Synthesis,characterization, and curing kinetics of novel ladder‐like polysilsesquioxanes containing side‐chain maleimide groups

Two ladder‐like polysilsesquioxanes (LPS) containing side‐chain maleimide groups have been synthesized successfully by reacting N‐(4‐hydroxyphenyl)maleimide (HPM) with LPS containing 100 mol % of chloropropyl groups (Ladder A ) and 50 mol % of each methyl and chloropropyl group (Ladder B ). HPM was synthesized by reacting maleic anhydride with 4‐aminophenol, and the resulting amic acid was imidized using p‐toluenesulfonic acid as a catalyst (Scheme 1 ). The LPSs were characterized by Fourier transform infrared (FTIR), ¹H nuclear magnetic resonance (NMR), proton‐decoupled ¹³C NMR, ²⁹Si NMR, wide‐angle X‐ray diffraction (WAXD), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Characterization indicated that these polymers had ordered ladder‐like structures with possible defects. These polymers were soluble in common solvents at ambient temperature, which suggested that they were not crosslinked. Both the polymers and the HPM were cured, and their kinetics were followed by dynamic DSC. The Ozawa and Kissinger methods were used to calculate activation energies for curing. Curing increased the temperature at which both 5% weight loss and maximum rate of weight loss were observed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4036–4046, 2004     

立窑窑面空气过剩系数与节能浅析

本文根据一些立窑水泥厂的热工测定数据,推导出了化学不完全燃烧热损失Q_(hb),废气带走热损失Q_f与窑面空气过剩系数之间的关系,阐述了产生化学不完全燃烧热损失的原因,并就如何降低热损失,节约能源提出了设想。     

分叉问题的几何描述及其计算方法

本文通过一个构造的向量场,建立了非线性代数方程组的解流形与对应向量场的不变流形之间的等价关系,把解流形的分叉问题转化为对向量场奇点附近局部性态的研究。这种思路具有几何直观性,并为解流形的跟踪与分叉计算提供了一套新的数值方法。     

空调冷凝器、蒸发器残留水分量检测系统

本文介绍了空调冷凝器、蒸发器残留水分量检测系统的组成和工作原理、技术指标、系统的工艺过程，最后说明了系统的考核和应用情况。     

小型建筑施工企业机械设备维修保养制度探析

小型建筑施工企业建立科学合理的机械设备维修保养制度，是保证工程质量和提高企业经济效益的重要环节。     

试论唐代宫廷宴饮风俗及其影响

唐代宫廷通过征收赋税、内官进奉、外官进奉和外蕃进奉等手段使得国库丰盈，这样唐代宫廷就有余财频繁地举行宴饮活动。唐代宫廷宴饮的主要类型有节日宴会、皇帝游宴、皇家醣宴、庆功宴、朝会及伴随祭祀活动而举行的宴会、宫廷内宴、皇帝为任命的外官饯行宴、皇帝迎接外蕃的宴会。唐代宫廷宴饮中主要的佐乐活动有行酒令、乐舞表演、百戏游艺节目表演等，这些活动一方面有效地调节宫廷宴饮气氛，另一方面也使得唐代宫廷宴饮风俗具有更丰富的文化内涵。唐代宫廷宴饮风俗作为一种上层丈化，为唐代社会各阶层所效仿，同时这种风俗也被五代直接继承。     

Molecular cloning and expression of interleukin Ibeta (IL-1β) from red seabream (Pagrus major)

The interleukin 1β (IL-1β) cDNA was cloned from the red seabream (Pagrus major) by homology cloning strategy. A cDNA fragment was amplified by PCR using two degenerated primers, which were designed according to the conserved regions of other known IL-1β sequences, and elongated by 3' ends and 5' ends RACE PCR to get the full length coding sequence of red seabream IL-1β (RS IL-1β). The sequence contained 1252 nucleotides that included a 5' untranslated region (UTR) of 84bp, a 3' UTR of 410 bp and an open reading frame (ORF) of 759 nucleotides which could be translated into a putative peptide of 253 amino acids with molecular weight of 28.6 kD and putative isoelectric point pI of 5.29. The deduced peptide contained two potential N-glycosylation sites and an identifiable IL1 family signature, but lacked the signal peptide and the clear ICE cut site, which were common in other nonmammalian IL-1β genes. The RS IL-1β had the highest homology with piscine IL-1β according to phylogenetic tree analysis.     

汽车碰撞事故的速度分析

通过对交通事故中汽车的碰撞问题的简化 ,运用动量守恒定理和能量守恒定律着重研究了正面碰撞、追尾碰撞和侧面碰撞三种情况下 ,汽车碰撞前动量和速度的求解方法 ,为交通事故模拟和再现提供了一种更为实用的方法 ,并为科学处理交通事故、明确事故责任提供了重要参考。     

300 km·h-1电动车组制动参数研究

在我国研制的先锋号电动车组制动系统的基础上 ,借鉴国外高速列车的经验 ,对自行研制 30 0km·h-1高速动车组制动系统的重要参数进行了研究 ,并提出了可供运用的设计值 .通过对先锋号动车组和 30 0km·h-1高速动车组制动参数的比较分析 ,指出先锋号制动系统的模式比较适合于 30 0km·h-1动车组 .     

关于W变换性质的进一步讨论

根据W变换和Delta函数的定义，讨论了函数f(x)的线性函数af(x) b的W变换和函数Ⅱi-1^n，(x)的W变换问题，并推广了W变换的线性性质，得到了几个进一步的结果．