EXAFS study of 20GaF3–15InF3–20CdF2–15ZnF2–20PbF2–10SnF2 glass

The structure of 20GaF₃–15InF₃ –20CdF₂–15ZnF₂–20PbF₂–10SnF₂ glass (GICZPS) was studied by EXAFS and XRD. The results indicate that Ga³⁺ is more stable than In³⁺ in the GICZPS glass network, and Zn²⁺ is the glass modifier, the coordination number of which is 6.     

新安江-海河模型的构建与应用

为研究海河流域下垫面变化对洪水的影响,对新安江模型进行修订,得到新安江-海河模型。选择海河6个典型流域作为研究对象,分别用新安江模型与新安江-海河模型进行产汇流模拟计算,结果表明:洪水分年代、分量级模拟精度较高,但此时新安江模型参数取值不合理,SM值偏大;新安江-海河模型与新安江模型精度相当或稍有提高,参数取值更加合理。     

Purification and Characterization of a Novel β-Galactosidase with Transglycosylation Activity from <Emphasis Type="Italic">Bacillus megaterium</Emphasis> 2-37-4-1

A novel β-galactosidase of 120 kDa (BgaBM) from Bacillus megaterium 2-37-4-1 was purified, and its gene (bgaBM) was analyzed and expressed. It displayed wide acceptor specificity for transglycosylation with a series of acceptors, including pentose, hexose, hydroxyl, and alkyl alcohol using o-nitrophenyl-β-d-galactoside (ONPG) as a donor. BgaBM preferentially hydrolyzed ONPG in all tested substrates and showed maximum activity at pH 7.5–8.0 and 55 °C. It was stable at pH 6.0–9.0 below 40 °C. The K _m and V _max values for ONPG and lactose were 9.5 mM, 16.6 mM/min and 12.6 mM, 54.4 mM/min, respectively. The nucleotide sequence of the bgaBM gene consists of an ORF of 3,105 bp corresponding to 118 kDa protein, which indicates that BgaBM is a modular enzyme in the glycosyl hydrolase family 2, including conserved sugar-binding domain, acid–base catalyst, and immunoglobulin-like beta-sandwich domain. The possible acid/base and nucleophile sites of BgaBM were estimated to be E481 and E547, respectively. Furthermore, expression of the bgaBM gene in Escherichia coli and purification of the recombinant enzyme were performed. The recombinant enzyme showed similar biochemical characteristics to natural enzyme.     

Osmabenzenes from Osmacycles Containing an η2‐Coordinated Olefin

Osmabenzenes can be easily synthesized from two η²‐coordinated olefin osmacycles in the presence of benzonitrile by means of facile hydrogen‐transfer conversions (see graphic). Mechanisms for the formation of osmabenzenes are proposed based on DFT calculations.

     

Long cycles in 4-connected planar graphs

Let G be a 4-connected planar graph on n vertices. Malkevitch conjectured that if G contains a cycle of length 4, then G contains a cycle of length k for every k∈{n,n−1,…,3}. This conjecture is true for every k∈{n,n−1,…,n−6} with k≥3. In this paper, we prove that G also has a cycle of length n−7 provided n≥10.     

金属有机骨架材料低温储氢性能测试装置

设计了一套金属有机骨架(MOFs)材料低温储氢性能测试装置。该装置的设计压力为10MPa,可以在低温宽温区范围内对多种金属有机骨架材料的低温储氢性能进行测试,且样品更换方便。此外,还介绍了试验的原理及步骤。     

液氮中单管加注二氧化碳气体的实验研究

向饱和液氮中加注常温二氧化碳气体时,为形成细小而分散的固体二氧化碳颗粒以及充分且均匀的固液混合物,通过实验分别采用不锈钢盘管、大管径塑料管以及金属毛细管往液氮中加注一定流量下的常温二氧化碳气体,研究固液混合过程、凝固颗粒大小以及管路的堵塞状况。结果表明,不管是否经过预冷,大直径管道加注时,经过一段时间后管道必定发生堵塞;而毛细管加注则不会堵塞,但是气体流量会发生脉冲性变化。     

低温储罐气相空间漏热的理论研究

低温液体在储罐内的无损储存时间是低温储运过程中非常值得关心的一个问题,而漏热量的准确确定是预测无损储存时间的关键因素。使用了大空间自然对流换热模型,对气相空间的漏热进行了研究,在此基础上,提出新的无量纲数G l。并在总结分析的基础上给出了适合工程应用的气相漏热计算公式和气相漏热实用估算表。     

On the structure of large sum-free sets of integers

A set of integers is called sum-free if it contains no triple (x, y, z) of not necessarily distinct elements with x + y = z. In this paper, we provide a structural characterisation of sum-free subsets of {1, 2,..., n} of density at least 2/5 ? c, where c is an absolute positive constant. As an application, we derive a stability version of Hu’s Theorem [Proc. Amer. Math. Soc. 80 (1980), 711–712] about the maximum size of a union of two sum-free sets in {1, 2,..., n}. We then use this result to show that the number of subsets of {1, 2,..., n} which can be partitioned into two sum-free sets is Θ(2^4n/5), confirming a conjecture of Hancock, Staden and Treglown [arXiv:1701.04754].