高温合金涡轮盘材料的裂纹扩展速率

用直流电位研究了高温合金涡轮盘材料的裂纹扩展速率，结果表明：高温合金涡轮盘材料的裂纺展速率快慢，不完全取决于材料强度，更主要地取决于持久塑性，在考察高温合金涡轮盘材料的裂纹扩展时，不能认速率值ｄａ／ｄＮ的绝对值来衡量，还应看裂纹扩展速率曲线的斜率是否锐减或曲线出现明显的拐点，以及曲线所对应的应力强度因子△Ｋ的范围。     

论网络时代高校思想政治工作面临的挑战及对策

本文主要分析新形式下网络对高校思想政治工作带来的挑战,及如何应对这种挑战,提出相应的对策,旨在为高校思想政治教育工作者提供指导。     

国有商业银行人力资源管理再造

随着股份制银行的异军突起，外资银行人才策略本土化的实施，国有商业银行面临极为激烈的竞争，如何提高人力资源管理水平，增强竞争优势。是摆在国有商业银行人力资源管理者面前一个严峻而重大的现实问题。本文通过对国有商业银行现行人力资源管理中存在的问题进行探讨，提出必须按照人力资源国际化的要求，建立起充满生机与活力的人力资源管理体制。     

基于过程挖掘的临床路径Petri网建模

提出基于统计α算法的临床路径Petri网模型,将Petri网和基于统计α算法的过程挖掘算法集成,从事件日志中挖掘重要信息,获得完善的诊疗流程,并在此基础上建立Petri网模型,有效实现诊疗流程的优化和改进.通过仿真数据试验,验证了本文提出的统计α算法相较于经典α算法在准确度和运行时间上有着较大的优势.并将模型运用到临床路径真实数据上,证明了模型的有效性和准确性.     

Optimization of Pretreatment Method for Alkylmercuries Speciation in Coal by High‐Performance Liquid Chromatography Coupled with UV‐Digestion Cold Vapor Atomic Fluorescence Spectrometry

Abstract

Exhaustive extraction of analytes in their original chemical forms from samples with complex matrices is a pivotal step for speciation analysis. Herein we propose a pretreatment method for extracting and preconcentrating methylmercury and ethylmercury from coal samples by using KBr–H₂SO₄/CuSO₄–C₆H₅CH₃–Na₂S₂O₃ system. The extraction conditions, including the volume of the organic phase and the extraction time, were optimized in detail. Speciation analysis of alkylmercuries was carried out by high‐performance liquid chromatography online coupled with UV‐digestion and cold vapor atomic fluorescence spectrometry. The detection limits were 0.6 ng mL^?1 for methylmercury and 1 ng mL^?1 for ethylmercury, respectively. The recoveries of methylmercury and ethylmercury spiked in a sample were 84% and 82%, respectively. The method was applied successfully to analysis of alkylmercuries in four coal samples collected from northeast China.     

Liposome-Boosted Peroxidase-Mimicking Nanozymes Breaking the pH Limit

Peroxidase-mimicking nanozymes such as Fe₃O₄ nanoparticles are promising substitutes for natural enzymes like horseradish peroxidase. However, most such nanozymes work efficiently only in acidic conditions. In this work, the influence of various liposomes on nanozyme activity was studied. By introducing negatively charged liposomes, peroxidase-mimicking nanozymes achieved oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) in neutral and even alkaline conditions, although the activity towards anionic 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) was inhibited. The Fe₃O₄ nanoparticles adsorbed on the liposomes without disrupting membrane integrity as confirmed by fluorescence quenching, dye leakage assays, and cryo-electron microscopy. Stabilization of the blue-colored oxidized products of TMB by electrostatic interactions was believed to be the reason for the enhanced activity. This work has introduced lipids to nanozyme research, and it also has practically important applications for using nanozymes at neutral pH, such as the detection of hydrogen peroxide and glucose.