Y. Ishikawa H. Sun J. Oddershede J. Juul Jensen D. Miura H. 《Experimental Mechanics》2021,61(5):817-828
Experimental Mechanics - The internal strain distribution developing during plastic deformation is important for understanding the mechanical properties of polycrystalline materials. Such... 相似文献
23.
Jiraya Kiriratnikom Xun Zhang Xiaohan Cao Bo Chu Chengjian Zhang Xinghong Zhang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2262-2268
Facile construction of sulfur-rich polymers using readily available raw chemicals is an area aggressively pursued but challenging. Herein we use common feedstocks of ethylene oxide (EO), propylene oxide (PO), and carbonyl sulfide (COS) to synthesize copoly(thioether)s which are traditionally produced from unpleasant and difficult to store episulfides. In this protocol, the EO/COS coupling selectively generates a pure poly(ethylene sulfide) (PES) with melting temperature (Tm) values up to 172°C and high yields up to 98%. The EO/PO/COS terpolymerization leads to the incorporation of soft poly(propylene sulfide) (PPS) and hard PES segments together, affording a random PES-co-PPS copoly(thioether) with the complete consumption of EO and PO. Additionally, by simply varying the EO/PO feeding ratio, the obtained copoly(thioether)s possess tunable thermal properties, Tm values in the range of 76–144°C, and excellent solubility. These copolymerizations are conducted in one-pot/one-step at industrially favored reaction temperatures of 100–120°C using catalysts of common organic bases, suggesting a facile and practical manner. Especially, the copoly(thioether) exhibits high refractive indices up to 1.68 owing to its high sulfur content, suggesting a broad application prospect in optical materials. 相似文献
24.
Nonlinear Dynamics - The classical Kuramoto model serves as a useful tool for studying synchronization transitions in coupled oscillators that is limited to the sinusoidal and pairwise... 相似文献
25.
近年来,我国金融行业数字化转型不断提速,金融机构数字化转型已迫在眉睫.金融机构面临的数字化转型环境包括3个方面:一是大数据走向跨界融合;二是人工智能加速发展;三是区块链等技术建立了新型连接关系.基于以上环境分析,文章认为金融机构数字化转型的核心在于业务与技术融合,需要在机制、组织、架构、人才和文化层面实行再造. 相似文献
26.
A numerical model was developed and validated to investigate the fluid–structure interactions between fully developed pipe flow and core–shell-structured microcapsule in a microchannel. Different flow rates and microcapsule shell thicknesses were considered. A sixth-order rotational symmetric distribution of von Mises stress over the microcapsule shell can be observed on the microcapsule with a thinner shell configuration, especially at higher flow rate conditions. It is also observed that when being carried along in a fully developed pipe flow, the microcapsule with a thinner shell tends to accumulate stress at a higher rate compared to that with a thicker shell. In general, for the same microcapsule configuration, higher flow velocity would induce a higher stress level over the microcapsule shell. The deformation gradient was used to capture the microcapsule's deformation in the present study. The effect of Young's modulus on the microcapsule shell on the microcapsule deformation was investigated as well. Our findings will shed light on the understanding of the stability of core–shell-structured microcapsule when subjected to flow-induced shear stress in a microfluidic system, enabling a more exquisite control over the breakup dynamics of drug-loaded microcapsule for biomedical applications. 相似文献
27.
湖北省多年来深入推行科技特派员制度,在全国科技特派员制度推行和科技服务的伟大实践中拼搏奋进,从启动科技特派员地市试点工作,到全面开展科技特派员基层创业行动,从出台深入推行科技特派员制度实施意见,到开展湖北省科技特派员"百县千镇万人"工程实施,围绕产业链布局人才链的科技生态日臻完善.科技特派员个人、团队和法人单位点面结合,工作室与工作站交相辉映,他们立足湖北服务华中片区和秦巴山区,辐射服务全国各地,湖北科技特派员的服务足迹遍布荆楚星辰大地,谱写着新时代湖北科技特派员服务体系的新篇章. 相似文献
28.
进入新发展阶段后,科技创新创业活动对孵化服务提出了更高的要求,科技创业载体需要加快提升专业化、精准化服务能力.文章基于2016-2019年全国科技创业孵化载体发展数据,全面分析专业化科技创业孵化载体建设发展现状,剖析了科技创业孵化载体在专业化建设方面存在的方向不清、动力不足、能力不够、模式不明、机制不畅等问题,从建立评价指标体系、明确建设主体、提升服务能力、加强资源开放和政策供给等方面提出对策建议. 相似文献
29.
Dr. Ruijuan Yao Prof. Di Liu Dr. Huihui Wan Dr. Yongqiang Mei Jiahui Wang Dr. Rui Cai Dr. Huimin Zhang Dr. Yuzhen Zhao Dr. Zemin He 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(71):e202202269
By linking the carbazole unit to the nitrogen atom of acridone through phenyl or pyridyl, two compounds, named 10-(4-(9H-carbazol-9-yl)phenyl)acridin-9(10H)-one (AC-Ph-Cz) and 10-(5-(9H-carbazol-9-yl)pyridin-2-yl)acridin-9(10H)-one (AC-Py-Cz) were designed and synthesized. These two materials, characterized with highly twisted and rigid structure, good thermal stability, and balanced carrier-transporting properties, were employed as host materials for green phosphorescent and thermally activated delayed fluorescent organic light-emitting diodes (OLEDs). The carbazole group, despite its small contribution to the highest occupied molecular orbitals (HOMOs) of these two materials, plays an essential role as an intramolecular host in energy delivering and improving the hole transporting ability of these two hosts. The incorporation of the electron-deficient pyridyl group as a linking group slightly improves the electron transporting capability of AC-Py-Cz. The green phosphorescent OLED (PhOLED) based on AC-Py-Cz exhibited excellent device performance with a turn-on voltage of 2.5 V, a maximum power efficiency and an external quantum efficiency (ηext) of 89.8 lm W−1 and 25.2 %, respectively, benefitting from the better charge-balancing ability of AC-Py-Cz host due to the presence of the pyridyl bridge. More importantly, all the devices based on these two hosts showed low efficiency roll-off at high brightness due to the suppressed non-radiative transition in the emitting layer. In particular, the AC-Py-Cz-hosted green PhOLED exhibited an efficiency roll-off of 1.6 % from the maximum next at a high brightness of 1000 cd m−2 and a roll-off of 15.9 % at an extremely high brightness of 10000 cd m−2. This study manifests that acridone-based host materials have great potential in fabricating OLEDs with low efficiency roll-off. 相似文献
30.
Liu Jingze Fei Qingguo Wu Shaoqing Tang Zhenhuan Zhang Dahai 《Nonlinear dynamics》2021,106(3):1869-1890
Nonlinear Dynamics - Rolling bearing and squeeze film damper will introduce structural nonlinearity into the dynamic model of aeroengine. Rubbing will occur due to the clearance reduction design of... 相似文献