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991.
避开了时间增量松弛法与波形松弛法的缺点,而将其优点综合起来并用于电力系统的潮流计算,得到了一种改进的新方法.该方法的速度比牛顿-拉夫逊法高一个数量级左右,所需存储量却降至1/5,并能确保计算精度. 相似文献
992.
Tribromomethylarenes were prepared efficiently, at room temperature, from trifluoromethylarenes with boron tribromide as the
brominating reagent. The present process is applicable to the preparation of various substituted benzotribromide derivatives
from substituted benzotrifluoride compounds. p-Substituted benzotrifluoride compounds were found to be more reactive than o-substituted isomers under the given reaction conditions. 相似文献
993.
Gang‐Yin Shi Cai‐Yuan Pan 《Journal of polymer science. Part A, Polymer chemistry》2009,47(10):2620-2630
A series of well‐defined θ‐shaped copolymers composed of polystyrene (PS) and poly(ε‐caprolactone) (PCL) with controlled molecular weight and narrow molecular weight distribution have been successfully synthesized without any purification procedure by the combination of atom transfer radical polymerization (ATRP), ring‐opening polymerization (ROP), and the “click” chemistry. The synthetic process involves two steps: (1) synthesis of AB2 miktoarm star copolymers, which contain one PCL chain terminated with two acetylene groups and two PS chains with two azido groups at their one end, (α,α′‐diacetylene‐PCL) (ω‐azido‐PS)2, by ROP, ATRP, and the terminal group transformation; (2) intramolecular cyclization of AB2 miktoarm star copolymers to produce well‐defined pure θ‐shaped copolymers using “click” chemistry under high dilution. The 1H NMR, FTIR, and gel permeation chromatography techniques were applied to characterize the chemical structures of the resultant intermediates and the target polymers. Their thermal behavior was investigated by DSC. The mobility decrease of PCL chain across PS ring in the theta‐shaped copolymers restricts the crystallization ability of PCL segment. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2620–2630, 2009 相似文献
994.
995.
996.
Ho Yin Lo Jörg Bentzien Chuk C. Man Steven S. Pullen Josephine King John P. Wolak Gregory P. Roth 《Tetrahedron letters》2008,49(51):7337-7340
Based on information from molecular modeling, a series of 2-aminobenzimidazoles with pyrrole moieties were designed and synthesized as ITK antagonists. Results showed that a significant improvement of intrinsic and cell-based potency was achieved. X-ray crystallographic analysis of an inhibitor complex with ITK confirmed the prediction from the de novo design that the pyrrole moiety of the inhibitor would form an additional hydrogen bonding interaction with Glu436 in the catalytic domain, and hence improve overall binding affinity of the inhibitor. 相似文献
997.
中性红(NR)可吸附在巯基丙酸自组装修饰金电极表面,并进而与DNA发生嵌插作用.以交流阻抗技术研究了DNA在巯基丙酸自组装/中性红修饰电极上的响应.结果表明,交流阻抗方法不仅可以反映DNA与小分子间发生的作用,还可以对DNA进行定量分析,响应在DNA浓度为0.4~8mg·L-1范围内呈线性关系,相关系数r=0.9973,检出下限为0.03 mg·L-1.该法是一种快速、简便、廉价的研究DNA及与小分子相互作用的方法. 相似文献
998.
通过对研究弹性梁受负载变化时机械波传播机理及实验分析 ,提出利用稳态正弦波和瞬态激振方法测取弹性梁的动态特性参数 ,依据振动频率变化情况来进行料位高度测量的方法 ,并设计了一种单片机智能料位测量系统。 相似文献
999.
In many classification applications and face recognition tasks, there exist unlabelled data available for training along with
labelled samples. The use of unlabelled data can improve the performance of a classifier. In this paper, a semi-supervised
growing neural gas is proposed for learning with such partly labelled datasets in face recognition applications. The classifier
is first trained on the labelled data and then gradually unlabelled data is classified and added to the training data. The
classifier is retrained; and so on. The proposed iterative algorithm conforms to the EM framework and is demonstrated, on
both artificial and real datasets, to significantly boost the classification rate with the use of unlabelled data. The improvement
is particularly great when the labelled dataset is small. Comparison with support vector machine classifiers is also given.
The algorithm is computationally efficient and easy to implement. 相似文献
1000.
Novel CdClOH sub‐nanocone crystals were successfully synthesized on a large scale by a facile solution‐based method using polymers as crystal growth modifiers. The crystals showed cone‐like morphology. Some factors affecting the morphology and size of the product, such as reaction temperature, concentrations of polyacrylamide (PAM), and pH value of the solution, were systematically studied. Experiments implied that polymer PAM played a key role in the formation of CdClOH sub‐nanocones. A possible formation mechanism of CdClOH sub‐nanocones was suggested based on nucleation‐etching process‐recrystallization in a mild aqueous solution. Furthermore, the as‐prepared CdClOH sub‐nanocones could be further transformed into CdS hollow sub‐nanocones by an anion‐exchange reaction. 相似文献