Highly Selective Copper‐Catalyzed Asymmetric [3+2] Cycloaddition of Azomethine Ylides with Acyclic 1,3‐Dienes

The first examples of the catalytic asymmetric 1,3‐dipolar cycloaddition of azomethine ylides with acyclic activated 1,3‐dienes (and 1,3‐enynes) are described. Under copper catalysis, a selective cycloaddition at the terminal γ,δ‐C?C bond is observed. In addition, depending on the ligand used, either the exo or the endo adduct can be obtained with high selectivity. Under appropriate reaction conditions, the acyclic 1,6‐addition product is detected, suggesting a stepwise mechanism. The resulting C4‐alkenyl‐substituted pyrrolidines are suitable substrates for further access to polycyclic systems, as highlighted by the preparation of hexahydrochromeno[4,3‐b]pyrrole and the tetracyclic core of the alkaloid gracilamine.     

中国大气颗粒物污染与致癌研究进展

 室外空气污染和污染空气中的颗粒物是一类致癌物，而近年中国的大气颗粒物污染仍然维持在较高浓度水平。通过综述中国近年大气颗粒物污染现状和开展的颗粒物致癌机制研究，分析中国研究中颗粒物有关实验动物致癌性的证据和颗粒物致癌的人群流行病学线索，阐述大气颗粒物与癌症的关系，提出中国亟需开展相关研究。     

Numerical Evaluation of a Two-Loop Diagram in the Cutoff Regularization

The sunset diagram of λφ4 theory is evaluated numerically in cutoff scheme and a nonzero finite term(in accordance with dimensional regularization (DR) result) is found in contrast to published calculations. This findingdramatically reduces the critical couplings for symmetry breaking in the two-loop effective potential discussed in ourprevious work.     

Unidirectional Quantum Remote Control:Teleportation of Control-State

We investigate the problem of teleportation of unitary operations by unidirectional control-state telepor-tation and propose a scheme called unidirectional quantum remote control. The scheme is based on the isomorphismbetween operation and state. It allows us to store a unitary operation in a control state, thereby teleportation of theunitary operation can be implemented by unidirectional teleportation of the control-state. We find that the probabilityof success for implementing an arbitrary unitary operation on arbitrary M-qubit state by unidirectional control-stateteleportation is 4-M, and 2M ebits and 4M cbits are consumed in each teleportation.     

大学新生入馆教育初探

对新生入学后出现的一些借阅问题进行了有针对性的分析，并提出了相应的解决办法。阐述了新生入馆教育的重要性及其在沟通师生关系、做好服务工作方面的深远意义。     

各向同性介质与单轴晶体界面上e光波法线的折射

根据光的电矢量满足的边条件，对各向同性介质与单轴晶体界面上e光波法线的折射进行了具体的讨论，得到了确定e光波法线在单轴晶体中传播方向的公式，并对几种特殊情况进行了具体讨论。指出了由所得结果可以确定e光光线的行进方向。     

数学难以理解的逻辑透视

对数学教学内容的逻辑结构、逻辑规则和方法以及数学语言进行逻辑透视，探讨数学难以理解的客观因素及对策．     

区域经济发展不平衡对义务教育投入的影响

地区经济发展不平衡是我国的一个基本国情，上世纪90年代义务教育投资总量和人均教育经费投入水平在我国三大地带呈现巨大差距，其成因是多方面的，要改变这种状态，必须建立规范的政府间基础教育财政支付制度，对政府管理基础教育的层级进行调整，建立农村义务教育教师工资保障机制。     

新课程标准下初中化学教师应建立的教育理念

结合化学学科的特点,从课程观、学生观、学习观、教学观和评价观5个方面对新课程标准下初中化学教师应具有的教育理念进行了探讨,希望能对教师教育理念的转变有所帮助.     

Environmental Friendly Route and Wool Shrink Proofing

The shrink proofing on wool with treatment of protease named Argaenzyme STL was studied. The various pretreating auxiliaries, different parameters for protease treating process and the effect of stabilizer were discussed in detail. The varieties of some properties before and after protease treatment were also investigated.