Chemical Constituents and Antibacterial and Antifungal Activities of Two Aglaia Species

In the course of searching bioactive natural products from the plant genus Aglaia, we selected two species, A. cordata and A. testicularis, for further chemical study. Totally twenty natural compounds were obtained and structurally elucidated with which eleven of them were discovered for the first time. Among these compounds, lignans, rocaglamides,aglains and bisamides were the main constituents of the two plant species. The results from a bioactive screening indicated that some of the lignans possess potent antibacterial and antifungal activity.     

新型Zhuo酚酮类糖苷化合物的合成

根据Zhuo酮的结构特点，对Zhuo酚酮类化合物与半乳糖的Kenigs-Knorr反应进 行了研究。探索出一种具有较高立体选择性的合成方法，从而制得四种具有β－构 型的单一端基异构体的Zhuo酚酮半乳糖苷新化合物。生成的新化合物不但保持了原 有的生理活性，而且降低了毒性、提高了药效，为人工合成Zhuo酚酮类增添新化合 物的同时，也扩展了此类化合物的应用领域。应用元素分析、核磁共振、红外光谱 表征了它们的结构。     

An Efficient Method for the Synthesis of Acyl-diazenes Using NaNO_2/NaHSO_4·H_2O

Azo compounds are widely utilized as analytic reagents and dyes1, they can also be used in material of non-linear optics, material of optics information storing in laser disks, and dyes with oil solubility in photochromy in modern technology2. Recently, many noteworthy studies have shown that some azo compounds possess excellent optical memory and photoelectric properties3,4. For example, polymer scaffolds bearing azobenzene-potential are useful for optical information storage, azo-dye doped…     

A Novel, Simple and Efficient Synthesis of Ferrocenyl Enones and Alkynols

Propargylic alcohols are versatile precursors to many organic molecules including natural products and pharmaceutical compounds.[1] In our continuing interest in the development of practical methods for synthesis of ferrocene derivatives, we decided to investigate the efficiencies of ferrocenylacetylene addition to aromatic aldehydes under t-BuOKcatalyzed condition.[2] Interestingly, we found that the usually reliable coupling reaction between terminal alkyne of type 1 and aromatic aldehydes of type 2 does not furnish the expected propargylic alcohols, but that the isomeric aryl enones 3are found in high yield and very short reaction time (10～20 min). This provided a promising protocol for preparation of ferrocenyl chalcones in a practical, economical and mild sense compared with the traditional method. To the best of our knowledge, this unusual reaction was first observed for the addition of ferrocenylacetylene to aldehyde in a base-catalyzed manner (Eq. 1).     

Microwave-Assisted Olefination Reaction of Alkylzinc with Aromatic Aldehyde Catalyzed by Nickel Complex

Carbon-carbon double bond-forming reactions have always been great importance in organic synthesis. Manymethods have been described for C =C bond formation. We[1] have reported the new method of C =C bond formation of nickel catalyzed organozinc with aromatic aldehydes in the presence of Me3SiC1.     

ArcGIS在武夷山保护区林业有害生物分布电子地图制作中的应用

本文详细介绍了利用ArcG IS 9.0制作林业有害生物分布电子地图的方法,包括创建要素图层,建立连接,数据符号化以及图层标注。     

基于0.6μm CMOS复接器的设计

复接器是光纤通信系统的重要组成部分。文章采用CSMC-HJ0.6μmCMOS工艺设计,工作速率为622Mb/s的4∶1复接器。为了适应高速电路设计的需要,采用源级耦合场效应管逻辑(SCFL)电路形式和树型结构,分析和设计了复接器的系统结构和单元电路,并用SmartSpice进行了仿真。仿真结果表明,电路的工作速率可以达到622Mb/s,且其它各项指标均可达到要求。     

具有多奇性的非线性热方程的定解问题

利用Kato类函数和Green胎紧函数的性质得到了具有多奇性的非线性热方程的初值问题和初边值问题．弱解的存在性．     

高校德育内容的构建与创新

高校德育目标的实现关键在于德育内容的系统构建.目前高校德育内容存在着把德育等同于政治教育、社会适应性教育及理想教育的倾向.针对存在问题,按系统论的要求,对高校德育内容构建进行改革和创新:一是以人的发展为出发点;二是实现理想性与现实性的统一;三是要做到社会适应性与个体发展相结合.     

螺旋加料动态定量称重控制方法的研究

提出了一种新型螺旋加料动态定量称重控制方法 .该方法基于自校正预测控制算法 ,采用“先快后慢、最后点动”的动态控制方式 ,从而有效地解决了动态定量称重过程中精度和速度的矛盾 .理论和实验的研究表明 ,该方法对动态在线定量装料、定量包装和称重配料等方面具有广泛的应用潜力