PURIFICATION OF L-METHIONINE AND N-ACETYL-D-METHIONINE FROM THE MIXTURE OF ENZYMATICALLY DEACYLATED N-ACETYL-DL-METHIONINE

1. INTRODUCTION Methionine, namely 2-amido-4-thiomethyl butyric acid with a structure of CH3SCH2CH2CHCOOH, is one of the essential amino acids and has two natural enantionmers, D and L-methionine. The mixture of L- and D-isomers can be used as analeptics or nutritive additives to maintain the equilibrium of amino acids of feed [1,2]. L-methionine can release active methyl and accelerate the synthesis of choline, which further speeds up the conversion of the lipid accumulated in liv…     

A New Triterpene from the Orchid Pholidota yunnanensis

A new triterpene, 25-methylenecyclopholidonyl p-hydroxy-trans-cinnamate, was isolated from a orchid Pholidota yunnanensis. The structure elucidation and ^1H, ^13C-NMR assignments were achieved by spectral and chemical method.     

Microwave Synthesis, Characterization and DNA-binding Properties of a New Cobalt（ Ⅱ ） Complex with 2,6-Bis（benzimidazol-2-yl）pyridine

A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra.     

Baker＇s Yeast Mediated Reduction of Optically Active Diketone

Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products.     

Thermal Oxidation of Polyethylene Films Containing Dispersed Copper and Amine Antioxidant

Thermal oxidation of polyethylene filled with dispersed copper and containing an amine antioxidant was studied. The concentration ranges in which the catalytic effect of the metal on the polymer oxidation or the stabilizing effect of the antioxidant prevails were determined. Under certain conditions, dispersed copper enhances the stabilizing effect of the antioxidant.     

Mean curvature flows and isotopy of maps between spheres

Let f be a smooth map between unit spheres of possibly different dimensions. We prove the global existence and convergence of the mean curvature flow of the graph of f under various conditions. A corollary is that any area‐decreasing map between unit spheres (of possibly different dimensions) is isotopic to a constant map. © 2004 Wiley Periodicals, Inc.     

关于三商映射

三商映射是完备映射和开映射的共同推广。本文综述三商映射的理论，论术这三商映射，开映射，紧覆盖映射，诱导完备映之间的一些转换关系，提出了几个供进一步研究的问题。     

Structure and magnetic properties of nanocrystalline ferromagnets (II)

The role of magnetoelastic coupling effects in nanocrystalline ferromagnets is investigated by means of high-field magnetization and Doppler-broadening spectrum measurements. For the nanocrystalline Fe_{73 5}Cu₁Nb₃Si_13.5B₉ alloy, the results show that the pinning effects resulting from the quasidislocation dipole intensely influence the movement of domain wall; by coupling with the magnetostriction the defects-induced stress fields determine the magnetic properties at the early stage of crystallization. In view of the effective anisotropy and magnetoelastic coupling energy the optimal annealing conditions of alloys are discussed.     

海口市番茄反季节栽培品种比较试验初报

海口市番茄生产的正常季节是冬种春收。其产量虽然较高,但产值较低。本试验是通过引进耐热番茄品种,将播种期推迟到二月春种夏收,即反季节栽培。试种结果初步表明:泰引3号、扬帆2号等引进品种,在气温较高的条件下,植株生长正常,座果率较高,产量与品质能达到当地正常季节栽培的水平。我们初步认为,泰引3号比较理想,可在海口市郊进一步试种。     

血液的光学性质研究

本文用辐射输运理论方法去计算红细胞的光学特征量,并在此基础上提出检测血细胞数密度的理论实验方案,其结果与传统的方法一致。本文为开发一种血球数自动检测仪提供了理论基础和仪器结构原型。