4块问题的H~∞优化设计

本文对状态不完全可测系统的4块H~∞控制问题进行了研究,运用动态输出反馈的方法,通过系统的两个代数Riccati方程,实现了预定H~∞范数指标下的优化控制.与现有文献不同之处在于,本文方法在代数Riccati方程不加摄动项的情况下放宽了假定条件,而且控制器的计算较为简单.     

多变量系统l~1最优反馈控制器的解耦设计方法

本文提出了一种多变量系统l~1最优反馈控制器设计方法。通过解耦灵敏度函数,使多变量系统的设计问题转化为若干个单变量系统设计问题。分别求解后,求出l~1优化控制器。文中还进一步讨论了在z平面单位圆内有重零、极点的单变量系统l~1优化控制器的求解问题,给出了这种情况下最优灵敏度函数次数的上界。     

三轴应力场中空穴扩张临界值与材料的微观断裂延性

选用一种球化碳钢的轴对称光滑和不同缺口拉伸试样研究了材料在三轴应力场中的宏、微观断裂延性。基于不同应力三轴性水平下空穴扩张与聚合的特性,给出了一个新的材料微观断裂延性表达式。结合空穴扩张的临界尺寸与断口韧窝几何的三维测量结果,证明了在不同的三轴应力水平下,材料微观断裂延性与实测宏观断裂延性之间均有着良好的一致性。从而揭示了材料断裂延性随应力三轴性水平升高而下降的微观机理。     

Direct mass measurements of the neutron-rich isotopes of chlorine through iron

Direct mass measurements of up to 6 isotopes for each of the elements chlorine through iron (over 35 masses) have been performed using the Time-of-Flight Isochronous (TOFI) spectrometer. We have used these measurements to: (1) investigate the local dependence of neutron and proton pairing energies on neutron excess, (2) find a new region of enhanced binding centered around⁵³Sc, and (3) evaluate the predictive capabilities of several mass models.     

Intramolecular [4+2] cycloaddition reactions of enamines and enamides

An attempt to utilize a new strategy for alkaloid synthesis which features the intramolecular [4+2] cycloaddition of enamines and enamides for the construction of the tetracyclic spiroamine skeleton characteristic of the Erythrina alkaloids was unsuccessful, unexpectedly giving a bridged cycloadduct rather than a fused one.     

One-step nanocasting synthesis of highly ordered single crystalline indium oxide nanowire arrays from mesostructured frameworks

A one-step nanocasting route has been demonstrated to prepare highly ordered single-crystal indium oxide nanowire (IONW) arrays with mesostructured frameworks. Unlike the reported multistep nanocasting process (synthesis of mesoporous materials, and then incorporation of precursors and formation of inorganic frameworks), a highly ordered mesostructured surfactant-silica monolith with low external surface serves as both the template and the reducing agent and makes the formation of single-crystal IONWs in its channels easily in one step by using normal In(NO(3))(3) as an inorganic precursor. After silica is removed, highly ordered uniform single-crystal IONW arrays with hexagonal (p6mm) or cubic (Ia3d) mesostructures are derived. These new materials are studied by XRD, SEM, TEM, N(2) adsoption, and UV spectrum. Furthermore, this one-step nanocasting synthesis route is a generalized method and can be used to synthesized a highly ordered mesoporous silica monolith with metal oxide nanocrystals in its channels. To the best of our knowledge, this is the first report of a single crystalline mesostructured In(2)O(3) framework.     

Efficient heterogeneous asymmetric transfer hydrogenation of ketones using highly recyclable and accessible silica-immobilized Ru-TsDPEN catalysts

[reaction: see text] Chiral Ru-TsDPEN [N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]-derived catalysts were first successfully immobilized onto amorphous silica gel and mesoporous silicas of MCM-41 and SBA-15 by an easily accessible approach. The catalyst immobilized on silica gel demonstrated remarkably high catalytic activities and excellent enantioselectivities (up to >99% ee) for the heterogeneous asymmetric transfer hydrogenation of various ketones. Particularly, the catalyst could be readily recovered and reused in multiple consecutive catalytic runs (up to 10 uses) with the completely maintained enantioselectivity.     

五氧化二钒催化钾碱液吸收二氧化碳的机理

从五氧化二钒(V_2O_5)的物理化学性质出发,研究了V_2O_5加快CO_2在钾碱液(K_2CO_3)中的吸收速率的化学作用机理。实验证明: 当9相似文献